公开(公告)号：EP1910427A1

公开(公告)日：2008-04-16

申请号：EP05856549.0

申请日：2005-10-14

申请人： SK Energy Co., Ltd.

发明人： WOO, Tae Woo ,  OK, Myung Ahn ,  HAHN, Jong Sok ,  LEE, Mal Ou ,  KANG, Sang Ook ,  KO, Sung Bo ,  KIM, Tae Jin ,  KIM, Sung Kwan

IPC分类号： C08F4/64

CPC分类号： C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F2420/03 ,  C08F4/6592 ,  C08F2500/12 ,  C08F210/14

摘要： Disclosed is an arylphenoxy catalyst system for producing an ethylene homopolymer or copolymers of ethylene and α-olefins, and a method of producing an ethylene homopolymer or copolymers of ethylene and α-olefins having a high molecular weight under a high temperature solution polymerization condition using the same. The catalyst system includes a 4 group arylphenoxy-based transition metal catalyst and an aluminoxane cocatalyst or a boron compound cocatalyst. In the transition metal catalyst, a cyclopentadiene derivative and arylphenoxide as fixed ligands are located around the 4th group transition metal, arylphenoxide is substituted with at least one aryl derivative and is located at the ortho position thereof, and the ligands are not crosslinked to each other. The catalyst includes an environmentally-friendly raw material, synthesis of the catalyst is economical, and thermal stability of the catalyst is excellent. It is useful for producing an ethylene homopolymer or copolymers of ethylene and α-olefins having various physical properties in commercial polymerization processes.

公开(公告)号：EP2076551A1

公开(公告)日：2009-07-08

申请号：EP06799305.5

申请日：2006-10-18

申请人： SK Energy Co., Ltd.

发明人： WOO, Tae Woo ,  OK, Myung Ahn ,  HAHN, Jong Sok ,  LEE, Mal Ou ,  KANG, Sang Ook ,  KO, Sung Bo ,  KIM, Tae Jin ,  KIM, Sung Kwan

IPC分类号： C08F4/642 ,  C08F4/646 ,  C08F4/649 ,  C08F10/00

CPC分类号： C08F10/02 ,  C08F4/65908 ,  C08F4/65912 ,  C08F110/02 ,  C08F210/16 ,  C08F2420/04 ,  C08F4/6592 ,  C08F2500/12 ,  C08F210/14

摘要： Disclosed is an arylphenoxy catalyst system for producing an ethylene homopolymer or copolymers of ethylene and α-olefins, and a method of producing an ethylene homopolymer or copolymers of ethylene and α-olefins having a high molecular weight under a high temperature solution polymerization condition using the same. The catalyst system includes a group 4 arylphenoxy-based transition metal catalyst and an aluminoxane cocatalyst or a boron compound cocatalyst. In the transition metal catalyst, a cyclopentadiene derivative and arylphenoxide as fixed ligands are located around the group 4 transition metal, arylphenoxide is substituted with at least one aryl derivative and at least one halogen compound, and is located at the ortho position thereof, and the ligands are not crosslinked to each other. The catalyst includes environmentally friendly raw materials, synthesis of the catalyst is economical, and thermal stability of the catalyst is excellent. It is useful for producing an ethylene homopolymer or copolymers of ethylene and α-olefins having various physical properties in commercial polymerization processes.