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    Pesticidal compounds
    1.
    发明公开
    Pesticidal compounds 失效
    Pestizide Verbindungen。

    公开(公告)号：EP0380312A1

    公开(公告)日：1990-08-01

    申请号：EP90300721.9

    申请日：1990-01-23

    申请人： ROUSSEL-UCLAF ,  THE REGENTS OF THE UNIVERSITY OF CALIFORNIA

    发明人： Larkin, John Patrick ,  Weston, John Bernard ,  Smith, Ian Harold ,  Palmer, Christopher John ,  Casida, John Edward

    IPC分类号： C07D493/08 ,  C07D497/08 ,  A01N43/32 ,  A61K31/335

    CPC分类号： C07D493/08 ,  A01N43/90 ,  A01N55/00 ,  C07D495/08 ,  C07D497/08

    摘要： The present invention provides novel compounds of the formula (I):
    wherein R is a phenyl group, substituted by 1 to 5 fluorine atoms and optionally substituted at the para position by methyl or chloro or R is a group
    being a three of four membered ring, where R⁴ is oxygen or a group CR⁷R⁸ wherein groups R⁷, R⁸ are the same or different and each is hydrogen, fluoro, chloro or bromo or methyl or ethyl optionally substituted by 1 to 3 fluoro atoms, and when
    is a three-membered ring R⁵ is a group CR 7a R 8a wherein R 7a , R 8a are the same or different and each is hydrogen, fluoro, chloro or bromo or methyl or ethyl optionally substituted by 1 to 3 fluoro atoms, or when
    is a four membered ring R⁵ is a group CR 7a R 8a CR⁹R¹⁰ wherein R 7a , R 8a are as hereinbefore defined and R⁹ and R¹⁰ are the same or different and each is hydrogen, fluoro, chloro or bromo or methyl or ethyl optionally substituted by 1 to 3 fluoro atoms; R⁶ is hydrogen, fluoro, chloro or methyl;
    R¹ and R² may be the same or different, and each is hydrogen, halo, or a C₁₋₃ aliphatic group optionally substituted by halo, cyano, C₂₋₅ carbalkoxy, C₁₋₄ alkoxy, or a group S(O) m R¹¹ wherein m is 0, 1 or 2 and R¹¹ is C₁₋₄ alkyl; cyano, gem dimethyl, or C₂₋₅ carbalkoxy; R³ contains between 3 and 18 carbon atoms and is a group R¹² wherein R¹² is a C₁₋₁₃ non-aromatic hydrocarbyl group, optionally substituted by a C₂₋₄ carbalkoxy or cyano group and/or by one or two hydroxy groups and/or by one to five halo atoms which are the same or different and/or by one to three groups R¹³ which are the same or different and each contains one to four hetero atoms, which are the same or different and are chosen from oxygen, sulphur, nitrogen and silicon, 1 to 10 carbon atoms and optionally 1 to 6 fluoro or chloro atoms or R³ is a 6-membered aromatic ring substituted by cyano and/or by one to five halo atoms and/or by one to three C₁₋₄ haloalkyl groups and/or by a group -C≡CH, C≡C-halo or -C≡C-R¹² wherein R¹² is as hereinbefore defined or -C≡C-R¹⁴ wherein R¹⁴ is a group S(O) q R¹⁵ wherein R¹⁵ is methyl, ethyl or trifluoromethyl or R¹⁴ is SiR¹⁶R¹⁷R¹⁸ wherein R¹⁶ and R¹⁷ are the same or different and are each C₁₋₄ aliphatic groups and R¹⁸ is a C₁₋₄ aliphatic group or phenyl provided that R¹⁶, R¹⁷ and R¹⁸ do not contain more than 10 carbon atoms in total; and Y, Y¹ and Y² are the same or different and are each selected from oxygen and S(O) t where t is 0, 1 or 2, processes for their preparation, formulations containing them and their use in controlling pest infestation.

