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1.发明授权A PROCESS FOR THE REMOVAL OF SO2, HCN AND H2S AND OPTIONALLY COS, CS2 AND NH3 FROM A GAS STREAM 有权程序以清除，HCN和H2S和可选COS，CS2和NH3从气流中
公开(公告)号：EP1628744B1
公开(公告)日：2008-07-09
申请号：EP04741672.2
申请日：2004-05-28
发明人： VAN GRINSVEN, Petrus, Franciscus, Antonius , KIJLSTRA, Wiebe, Sjoerd , ROOS, Inge , SMIT, Cornelis, Jacobus
CPC分类号： B01D53/8621 , B01D53/1425 , B01D53/1468 , B01D53/8603 , C10K1/12 , C10K1/34 , C10K3/00 , Y10S423/17
摘要： The invention relates to a process for the removal of S02, HCN and H2S and optionally one or more compounds from the group of COS, CS2 and NH3 from a first gas stream, which process comprises the steps of: (a) removing S02 from the first gas stream by contacting the first gas stream in a hydrogenation zone with a hydrogenation catalyst in the presence of hydrogen to obtain a second gas stream; (b) removing HCN and optionally COS and/or CS2 from the second gas stream obtained in step (a) by contacting the second gas stream in a hydrolysis zone with a hydrolysis catalyst in the presence of water to obtain a third gas stream; (c) removing NH3 from the third gas stream by contacting the third gas stream in a NH3-removal zone with an aqueous acidic washing liquid to obtain an ammonium-comprising aqueous stream and a fourth gas stream; (d) removing H2S from the fourth gas stream by contacting the fourth gas stream in a H2S-removal zone with an aqueous alkaline washing liquid to obtain a H2S-depleted gas stream and a hydrogensulphide-comprising aqueous stream; (e) contacting the hydrogensulphide-comprising aqueous stream obtained in step (d) with sulphide-oxidizing bacteria in the presence of oxygen in an oxidation reactor to obtain a sulphur slurry and a regenerated aqueous alkaline washing liquid; (f) separating at least part of the sulphur slurry obtained in step (e) from the regenerated aqueous alkaline washing liquid and; (g) recycling regenerated aqueous alkaline washing liquid obtained in step (e) to the H2S-removal zone in step (d).
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公开(公告)号：EP1836283A1
公开(公告)日：2007-09-26
申请号：EP05847516.1
申请日：2005-12-29
发明人： ANSORGE, Joachim , BILTON, Scott , VAN DER PLOEG, Hendrik Jan , SMIT, Cornelis, Jacobus , ROUTIER, Arnold, Marcel
CPC分类号： C10G1/002 , C01B3/16 , C01B3/22 , C01B3/52 , C01B2203/0415 , C01B2203/0475 , C01B2203/0485 , C01B2203/062 , C10G2/30 , C10G2/32 , C10J3/00 , C10J2300/093 , C10J2300/1618 , C10J2300/1659 , C10J2300/1823 , C10K3/04 , C10K3/06
摘要： A method of increasing the hydrogen/carbon monoxide (H2/CO) ratio in a syngas stream derived from a carbonaceous fuel including coal, brown coal, peat, and heavy residual oil fractions, preferably coal. The fuel-derived syngas stream is divided into at least two sub-streams, one of which undergoes a catalytic water shift conversion reaction. The so-obtained converted sub-stream is combined with the non-converted sub-stream(s) to form a second syngas stream with an increased H2/CO ratio. The method of the present invention can provide a syngas with a H2/CO ratio more suitable for efficient hydrocarbon synthesis carried out on a given catalyst, such as in one or more Fischer-Tropsch reactors, as well as being able to accommodate variation in the H2/CO ratio of syngas formed from different qualities of feedstock fuels.
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3.发明公开A PROCESS FOR THE REMOVAL OF SO sb 2 /sb , HCN AND H sb 2 /sb S AND OPTIONALLY COS, CS sb 2 /sb AND NH sb 3 /sb FROM A GAS STREAM 有权程序以清除，HCN和H2S和可选COS，CS2和NH3从气流中
公开(公告)号：EP1628744A1
公开(公告)日：2006-03-01
申请号：EP04741672.2
申请日：2004-05-28
发明人： VAN GRINSVEN, Petrus, Franciscus, Antonius , KIJLSTRA, Wiebe, Sjoerd , ROOS, Inge , SMIT, Cornelis, Jacobus
CPC分类号： B01D53/8621 , B01D53/1425 , B01D53/1468 , B01D53/8603 , C10K1/12 , C10K1/34 , C10K3/00 , Y10S423/17
摘要： The invention relates to a process for the removal of S02, HCN and H2S and optionally one or more compounds from the group of COS, CS2 and NH3 from a first gas stream, which process comprises the steps of: (a) removing S02 from the first gas stream by contacting the first gas stream in a hydrogenation zone with a hydrogenation catalyst in the presence of hydrogen to obtain a second gas stream; (b) removing HCN and optionally COS and/or CS2 from the second gas stream obtained in step (a) by contacting the second gas stream in a hydrolysis zone with a hydrolysis catalyst in the presence of water to obtain a third gas stream; (c) removing NH3 from the third gas stream by contacting the third gas stream in a NH3-removal zone with an aqueous acidic washing liquid to obtain an ammonium-comprising aqueous stream and a fourth gas stream; (d) removing H2S from the fourth gas stream by contacting the fourth gas stream in a H2S-removal zone with an aqueous alkaline washing liquid to obtain a H2S-depleted gas stream and a hydrogensulphide-comprising aqueous stream; (e) contacting the hydrogensulphide-comprising aqueous stream obtained in step (d) with sulphide-oxidizing bacteria in the presence of oxygen in an oxidation reactor to obtain a sulphur slurry and a regenerated aqueous alkaline washing liquid; (f) separating at least part of the sulphur slurry obtained in step (e) from the regenerated aqueous alkaline washing liquid and; (g) recycling regenerated aqueous alkaline washing liquid obtained in step (e) to the H2S-removal zone in step (d).
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公开(公告)号：EP1094881B1
公开(公告)日：2004-05-26
申请号：EP99932872.7
申请日：1999-07-05
CPC分类号： B01D53/02 , B01D53/04 , B01D53/46 , B01D2253/108 , B01D2253/1085 , B01D2253/30 , B01D2253/308 , B01D2253/311 , B01J20/08 , B01J20/103 , B01J20/183 , B01J20/28014 , B01J20/2803 , B01J20/28069 , B01J20/28078 , C01B3/56 , C01B2203/043 , C01B2203/0465 , C01B2203/0475 , C01B2203/048 , C01B2203/0485 , C10K1/32 , Y10S95/902
摘要： Process for the removal of metal carbonyl from gaseous streams in the presence of hydrogen sulphide and/or water using a hydrophobic porous adsorbent with an accessible pore volume for pore sizes between 0.55 and 4 nm of at least 0.005 ml/g.
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