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1.发明公开Process for the removal of hydrogen sulfide from a gas stream 有权瓦斯特罗姆（Verstahren zur Entfernung von Schwefelwasserstoff aus einem Gasstrom）
公开(公告)号：EP2594328A1
公开(公告)日：2013-05-22
申请号：EP11189978.7
申请日：2011-11-21
发明人： Heisel, Michael
CPC分类号： B01D53/002 , B01D53/8612 , B01D53/869 , B01D2251/102 , B01D2251/11 , B01D2255/20707 , B01D2255/20746 , B01D2255/20753 , B01D2255/20769 , B01D2255/2092 , B01D2256/24 , B01D2258/05 , C01B3/58 , C01B17/0404 , C01B17/0469 , C01B2203/045 , C01B2203/0485 , C07C7/17 , C10L3/103
摘要： The application relates to a process for the removal of hydrogen sulfide from a gas stream by catalytic direct oxidation without employing the combustion step of a Claus process. The process is particularly suitable for desulfurization of gas streams that contain hydrogen and allows sulfur recovery efficiency of better than 99%
摘要翻译： 本申请涉及通过催化直接氧化从气流中除去硫化氢的方法，而不采用克劳斯法的燃烧步骤。 该方法特别适用于含氢气流的脱硫，硫回收效率优于99％
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公开(公告)号：EP2362849A1
公开(公告)日：2011-09-07
申请号：EP09756762.2
申请日：2009-11-26
CPC分类号： B01D53/8612 , B01D2251/10 , B01D2255/20707 , B01D2256/16 , B01D2256/24 , B01D2257/304 , C01B17/0469
摘要： The present invention provides a process for the selective oxidation of hydrogen sulphide in a hydrogen sulphide-containing hydrocarbon and/or hydrogen feed gas to elemental sulphur, wherein the hydrogen sulphide- containing hydrocarbon and/or hydrogen feed gas and a sulphur dioxide-containing gas are supplied to a reaction zone comprising at least one catalytic zone comprising a TiO
2 -comprising catalyst, to form elemental sulphur and a gaseous stream depleted in hydrogen sulphide, in which process the Tiθ2-comprising catalyst of the at least one catalytic zone is contacted with hydrogen sulphide and/or sulphur dioxide at elevated pressure and at a temperature in the range of from 120 and below 160 °C, under such conditions that the elemental sulphur formed is essentially in liquid form, and wherein at least part of the sulphur dioxide comprising gas is obtained by combusting elemental sulphur to obtain a mixture of sulphur dioxide and nitrogen and concentrating the mixture of sulphur dioxide to increase the sulphur dioxide concentration.-
公开(公告)号：EP1866061A1
公开(公告)日：2007-12-19
申请号：EP06725337.7
申请日：2006-03-28
CPC分类号： C01B17/54 , B01D53/8612 , C01B17/0469 , C01B17/05
摘要： The invention provides a process for producing a gas stream depleted of H2S from a feed gas stream comprising H2S, the process comprising the steps of: (a) selectively oxidizing H2S by supplying the feed gas stream comprising H2S, an inert liquid medium and a molecular-oxygen comprising gas stream to a reaction zone comprising at least one catalytic zone comprising an oxidation catalyst and contacting the oxidation catalyst of each catalytic zone with the feed gas stream and/or the molecular-oxygen comprising gas stream in the presence of inert liquid medium at a temperature in the range of from 120 to 160 °C to form elemental sulphur and the gas stream depleted of H2S, under such conditions that the elemental sulphur formed is essentially in liquid form and is removed from the reaction zone with inert liquid medium to obtain a liquid stream comprising inert liquid medium and essentially liquid elemental sulphur; (b) optionally separating the liquid stream obtained in step (a) into a first liquid phase enriched in inert liquid medium and a second liquid phase enriched in liquid elemental sulphur; (c) combusting at least part of the liquid stream obtained in step (a) or at least part of the second liquid phase obtained in step (b) to form a fluid stream comprising sulphur dioxide.
