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公开(公告)号：EP1492754A2
公开(公告)日：2005-01-05
申请号：EP03745809.8
申请日：2003-03-28
摘要： The invention concerns a method for making carboxylic acids by oxidizing an alkyl hydroperoxide compound. More particularly, the invention concerns oxidation of a cyclohexyl peroxide into an adipic acid with an oxidizing agent containing molecular oxygen or an oxygen-containing gas in the presence of an oxidation catalyst including a metal belonging to the groups of transition metals.
摘要翻译： 本发明涉及一种通过氧化烷基过氧化氢化合物制备羧酸的方法。 更具体地说，本发明涉及在包含属于过渡金属族的金属的氧化催化剂存在下，用含分子氧或含氧气体的氧化剂将过氧化环己基氧化成己二酸。
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2.发明公开PROCEDE DE DECOMPOSITION CATALYTIQUE DES HYDROPEROXYDES ORGANIQUES 有权VERFAHREN ZUR KATALYTISCHEN ZERSETZUNG冯有机原料HYDROPEROXIDEN
公开(公告)号：EP1440050A2
公开(公告)日：2004-07-28
申请号：EP02785556.8
申请日：2002-10-29
发明人： BONNET, Didier , FACHE, Eric , SEIGNEURIN, Aline
IPC分类号： C07C45/53 , C07C49/403 , C07C29/132 , C07B41/02 , C07B41/06
CPC分类号： C07C29/132 , B01J23/464 , B01J23/63 , C07B41/02 , C07B41/06 , C07C45/53 , C07C2601/14 , C07C31/1355 , C07C49/403
摘要： The invention concerns a method for decomposition of organic hydroperoxides, in the presence of a catalyst. It provides a method for decomposition of organic hydroperoxides in the presence of a catalyst in an alcohol and ketone mixture wherein the catalyst comprises at least a catalytically active ruthenium-based metal element incorporated in a solid support selected from the group consisting of metal oxides and carbons such as carbons obtained by pyrolysis of organic compounds. The inventive method is particularly useful for decomposition of chemical intermediates such as cyclohexyl hydroperoxide.
摘要翻译： 本发明涉及在催化剂存在下分解有机氢过氧化物的方法。 它提供了一种在催化剂存在下将有机氢过氧化物分解成醇和酮的混合物的方法，其中催化剂包含至少一种掺入固体载体中的钌基催化活性金属元素，所述固体载体选自包含金属氧化物和 炭黑，例如通过有机化合物的热解获得的炭黑。 本发明的方法在重要的化学中间体如环己基氢过氧化物的分解中特别有用。
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公开(公告)号：EP1412316A1
公开(公告)日：2004-04-28
申请号：EP02767570.1
申请日：2002-07-15
IPC分类号： C07C51/31 , C07C55/21 , C07C55/14 , C07C51/215 , C07C51/265 , C07C51/235 , C07C51/245 , C07C55/00 , C07C63/00
CPC分类号： C07C51/313 , C07C55/14 , C07C55/21
摘要： Process for the oxidation of an aliphatic or cycloaliphatic hydrocarbon (optionally substituted) or an alkylaromatic hydrocarbon and/or alcohols and ketones in a liquid medium by molecular oxygen in the presence of a manganese-based catalyst and an organic acid. The organic acid compound conforms to the formula(I) :- HOOC - Ar -(R)n - in which Ar = aromatic radical of one ring or several condensed rings; n = 1, 2 or 3; and R = a radical of formula -C(R1,R2,R3) (R1, R2, R3 = 1 - 4C alkyl or F).
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公开(公告)号：EP1060157B1
公开(公告)日：2003-06-25
申请号：EP99937924.1
申请日：1999-02-24
CPC分类号： C07C51/44 , C07C51/42 , C07C51/43 , C07C51/487 , C07C55/14
摘要： The invention concerns the treatment of reaction mixtures derived from an oxidation reaction of cyclohexane into adipic acid and more particularly the separation of the different constituents of said mixtures and the purification of the adipic acid.