    摘要翻译： 本发明提供新的式（I）化合物：其中R为苯基，被1至5个氟原子取代，并且在对位被甲基或氯取代，或R为基团CHEM 其中R 4为氧或基团CR 7 R 8，其中基团R 7，R 8相同或不同，各自为氢，氟，氯或 溴或甲基或乙基，其任选被1至3个氟原子取代，当为三元环时，R 5为基团CR 7a R 8a，其中R 7a，R 8a， 各自为氢，氟，氯或溴或任选被1至3个氟原子取代的甲基或乙基，或当为四元环时R 5为基团CR 7a 其中R 7a，R 8a如上所定义，R 9和R 1相同或不同，各自为氢 氟，氯或溴或任选被1至3个氟原子取代的甲基或乙基; R 6是氢，氟，氯或甲基; R 1和R 2可以相同或不同，各自为氢，卤素或任选被卤素，氰基，C 2-5烷氧基，C 1-4烷氧基或基团取代的C 1-3脂族基团 S（O）m R 1，其中m为0,1或2，R 1为C 1-4烷基; 氰基，二甲基或C 2-5烷氧基; R 3含有3至18个碳原子，并且是基团R 1，其中R 1 2是C 1-13非芳族烃基，任选被C 2-4烷氧基取代或 氰基和/或一个或两个羟基和/或一至五个相同或不同的卤素原子和/或一至三个相同或不同的基团R 1，3各自包含 1至4个相同或不同的杂原子，选自氧，硫，氮和硅，1至10个碳原子和任选1至6个氟或氯原子或R 3为6元芳环 被氰基和/或一至五个卤素原子和/或一至三个C 1-4卤代烷基和/或被基团取代-C取代基C，C-C或卤代C 1 -C 2烷基 其中R 1'如上文所定义或-C元素CR 1其中R 1是S（O）q R 5基团，其中R 1是 > 5是甲基，乙基或三氟甲基，或者R 1是SiR 1 R 6 R 7 R 8其中R 1和R 2都是R <1> <7> R 1相同或不同，并且各自为C 1-4脂族基团，并且R 1'为C 1-4脂族基团或苯基，条件是R 1，R 2，R 1， 总共不含10个以上碳原子; Y，Y 1和Y 2相同或不同，各自选自氧和S（O）t，其中t为0,1或2，其制备方法，含有它们的制剂及其用途 防治虫害。

    Novel heterocyclic pesticidal compounds
    6.
    发明公开
    Novel heterocyclic pesticidal compounds 失效
    新型杂环农药化合物

    公开(公告)号：EP0372816A1

    公开(公告)日：1990-06-13

    申请号：EP89312432.1

    申请日：1989-11-29

    申请人： THE WELLCOME FOUNDATION LIMITED ,  THE REGENTS OF THE UNIVERSITY OF CALIFORNIA

    发明人： Larkin, John Patrick ,  Parkin, Donald ,  Palmer, Christopher John ,  Casida, John Edward