摘要翻译： 本发明提供了一种从包含H 2 S的进料气流生产贫含H 2 S的气流的方法，所述方法包括以下步骤：（a）通过供应包含H 2 S，惰性液体介质和分子的进料气流来选择性氧化H 2 S 将包含氧气的气流送入反应区，该反应区包含至少一个包含氧化催化剂的催化区，并在惰性液体介质存在下使每个催化区的氧化催化剂与进料气流和/或含分子氧气流接触 在120-160℃的温度下形成元素硫和贫含H2S的气流，在这样的条件下，形成的元素硫基本上为液体形式，并且用惰性液体介质从反应区除去 获得包含惰性液体介质和基本上液体元素硫的液体流; （b）任选地将步骤（a）中获得的液体物流分离成富含惰性液体介质的第一液相和富含液体元素硫的第二液相; （c）燃烧步骤（a）中获得的至少一部分液体物流或步骤（b）中获得的至少部分第二液体物流以形成包含二氧化硫的流体物流。
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公开(公告)号：EP1708964A2
公开(公告)日：2006-10-11
申请号：EP05704553.6
申请日：2005-01-14
发明人： BORSBOOM, Johannes , VAN WARNERS, Anne , VAN NISSELROOIJ, Petrus F. M. T. , VAN YPEREN, Renee , CHOPRA, Vijay, Kumar
IPC分类号： C01B17/04
CPC分类号： C01B17/0439 , C01B17/0404 , C01B17/0465 , C01B17/0469
摘要： The invention relates to a process for the recovery of sulfur from a hydrogen sulfide containing gas, comprising (a) Oxidizing part of the hydrogen sulfide in a gaseous stream with oxygen or an oxygen containing gas in an oxidation stage to sulfur dioxide, and thereafter reacting the major part of the remaining hydrogen sulfide and the major part of sulfur dioxide to elemental sulfur and water, (b) reacting the product gas of oxidation stage a) in at least three catalytic reaction systems and c. selectively oxidizing H2S in the gas leaving stage b (in particular leaving) the (last) sub-dewpoint Claus reactor) to elemental sulfur, preferably employing for this purpose a catalytic stage including a selective oxidation catalyst, which is substantially insensitive to the presence of water vapor in the gas stream and is ineffective in promoting the establishment of the Claus equilibrium: 2 H2S + SO2 2 H2O + 3/n Sn.
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公开(公告)号：EP1667933A1
公开(公告)日：2006-06-14
申请号：EP04787232.0
申请日：2004-09-28
CPC分类号： C01B17/0469
摘要： A process for the selective oxidation of hydrogen sulphide in a hydrogen sulphide containing feed gas to elemental sulphur, wherein the hydrogen sulphide containing feed gas (3), an inert liquid medium (5), and a molecular-Oxygen containing gas (4) are supplied to a reaction zone (1) comprising at least one catalytic zone (2) comprising an oxidation catalyst to form elemental sulphur and a gaseous stream depleted in hydrogen sulphide (8), in which process the oxidation catalyst. of each catalytic zone (2) is contacted with hydrogen sulphide and/or molecular-oxygen in the presence of inert liquid medium at a temperature in the range of from 120 to 160 oC, under such conditions that the elemental sulphur formed is essentially in liquid form and is removed from the reaction zone with the inert liquid medium.
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6.发明授权Verfahren zur Entfernung von Schwefelwasserstoff aus kohlenwasserstoffhaltigen Gasgemischen 失效从含有碳氢化合物的气体混合物中消除硫化氢的方法
公开(公告)号：EP0045865B1
公开(公告)日：1983-10-12
申请号：EP81105649.8
申请日：1981-07-18
CPC分类号： B01D53/12 , B01D53/04 , B01D53/8612 , B01D2253/102 , B01D2253/306 , B01D2253/311 , B01D2256/24 , B01D2257/304 , B01D2259/402 , B01D2259/404 , C01B17/0469
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公开(公告)号：EP1708964B1
公开(公告)日：2011-03-02
申请号：EP05704553.6
申请日：2005-01-14
发明人： BORSBOOM, Johannes , VAN WARNERS, Anne , VAN NISSELROOIJ, Petrus F. M. T. , VAN YPEREN, Renee , CHOPRA, Vijay, Kumar
IPC分类号： C01B17/04
CPC分类号： C01B17/0439 , C01B17/0404 , C01B17/0465 , C01B17/0469
摘要： The invention relates to a process for the recovery of sulfur from a hydrogen sulfide containing gas, comprising (a) Oxidizing part of the hydrogen sulfide in a gaseous stream with oxygen or an oxygen containing gas in an oxidation stage to sulfur dioxide, and thereafter reacting the major part of the remaining hydrogen sulfide and the major part of sulfur dioxide to elemental sulfur and water, (b) reacting the product gas of oxidation stage a) in at least three catalytic reaction systems and c. selectively oxidizing H2S in the gas leaving stage b (in particular leaving) the (last) sub-dewpoint Claus reactor) to elemental sulfur, preferably employing for this purpose a catalytic stage including a selective oxidation catalyst, which is substantially insensitive to the presence of water vapor in the gas stream and is ineffective in promoting the establishment of the Claus equilibrium: 2 H2S + SO2 2 H2O + 3/n Sn.