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公开(公告)号：EP1305273A1
公开(公告)日：2003-05-02
申请号：EP01947587.0
申请日：2001-06-22
发明人： FACHE, Eric
CPC分类号： C07C51/313 , C07C55/14
摘要： The invention concerns a method for oxidising with oxygen or an oxygen-containing gas, hydrocarbons into corresponding carboxylic acids, alcohols and/or ketones or alcohols and/or ketones into corresponding carboxylic acids. More precisely the invention concerns a method for oxidising hydrocarbon, alcohol and/or ketone using oxygen or an oxygen-containing gas, in liquid phase and in the presence of a catalyst dissolved in a reaction medium. The invention is characterised in that the catalyst comprises a soluble manganese and/or cobalt compound, at least a soluble chromium compound and at least a soluble iron compound.
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6.发明授权
公开(公告)号：EP1268384B1
公开(公告)日：2005-10-19
申请号：EP01913955.9
申请日：2001-03-07
发明人： FACHE, Eric
IPC分类号： C07C51/215 , C07C51/31 , C07C55/14 , C07C55/21
CPC分类号： C07C51/313 , C07B41/00 , C07C27/12 , C07C29/50 , C07C45/33 , C07C45/36 , C07C51/215 , C07C2601/14 , C07C2601/20 , C07C49/403 , C07C55/14 , C07C55/21 , C07C35/08 , C07C35/205 , C07C31/38 , C07C31/40
摘要： The invention concerns a method for oxidising hydrocarbons, in particular saturated aliphatic hydrocarbons, whether branched or not, cycloaliphatic and alkylaromatic hydrocarbons into acid or polyacid compounds. More particularly, the invention concerns oxidation of cyclohexane into adipic acid with an oxidising agent containing molecular oxygen, in the presence of a lipophilic organic acid and in the absence of adipic acid. The separation and recycling of the non-oxidised cyclohexane from the oxidation intermediates and the catalysts are made easier than in the presence of acetic acid.
摘要翻译： 本发明涉及一种将烃类特别是支链或非支链饱和脂族烃，脂环族或烷基芳族烃氧化成酸性或多元酸化合物的方法。 本发明更具体地涉及在亲油性质的有机酸和不存在己二酸的情况下，使用含有分子氧的环己烷与己二酸的氧化剂进行氧化。 未氧化的环己烷，氧化中间体和催化剂的分离和再循环比在乙酸存在下更容易。
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公开(公告)号：EP1305273B1
公开(公告)日：2005-04-27
申请号：EP01947587.0
申请日：2001-06-22
发明人： FACHE, Eric
CPC分类号： C07C51/313 , C07C55/14
摘要： The invention concerns a method for oxidising with oxygen or an oxygen-containing gas, hydrocarbons into corresponding carboxylic acids, alcohols and/or ketones or alcohols and/or ketones into corresponding carboxylic acids. More precisely the invention concerns a method for oxidising hydrocarbon, alcohol and/or ketone using oxygen or an oxygen-containing gas, in liquid phase and in the presence of a catalyst dissolved in a reaction medium. The invention is characterised in that the catalyst comprises a soluble manganese and/or cobalt compound, at least a soluble chromium compound and at least a soluble iron compound.
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公开(公告)号：EP1237836B1
公开(公告)日：2004-05-06
申请号：EP00987558.4
申请日：2000-12-14
发明人： CLARK, James , FACHE, Eric , MACQUARRIE, Ducan , PRICE, Peter , RAFELT, John
IPC分类号： C07C45/53 , C07C29/132 , C07C409/14 , C07C49/403 , C07C35/08 , B01J31/16 , B01J31/18
CPC分类号： C07C409/14 , B01J31/1633 , B01J31/2243 , B01J2531/16 , B01J2531/62 , C07C29/132 , C07C45/53 , C07C407/00 , C07C2601/14 , Y02P20/588 , C07C49/403 , C07C35/08
摘要： The invention relates to a method for producing a mixture of alcohols/ketones by decomposing an alkyl hydroperoxide, particularly to a method for producing a cyclohexanol/cyclohexanone by decomposing cyclohexyl hydroperoxide in the presence of a heterogeneous catalyst. According to the invention, the reaction is carried out in the presence of a heterogeneous catalyst containing an organometallic segment fixed on the surface of a porous solid compound such as silicon. The organometallic segment ca be formula (I).
