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公开(公告)号：EP2021278A1
公开(公告)日：2009-02-11
申请号：EP07729065.8
申请日：2007-05-14
摘要： The invention provides a process for the manufacture of carbon disulphide comprising supplying a molecular oxygen-containing gas and a feedstock comprising a hydrocarbonaceous compound to a reaction zone containing a liquid elemental sulphur phase and reacting, in the liquid sulphur phase, at a temperature in the range of from 300 to 750 °C, the hydrocarbonaceous compound with elemental sulphur to form carbon disulphide and hydrogen sulphide and oxidising at least part of the hydrogen sulphide formed to elemental sulphur and water. The invention further provides the use of a liquid stream comprising carbon disulphide, hydrogen sulphide and carbonyl sulphide obtainable such process for enhanced oil recovery.
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公开(公告)号：EP1965918A1
公开(公告)日：2008-09-10
申请号：EP06841356.6
申请日：2006-12-14
IPC分类号： B01J37/00 , C07C1/04 , B01J35/00 , B01J23/75 , B01J37/18 , B01J23/847 , B01J23/889 , B01J23/89
CPC分类号： B01J35/002 , B01J23/75 , B01J23/8472 , B01J23/889 , B01J23/8913 , B01J37/0018 , B01J37/0036 , B01J37/18 , C10G2/33 , C10G2/331
摘要： A process for the preparation of a catalyst or catalyst precursor, comprising the steps of : (a) admixing: (i) a catalytically active metal or metal compound (ii) a carrier material (iii) a gluing agent; and (iv) optionally one or more promoters, and /or one or more co-catalysts; (b) forming the mixture of step (a) ; and (c) drying the product of step (b) for more than 5 hours at a temperature up to 100 C to form the catalyst or catalyst precursor. The catalyst material mixture does not need to be calcined after forming to achieve the required minimum strength for use in a suitable reaction, such as Fischer Tropsch.
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3.发明授权
公开(公告)号：EP1581601B1
公开(公告)日：2008-08-13
申请号：EP03813153.8
申请日：2003-12-16
摘要： A process for the catalytic selective oxidation of sulphur compounds in a hydrocarbonaceous feedstock to sulphur dioxide, wherein a gaseous feed mixture of the hydrocarbonaceous feedstock and a molecular-oxygen containing gas is contacted with a catalyst at a temperature of at most 500 °C, the catalyst comprising a group VIII noble metal on a catalyst carrier, wherein the oxygen-to-carbon ratio of the feed mixture is below 0.15.
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公开(公告)号：EP1667933B1
公开(公告)日：2010-07-21
申请号：EP04787232.0
申请日：2004-09-28
CPC分类号： C01B17/0469
摘要： A process for the selective oxidation of hydrogen sulphide in a hydrogen sulphide containing feed gas to elemental sulphur, wherein the hydrogen sulphide containing feed gas (3), an inert liquid medium (5), and a molecular-Oxygen containing gas (4) are supplied to a reaction zone (1) comprising at least one catalytic zone (2) comprising an oxidation catalyst to form elemental sulphur and a gaseous stream depleted in hydrogen sulphide (8), in which process the oxidation catalyst. of each catalytic zone (2) is contacted with hydrogen sulphide and/or molecular-oxygen in the presence of inert liquid medium at a temperature in the range of from 120 to 160 oC, under such conditions that the elemental sulphur formed is essentially in liquid form and is removed from the reaction zone with the inert liquid medium.
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公开(公告)号：EP1863744B1
公开(公告)日：2009-09-30
申请号：EP06708819.5
申请日：2006-03-29
发明人： REYNHOUT, Marinus Johannes , MESTERS, Carolus Matthias Anna Maria , VERBIST, Guy Lode Magda Maria
CPC分类号： C04B28/36 , C01B17/0216 , C01B17/046 , C01B17/0469 , C04B14/06 , C04B24/00 , C04B40/0259
摘要： The invention provides a process for preparing a sulphur cement product comprising the following steps: (a) selectively oxidising hydrogen sulphide to elemental sulphur by contacting, in a reaction zone, a hydrogen sulphide containing feed gas and a molecular-oxygen containing gas with a particulate oxidation catalyst under selective oxidation conditions; (b) discharging a stream comprising liquid and/or solid elemental sulphur and particulate oxidation catalyst from the reaction zone; (c) admixing the stream comprising elemental sulphur and particulate oxidation catalyst with at least any one of elemental sulphur, a sulphur cement filler, a sulphur cement modifier, or aggregate at a temperature at which sulphur is molten; (d) solidifying the mixture obtained in step (c) by cooling it to a temperature below the melting temperature of sulphur to obtain the sulphur cement product. The invention further provides the use of a stream comprising elemental sulphur and particulate oxidation catalyst for preparing a sulphur cement product, which stream is obtained in selective oxidation step (a) of such process.