    IPC分类号： C07D339/08 ,  A01N43/28 ,  C07F7/08

    CPC分类号： A01N43/32 ,  A01N55/00 ,  C07D339/08 ,  C07F7/0812

    摘要： The present invention provides compounds of the formula (I):
    which contains between 9 and 27 carbon atoms, and wherein m and m¹ are independently selected from 0, 1 and 2; R 2a is hydrogen, methyl, or ethyl; R 2b is acetylene or contains between 3 and 18 carbon atoms and is a group R⁷, wherein R⁷ is a C₁₋₁₃ non-aromatic hydrocarbyl group, optionally substituted by a cyano or C₁₋₄ carbalkoxy group and/or by one or two hydroxy groups and/or by one to five halo atoms which are the same or different and/or by one to three groups R⁸ which are the same or different and each contains one to four hetero atoms, which are the same or different and are chosen from oxygen, sulphur, nitrogen and silicon, 1 to 10 carbon atoms and optionally 1 to 6 fluoro or chloro atoms or R 2b is a 6-membered aromatic ring substituted by cyano and/or by one to three groups R 8a and/or by a group -C≡CH, -C≡C-R 7a or C≡C-halo and/or by one to five halo atoms and/or by one to three C₁₋₄ haloalkyl groups wherein R 7a and R 8a are groups R⁷ and R⁸ as hereinbefore defined; R⁴ and R⁶ are the same or different and are chosen from hydrogen, methyl, trifluoromethyl or cyano; R 5a is a group
    wherein R⁹ is methyl, ethyl, chloro, bromo, methoxy, cyano, nitro, methoxymethyl, C₁₋₄ carbalkoxy or trifluoromethyl, R¹⁰ is chloro, methyl or trifluoromethyl or
    is a
    group wherein R¹² and R¹³ are both hydrogen, methyl, trifluoromethyl, fluoro, chloro or bromo or R¹² is hydrogen and R¹³ is fluoro, chloro or bromo, or
    is a three or four membered ring, R⁹ is oxygen or a group CR¹⁴R¹⁵ wherein the groups R¹⁴ and R¹⁵ are the same or different and each is hydrogen, fluoro, chloro or bromo or methyl or ethyl optionally substituted by 1 to 3 fluoro atoms, when
    is a three membered ring R¹⁰ is a group CR 14a R 15a wherein R 14a ,R 15a are the same or different and each is hydrogen, fluoro, chloro or bromo or methyl or ethyl optionally substituted by 1 to 5 fluoro atoms, or when
    is a four membered ring R¹⁰ is a group CR 14a R 15a CR¹⁶R¹⁷ wherein R 14a , R 15a are as hereinbefore defined, R¹⁶, and R¹⁷ are the same or different and each is hydrogen, fluoro, chloro or bromo or methyl or ethyl optionally substituted by 1 to 5 fluoro atoms and R¹¹ is hydrogen, methyl, trifluoromethyl, iodo, fluoro, chloro or bromo; and R 5b is hydrogen or C₁₋₃ alkyl; provided that R 2b is not propyl or butyl and that R 5a is not tertiary butyl or tertiary amyl;which are useful pesticides, processes for preparing them, pesticidal formulations containing them and their use in the control of pest infestation.

    摘要翻译： 本发明提供了式（I）的化合物：其含有9-27个碳原子，并且其中m和m'独立地选自0,1和2; R 2a是氢，甲基或乙基; R2b是乙炔或含有3-18个碳原子并且是基团R9，其中R9是任选被氰基或C1-4烷氧羰基取代和/或被一个或两个羟基取代的C 1-13非芳族烃基 和/或1-5个相同或不同的卤素原子和/或1-3个相同或不同的卤素原子，每个相同或不同，各自含有1-4个相同或不同的杂原子，并选自氧 ，硫，氮和硅，1-10个碳原子和任选1-6个氟或氯原子，或者R 2b是被氰基和/或被一至三个基团R 8a取代的6元芳环和/或被-C ≡CH，-C≡C-R7a或C≡C-卤素和/或被1-5个卤素原子和/或被1-3个C 1-4卤代烷基取代，其中R7a和R8a是如上所定义的基团R9和R9; R 4和R 6相同或不同，选自氢，甲基，三氟甲基或氰基; R5a是其中R7是甲基，乙基，氯，溴，甲氧基，氰基，硝基，甲氧基甲基，C1-4烷氧基或三氟甲基，R16是氯，甲基或三氟甲基或其中R12和R13都是氢的基团， ，三氟甲基，氟，氯或溴，或R 12是氢和R 13是氟，氯或溴，或是三或四元环，R 7是氧或CR 14 R 15基团，其中基团R 14和R 15相同或不同， 是氢，氟，氯或溴或任选被1-3个氟原子取代的甲基或乙基，当为三元环时，R 10为基团CR 14aR 15a，其中R 14a，R 15a相同或不同并且各自为氢，氟，氯或 溴或被1至5个氟原子任选取代的甲基或乙基，或当为四元环时，R 10为基团CR 14 a R 15a CR 17 R 18，其中R 14a，R 15a如前文所定义，R 10和R 10相同或不同， 氟，氯或溴或任选被1至5个氟原子取代的甲基或乙基，并且R 11为氢，甲基，三氟甲基，碘，氟，氯或溴; 和R5b是氢或C 1-3烷基; 条件是R2b不是丙基或丁基，R5a不是叔丁基或叔戊基;它们是有用的农药，它们的制备方法，含有它们的农药制剂以及它们在防治害虫侵染中的用途。