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公开(公告)号：EP1390338A1
公开(公告)日：2004-02-25
申请号：EP02727704.5
申请日：2002-04-30
发明人： FACHE, Eric , SIMONATO, Jean-Pierre
CPC分类号： C07C45/33 , C07B41/00 , C07C27/12 , C07C29/50 , C07C51/313 , C07C2601/14 , C07C2601/20 , C07C49/403 , C07C55/14 , C07C35/08 , C07C35/205
摘要： The invention relates to a method for oxidising hydrocarbons, particularly branched or non-branched saturated aliphatic hydrocarbons, cycloaliphatic or alkyl aromatic hydrocarbons, into alcohol, ketone and/or acid, polyacid compounds. More specifically, the invention relates to the oxidation, using an oxidising agent containing molecular oxygen, of cyclohexane into cyclohexanol, cyclohexanone and/or adipic acid. The oxidation is carried out in the presence of a catalytic system comprising a catalyst based on at least one metal compound and a co-catalyst comprising an imide function such as N-bromosuccinimide, N-bromomaleimide, N-bromohexahydrophtalimide, N,N'-dibromocyclohexanetetracarboximide, N-bromophtalimide, N-bromotrimellitimide, N,N'-dibromopyromellitimide.
摘要翻译： 本发明涉及一种将烃，特别是支链或非支链饱和脂族烃，环脂族或烷基芳烃，氧化成醇，酮和/或酸多酸化合物的方法。 更具体地说，本发明涉及使用含分子氧的氧化剂，将环己烷氧化成环己醇，环己酮和/或己二酸。 该氧化在包含基于至少一种金属化合物的催化剂和包含酰亚胺官能团的助催化剂如N-溴琥珀酰亚胺，N-溴马来酰亚胺，N-溴六氢邻苯二甲酰亚胺，N， 二溴环己烷四羧酰亚胺，N-溴邻苯二甲酰亚胺，N-溴三苯六甲酰亚胺，N，N'-二溴偏苯三酸酰亚胺。
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10.发明授权PROCEDE D'OXYDATION DE CYCLOALCANES, DE CYCLOALCANOLS ET/OU DE CYCLOALCANONES 有权VERFAHREN ZUR OXIDATION VON CYCLOALKANEN，CYCLOALKOHOLEN UND / ODER CYCLOKETONEN
公开(公告)号：EP1165481B1
公开(公告)日：2003-09-17
申请号：EP00915243.0
申请日：2000-03-29
发明人： FACHE, Eric , COSTANTINI, Michel
CPC分类号： C07C29/50 , C07C51/313 , C07C2601/14 , C07C55/14 , C07C35/08
摘要： The invention relates to a method for the oxidation of hydrocarbon in carboxylic acid, alcohol and/or corresponding ketone or alcohol and/or ketone in corresponding carboxylic acid by oxygen or a gas containing oxygen. The inventive method consists in oxidation of hydrocarbon, alcohol and/or ketone with the aid of oxygen or a gas containing oxygen in a liquid phase and in the presence of a catalyst that is dissolved in the reaction mixture, characterized in that the catalyst comprises a soluble manganese compound and at least one soluble chrome compound.
摘要翻译： 本发明涉及通过氧气或含有它的气体将烃与相应的羧酸，醇和/或酮或醇和/或酮与相应的羧酸氧化。 它更精确地包括在液相中和在溶解在反应介质中的催化剂存在下，使用氧气或含有它的气体氧化烃，醇和/或酮的方法，其特征在于催化剂包含可溶性锰 化合物和至少一种可溶性铬化合物。
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