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公开(公告)号：EP3433010A1
公开(公告)日：2019-01-30
申请号：EP17717863.9
申请日：2017-03-17
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公开(公告)号：EP3350143A1
公开(公告)日：2018-07-25
申请号：EP16770088.9
申请日：2016-09-13
发明人： ALQAHTANI, Abdullah , WOHL, Anina , MULLER, Wolfgang , HARFF, Marco , BOLT, Heinz , METZNER, Andreas , NOACK, Ralf , GARTNER, Lars-Erik , MEISWINKEL, Andreas
CPC分类号： C07C2/32 , B01J31/143 , B01J31/189 , B01J31/34 , B01J2231/20 , B01J2531/62 , C07C2/22 , C07C2/26 , C07C2527/132 , C07C2531/14 , C07C2531/22 , C07C11/08 , C07C11/107 , C07C11/02
摘要： A process for deactivation of an olefin oligomerization catalyst is described, including contacting a catalyst composition with a catalyst quenching medium to form a deactivated catalyst composition, and recovering excess catalyst quenching medium. The catalyst quenching medium includes an alcohol having at least 6 carbon atoms, an organic amine, an amino alcohol, or a combination comprising at least one of the foregoing. The catalyst quenching medium is present in a molar ratio of catalyst quenching medium to catalyst of at least 3:1. A process for the oligomerization of an olefin is also described, including feeding the olefin, a solvent, and a catalyst composition into a reactor, oligomerizing the olefin in the reactor to form a reaction product stream including linear alpha olefins, solvent, and the catalyst composition, and contacting the reaction product stream with a catalyst quenching medium.
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公开(公告)号：EP3562584A1
公开(公告)日：2019-11-06
申请号：EP17840572.6
申请日：2017-12-28
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公开(公告)号：EP3558913A1
公开(公告)日：2019-10-30
申请号：EP17836054.1
申请日：2017-12-19
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公开(公告)号：EP3558905A1
公开(公告)日：2019-10-30
申请号：EP17835707.5
申请日：2017-12-19
发明人： AL-SHAHRANI, Dafer Mubarak , AZAM, Shahid , ZANDER, Hans-Jörg , MULLER, Wolfgang , WOHL, Anina , MEISWINKEL, Andreas , NOACK, Ralf , MEIER, Tobias , SCHMADERER, Harald
IPC分类号： C07C2/08
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公开(公告)号：EP3562585A1
公开(公告)日：2019-11-06
申请号：EP17835708.3
申请日：2017-12-21
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7.发明公开
公开(公告)号：EP3562579A1
公开(公告)日：2019-11-06
申请号：EP17838156.2
申请日：2017-12-21
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8.发明授权CATALYST COMPOSITION AND PROCESS FOR OLIGOMERIZATION OF ETHYLENE TO PRODUCE 1-HEXENE AND/OR 1-OCTENE 有权催化剂组合物和乙烯低聚反应生产1-己烯和/或1-辛烯的方法
公开(公告)号：EP3171974B1
公开(公告)日：2018-04-18
申请号：EP15770967.6
申请日：2015-07-22
发明人： AL-HAZMI, Mohammed H. , ALQAHTANI, Abdullah , ROSENTHAL, Uwe , MULLER, Bernd H. , PEULECKE, Normen N. , HARFF, Marco , WOHL, Anina , MEISWINKLE, Andreas , BOLT, Heinz , MULLER, Wolfgang
CPC分类号： B01J31/187 , B01J31/143 , B01J2231/20 , B01J2531/62 , C07C2/32 , C07C2531/14 , C07C2531/18
摘要： The present invention relates to a catalyst composition and a process for the oligomerization of ethylene to produce 1-hexene or 1-octene, wherein the catalyst composition comprises a chromium compound; an NPNPN ligand of the formula (R1) (R2)N—P(R3)—N(R4)—P(R5)—N(R6)(R7), wherein R1, R2, R3, R4, R5, R6 and R7 are each independently hydrogen, halogen, amino, tri-methylsilyl or C1-C20 hydrocarbyl, preferably straight-chain or branched C1-C10 alkyl, phenyl, C6-C20 aryl or C6-C20 alkyl-substituted phenyl.
