摘要:
A process for increasing purity of a low density polyethylene (LDPE) composition, comprising the steps of: a) providing a melted composition comprising LDPE having Mn of at least 5.0 kg/mol according to size exclusion chromatography, Mw of at least 50 kg/mol according to size exclusion chromatography, a density of 915 to 935 kg/m3 according to ISO1183 and a melt flow rate of 0.10 g/10 min to 80 g/10 min according to ISO1133:2011 measured at 190° C. and 2.16 kg, and b) providing particles from the melted composition by: b1) mixing a supercritical fluid in the melted composition to obtain a solution saturated with the supercritical fluid and b2) expanding the solution through an opening to obtain the particles.
摘要:
The present invention relates to a process for the production of ethylene polymers in a tubular reactor comprising reacting in said tubular reactor a feed composition comprising ethylene and one or more composition comprising one or more cyclic olefin wherein the cyclic olefin is a compound having the structure of Formula (I): wherein R may be a moiety comprising≥1 and≤10 carbon atoms; wherein R1 and R2 may each individually be hydrogen or a moiety comprising≥1 and ≤5 carbon atoms, R1 and R2 may be the same or different; wherein • the tubular reactor may be operated at a pressure of≥ 200 and ≤ 280 MPa; • the average reaction peak temperature may be≥ 220°C and ≤ 300°C; • the composition comprising one or more cyclic olefin may be fed to the reactor in one or more feed inlet of said tubular reactor; and • said cyclic olefin may be fed to the tubular reactor in quantities of≤ 1.0 mol %, with regards to the total feed composition. Such process allows for the production of ethylene polymers having a high density and a high purity.
摘要:
A process for increasing purity of a low density polyethylene (LDPE) composition, comprising the steps of: a) providing a melted composition comprising LDPE having Mn of at least 5.0 kg/mol according to size exclusion chromatography, Mw of at least 50 kg/mol according to size exclusion chromatography, a density of 915 to 935 kg/m3 according to ISO1183 and a melt flow rate of 0.10 g/10 min to 80 g/10 min according to ISO1133:2011 measured at 190° C. and 2.16 kg, and b) providing particles from the melted composition by: b1) mixing a supercritical fluid in the melted composition to obtain a solution saturated with the supercritical fluid and b2) expanding the solution through an opening to obtain the particles.
摘要:
The invention relates to a composition comprising A) a first polymer which is a polyethylene selected from linear low density polyethylene (LLDPE), low density polyethylene (LDPE), high density polyethylene (HDPE), an elastomeric copolymer of ethylene and an α-olefin having 4 to 10 carbon atoms and combinations thereof, B) a second polymer selected from the group consisting of a polyamide, a polycarbonate and an ethylene vinyl alcohol and combinations thereof and C) a third polymer which is an ethylene-acrylate copolymer which includes an acrylate represented by formula (I) or (II) as a comonomer:
CH 2 =CR 1 -COO-(CH 2 ) n -OH (I)
CH 2 =CR 1 -COO-(CH 2 ) m -CHOH-CH 2 OH (II)
wherein R 1 is H or C1-C5 linear or branched alkyl, n is an integer of 1-10 and m is an integer of 0-10, wherein the amount of A) with respect to the total composition is more than 50 wt%, the amount of B) with respect to the total composition is 3 to 45 wt% and the amount of C) with respect to the total composition is 0.1 to 10.0 wt%.