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公开(公告)号：EP1863744A1
公开(公告)日：2007-12-12
申请号：EP06708819.5
申请日：2006-03-29
发明人： REYNHOUT, Marinus Johannes , MESTERS, Carolus Matthias Anna Maria , VERBIST, Guy Lode Magda Maria
CPC分类号： C04B28/36 , C01B17/0216 , C01B17/046 , C01B17/0469 , C04B14/06 , C04B24/00 , C04B40/0259
摘要： The invention provides a process for preparing a sulphur cement product comprising the following steps: (a) selectively oxidising hydrogen sulphide to elemental sulphur by contacting, in a reaction zone, a hydrogen sulphide containing feed gas and a molecular-oxygen containing gas with a particulate oxidation catalyst under selective oxidation conditions; (b) discharging a stream comprising liquid and/or solid elemental sulphur and particulate oxidation catalyst from the reaction zone; (c) admixing the stream comprising elemental sulphur and particulate oxidation catalyst with at least any one of elemental sulphur, a sulphur cement filler, a sulphur cement modifier, or aggregate at a temperature at which sulphur is molten; (d) solidifying the mixture obtained in step (c) by cooling it to a temperature below the melting temperature of sulphur to obtain the sulphur cement product. The invention further provides the use of a stream comprising elemental sulphur and particulate oxidation catalyst for preparing a sulphur cement product, which stream is obtained in selective oxidation step (a) of such process.
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9.发明公开
公开(公告)号：EP1590069A1
公开(公告)日：2005-11-02
申请号：EP04707694.8
申请日：2004-02-03
IPC分类号： B01D53/86 , B01J23/745 , B01J35/10 , C01B17/04
CPC分类号： B01J35/10 , B01D53/8612 , B01J21/08 , B01J23/745 , B01J35/1066 , B01J35/108 , C01B17/04 , C01B17/0465 , C01B17/0469
摘要： The present invention relates to a supported catalyst system for the removal of sulfur compounds, such as H2S comprising a metal compound on a support material, wherein in said support material, the sum of the pore volume present in micro-pores and in mesopores is less than 0.20 ml per gram of catalyst, and wherein the pore volume V-Hg, as measured by mercury intrusion porosimetry, is at least 0.30 ml/g. The invention further relates to processes for desulfurization of gases containing sulfur compounds, such as H2S in which this catalyst system is used.
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10.发明公开Recovery of sulfur from a hydrogen sulfide containing gas 审中-公开天然气（Wiederegewinnung von Schwefel aus einem schwefelwasserstoffenthaltenden Gas
公开(公告)号：EP1555241A1
公开(公告)日：2005-07-20
申请号：EP04075104.2
申请日：2004-01-16
发明人： Borsboom, Johannes , van Nisselrooij, Petrus Fransciscus Maria Theresia , van Warners, Anne , van Yperen, Renee , Chopra, Vijay Kumar
IPC分类号： C01B17/04
CPC分类号： C01B17/0439 , C01B17/0404 , C01B17/0465 , C01B17/0469
摘要： The invention relates to a process for the recovery of sulfur from a hydrogen sulfide containing gas, comprising:
a. Oxidizing part of the hydrogen sulfide in a gaseous stream with oxygen or an oxygen containing gas in an oxidation stage to sulfur dioxide, and thereafter reacting the major part of the remaining hydrogen sulfide and the major part of sulfur dioxide to elemental sulfur and water,
b. reacting the product gas of oxidation stage a) in at least three catalytic reaction systems
and
c. selectively oxidizing H 2 S in the gas leaving stage b (in particular leaving) the (last) sub-dewpoint Claus reactor) to elemental sulfur, preferably employing for this purpose a catalytic stage including a selective oxidation catalyst, which is substantially insensitive to the presence of water vapor in the gas stream and is ineffective in promoting the establishment of the Claus equilibrium: 2 H 2 S + SO 2 ⇔ 2 H 2 O + 3/n S n .摘要翻译： 本发明涉及从含硫化氢的气体中回收硫的方法，包括：a。 在氧化阶段将氧气或含氧气体的气态物流中的一部分硫化氢氧化成二氧化硫，然后将剩余硫化氢和主要部分二氧化硫的主要部分与元素硫和水反应，b 。 使氧化阶段a）的产物气体在至少三个催化反应体系中反应，c。 选择性地将离开阶段b的气体（特别是离开）（最后）次级露点克劳斯反应器）中的H 2 S氧化成元素硫，优选为此目的使用包括选择性氧化催化剂的催化级，其对于存在 气流中的水汽，并且促进了克劳斯平衡的建立无效：2 H2S + SO2 <2> H2O + 3 / n Sn。
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