RESINS OF B-HYDROXY PROPYL GAMMA-POLYOXYALKYLENE ETHERS AND POLYMERS THEREOF
    3.
    发明公开
    RESINS OF B-HYDROXY PROPYL GAMMA-POLYOXYALKYLENE ETHERS AND POLYMERS THEREOF 有权
    VERFAHREN ZUR HERSTELLUNG VON HARZEN AUS B-羟基丙酸 - 聚氨基甲醛

    公开(公告)号:EP2742076A1

    公开(公告)日:2014-06-18

    申请号:EP12783776.3

    申请日:2012-10-25

    IPC分类号: C08F220/28 C08F8/14

    摘要: The present invention provides aqueous compositions comprising ß-hydroxy propyl gamma-polyoxyalkylene ether functional resins chosen from (poly)oxyalkylene ether ß-hydroxy propyl (meth)acrylates, maleates and itaconates, water soluble copolymers thereof, and mixtures thereof. The water soluble copolymers are comb polymers and (meth)acrylate, maleate and itaconate monomer resins can be addition polymerized to form comb polymers suitable for many uses, such as superplasticizers, dispersants, detergents and floor care compositions. In addition, the present invention provides methods of making the resins by reacting in water or aqueous solvent one or more reactant a) a glycidyl polyether or glycidyl ether, optionally having an alkyl or aryl end group with one or more reactant b) a carboxylate anion containing vinyl compound or polymer, preferably a polymer such as poly(meth)acrylic acid. The methods enable simple formation of comb polymers.

    摘要翻译: 本发明提供包含选自(聚)氧化烯醚和( - )羟基丙基(甲基)丙烯酸酯,马来酸酯和衣康酸酯,其水溶性共聚物和它们的混合物的β-羟基丙基γ-聚氧化烯醚官能树脂的含水组合物。 水溶性共聚物是梳状聚合物,(甲基)丙烯酸酯,马来酸酯和衣康酸酯单体树脂可以加成聚合以形成适用于许多用途的梳状聚合物,例如超增塑剂,分散剂,洗涤剂和地板护理组合物。 此外,本发明提供了通过在水或水性溶剂中反应制备树脂的方法,一种或多种反应物a)任选具有烷基或芳基端基的一种或多种反应物的缩水甘油醚或缩水甘油醚b)羧酸根阴离子 含有乙烯基化合物或聚合物,优选聚合物如聚(甲基)丙烯酸。 这些方法能够简单地形成梳状聚合物。