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9.发明公开CATALYST COMPOSITION AND PROCESS FOR OLIGOMERIZATION OF ETHYLENE TO PRODUCE 1-HEXENE AND/OR 1-OCTENE 有权催化剂组合物和方法的乙烯低聚FOR PRODUCING 1-巫师和/或1-辛烯
公开(公告)号：EP3171974A1
公开(公告)日：2017-05-31
申请号：EP15770967.6
申请日：2015-07-22
发明人： AL-HAZMI, Mohammed H. , ALQAHTANI, Abdullah , ROSENTHAL, Uwe , MULLER, Bernd H. , PEULECKE, Normen N. , HARFF, Marco , WOHL, Anina , MEISWINKLE, Andreas , BOLT, Heinz , MULLER, Wolfgang
CPC分类号： B01J31/187 , B01J31/143 , B01J2231/20 , B01J2531/62 , C07C2/32 , C07C2531/14 , C07C2531/18
摘要： The present invention relates to a catalyst composition and a process for the oligomerization of ethylene to produce 1-hexene or 1-octene, wherein the catalyst composition comprises a chromium compound; an NPNPN ligand of the formula (R1) (R2)N—P(R3)—N(R4)—P(R5)—N(R6)(R7), wherein R1, R2, R3, R4, R5, R6 and R7 are each independently hydrogen, halogen, amino, tri-methylsilyl or C1-C20 hydrocarbyl, preferably straight-chain or branched C1-C10 alkyl, phenyl, C6-C20 aryl or C6-C20 alkyl-substituted phenyl.
摘要翻译： 本发明涉及一种催化剂组合物和用于乙烯低聚以制备过程1-己烯或1-辛烯，worin催化剂组合物包含的铬化合物; 在式（R 1）（R 2）P N（R 3）-N（R 4）P（R 5）-N（R6）（R7），的配体NPNPN worin R1，R2，R3，R4，R5，R6和 R7各自独立地是氢，卤素，氨基，三甲基甲硅烷或C1-C20烃基，优选直链或支链C1-C10烷基，苯基，C6-C20芳基或C6-C20烷基取代的苯基。
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10.发明公开METALATED PNPNH LIGAND, CATALYST COMPOSITION AND USE THEREOF IN THE OLIGOMERIZATION OF ETHYLENE 审中-公开METALLIERTER PNPNH-LIGAND，KATALYSATORZUSAMMENSETZUNG UND VERWENDUNG DAVON BEI DER OLIGOMERISIERUNG VON ETHYLEN
公开(公告)号：EP2953717A1
公开(公告)日：2015-12-16
申请号：EP14707241.7
申请日：2014-02-11
发明人： AL-HAZMI, Mohammed H, , ALQAHTANI, Abdullah , ROSENTHAL, Uwe , MULLER, Bernd , PEULECKE, Normen , HARFF, Marco , WOHL, Anina , MEISWINKEL, Andreas , BOLT, Heinz , MULLER, Wolfgang
CPC分类号： C07C2/30 , B01J31/0231 , B01J31/0239 , B01J31/0271 , B01J31/143 , B01J31/1885 , B01J2231/20 , B01J2531/0205 , B01J2531/11 , B01J2531/22 , B01J2531/26 , B01J2531/31 , B01J2531/62 , C07C2/36 , C07C2527/10 , C07C2531/14 , C07C2531/24 , C07F9/5004 , C07F9/5045 , C07F9/5054 , C07F11/00 , Y02P20/52 , C07C11/107
摘要： A process for oligomerization of ethylene, comprising subjecting a catalyst composition to a gas phase of ethylene and conducting an oligomerization, wherein the catalyst composition comprises (a) a chromium compound, (b) a metalated PNPN-H ligand, and (c) an activator or cocatalyst, pref. Et3AI; and the catalyst composition as such, as well as a metalated PNPN-H ligand and a method to obtain it.
摘要翻译： 本发明涉及一种乙烯低聚方法，包括使催化剂组合物进行乙烯气相并进行低聚反应，其中催化剂组合物包含（a）铬化合物，（b）金属化PNPNH配体和（ c）活化剂或助催化剂， Et3Al; 催化剂组合物以及金属化PNPNH配体以及获得它的方法。
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