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公开(公告)号：EP2018349A1
公开(公告)日：2009-01-28
申请号：EP07729062.5
申请日：2007-05-14
摘要： The invention provides a process for the manufacture of carbon disulphide comprising supplying a feedstock comprising a hydrocarbonaceous compound to a reaction zone containing a liquid elemental sulphur phase and reacting, in the liquid sulphur phase, at a temperature in the range of from 350 to 750 °C and a pressure in the range of from 3 to 200 bar (absolute) and in the absence of a catalyst, the hydrocarbonaceous compound with elemental sulphur in the absence of molecular oxygen. The invention further provides the use of a liquid stream comprising carbon disulphide and hydrogen sulphide obtainable by such process for enhanced oil recovery.
摘要翻译： 本发明提供了一种制造二硫化碳的方法，包括将包含含烃化合物的原料提供给含有液态元素硫相的反应区，并在液相硫相中在350至750℃ 在不存在催化剂的情况下，在不存在分子氧的情况下，所述含烃化合物与元素硫反应。 本发明进一步提供了包含二硫化碳和硫化氢的液体物流可通过这种方法获得，用于提高石油采收率。
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7.发明公开
公开(公告)号：EP1581601A1
公开(公告)日：2005-10-05
申请号：EP03813153.8
申请日：2003-12-16
摘要： A process for the catalytic selective oxidation of sulphur compounds in a hydrocarbonaceous feedstock to sulphur dioxide, wherein a gaseous feed mixture of the hydrocarbonaceous feedstock and a molecular-oxygen containing gas is contacted with a catalyst at a temperature of at most 500 °C, the catalyst comprising a group VIII noble metal on a catalyst carrier, wherein the oxygen-to-carbon ratio of the feed mixture is below 0.15.
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公开(公告)号：EP3774644A1
公开(公告)日：2021-02-17
申请号：EP19716141.7
申请日：2019-04-04
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公开(公告)号：EP2362849A1
公开(公告)日：2011-09-07
申请号：EP09756762.2
申请日：2009-11-26
CPC分类号： B01D53/8612 , B01D2251/10 , B01D2255/20707 , B01D2256/16 , B01D2256/24 , B01D2257/304 , C01B17/0469
摘要： The present invention provides a process for the selective oxidation of hydrogen sulphide in a hydrogen sulphide-containing hydrocarbon and/or hydrogen feed gas to elemental sulphur, wherein the hydrogen sulphide- containing hydrocarbon and/or hydrogen feed gas and a sulphur dioxide-containing gas are supplied to a reaction zone comprising at least one catalytic zone comprising a TiO
2 -comprising catalyst, to form elemental sulphur and a gaseous stream depleted in hydrogen sulphide, in which process the Tiθ2-comprising catalyst of the at least one catalytic zone is contacted with hydrogen sulphide and/or sulphur dioxide at elevated pressure and at a temperature in the range of from 120 and below 160 °C, under such conditions that the elemental sulphur formed is essentially in liquid form, and wherein at least part of the sulphur dioxide comprising gas is obtained by combusting elemental sulphur to obtain a mixture of sulphur dioxide and nitrogen and concentrating the mixture of sulphur dioxide to increase the sulphur dioxide concentration.-
公开(公告)号：EP1866061A1
公开(公告)日：2007-12-19
申请号：EP06725337.7
申请日：2006-03-28
CPC分类号： C01B17/54 , B01D53/8612 , C01B17/0469 , C01B17/05
摘要： The invention provides a process for producing a gas stream depleted of H2S from a feed gas stream comprising H2S, the process comprising the steps of: (a) selectively oxidizing H2S by supplying the feed gas stream comprising H2S, an inert liquid medium and a molecular-oxygen comprising gas stream to a reaction zone comprising at least one catalytic zone comprising an oxidation catalyst and contacting the oxidation catalyst of each catalytic zone with the feed gas stream and/or the molecular-oxygen comprising gas stream in the presence of inert liquid medium at a temperature in the range of from 120 to 160 °C to form elemental sulphur and the gas stream depleted of H2S, under such conditions that the elemental sulphur formed is essentially in liquid form and is removed from the reaction zone with inert liquid medium to obtain a liquid stream comprising inert liquid medium and essentially liquid elemental sulphur; (b) optionally separating the liquid stream obtained in step (a) into a first liquid phase enriched in inert liquid medium and a second liquid phase enriched in liquid elemental sulphur; (c) combusting at least part of the liquid stream obtained in step (a) or at least part of the second liquid phase obtained in step (b) to form a fluid stream comprising sulphur dioxide.
摘要翻译： 本发明提供了一种从包含H 2 S的进料气流生产贫含H 2 S的气流的方法，所述方法包括以下步骤：（a）通过供应包含H 2 S，惰性液体介质和分子的进料气流来选择性氧化H 2 S 将包含氧气的气流送入反应区，该反应区包含至少一个包含氧化催化剂的催化区，并在惰性液体介质存在下使每个催化区的氧化催化剂与进料气流和/或含分子氧气流接触 在120-160℃的温度下形成元素硫和贫含H2S的气流，在这样的条件下，形成的元素硫基本上为液体形式，并且用惰性液体介质从反应区除去 获得包含惰性液体介质和基本上液体元素硫的液体流; （b）任选地将步骤（a）中获得的液体物流分离成富含惰性液体介质的第一液相和富含液体元素硫的第二液相; （c）燃烧步骤（a）中获得的至少一部分液体物流或步骤（b）中获得的至少部分第二液体物流以形成包含二氧化硫的流体物流。
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