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公开(公告)号：EP3377563B1
公开(公告)日：2020-09-30
申请号：EP16797870.9
申请日：2016-11-16
申请人： SOLVAY SA
发明人： ABUSLEME, Julio A. , LAVASELLI, Matteo , HAMON, Christine , FRACHE, Alberto , BESANA, Giambattista , CAMINO, Giovanni , BRUSSEAU, Ségolène
IPC分类号： C08J5/22 , C08L27/16 , C08L71/02 , C08L83/12 , H01M8/1048 , C08K5/5415
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公开(公告)号：EP3022341B1
公开(公告)日：2019-07-03
申请号：EP14741836.2
申请日：2014-07-15
申请人： Solvay SA
发明人： ABUSLEME, Julio A. , BESANA, Giambattista , BASSI, Mattia , HAMON, Christine , GUALANDI, Chiara , FOCARETE, Maria Letizia , ZUCCHELLI, Andrea
IPC分类号： D01F6/32 , D01F6/48 , D01D5/00 , D04H1/728 , D04H1/4318 , D01F1/10 , C08G83/00 , C08F214/18
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公开(公告)号：EP3377563A1
公开(公告)日：2018-09-26
申请号：EP16797870.9
申请日：2016-11-16
申请人： SOLVAY SA
发明人： ABUSLEME, Julio A. , LAVASELLI, Matteo , HAMON, Christine , FRACHE, Alberto , BESANA, Giambattista , CAMINO, Giovanni , BRUSSEAU, Ségolène
IPC分类号： C08J5/22 , C08L27/16 , C08L71/02 , C08L83/12 , H01M8/1048 , C08K5/5415
摘要： The present invention pertains to a fluoropolymer hybrid organic/inorganic composite, to a film comprising said fluoropolymer hybrid organic/inorganic composite and to uses of said film in various applications, in particular in electrochemical and in photo-electrochemical applications.
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公开(公告)号：EP4041783A1
公开(公告)日：2022-08-17
申请号：EP20785982.8
申请日：2020-10-07
申请人： SOLVAY SA , Politecnico Di Torino
IPC分类号： C08F214/22 , C09D127/16 , C08J5/22 , H01M8/10
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公开(公告)号：EP3622011A1
公开(公告)日：2020-03-18
申请号：EP18722553.7
申请日：2018-05-08
申请人： Solvay SA
发明人： FRACHE, Alberto , ABUSLEME, Julio A. , CISTERNINO, Alberto , HAMON, Christine , BESANA, Giambattista , BRUSSEAU, Ségolène , LAVASELLI, Matteo , CAMINO, Giovanni
IPC分类号： C08J5/22 , B01D71/34 , C08L27/16 , C08L71/02 , H01M10/0525 , H01M10/0565
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公开(公告)号：EP2914647B1
公开(公告)日：2016-12-07
申请号：EP13779613.2
申请日：2013-10-22
申请人： Solvay SA
发明人： FRACHE, Alberto , TATA, Jennifer Katty , CAMINO, Giovanni , BESANA, Giambattista , ABUSLEME, Julio A.
CPC分类号： C08J5/00 , C08J3/201 , C08J3/2056 , C08J2327/16 , C08J2327/18 , C08K5/05
摘要： The invention pertains to a process for manufacturing a fluoropolymer hybrid organic/inorganic composite comprising: (i) partially hydrolyzing and/or polycondensing, in the presence of an aqueous medium, a metal compound of formula (I): X4-mAYim, wherein X is a hydrocarbon group, Y is a hydrolysable group selected from the group consisting of an alkoxy group, an acyloxy group and a hydroxyl group, A is a metal selected from the group consisting of Si, Ti and Zr, and m is an integer from 1 to 4, so as to obtain an aqueous medium comprising a pre-gelled metal compound comprising one or more inorganic domains consisting of ≡A-O-A≡ bonds and one or more residual hydrolysable groups Y [compound (M)], and then (ii) reacting in the molten state at least a fraction of hydroxyl groups of a functional fluoropolymer [polymer (F)] with at least a fraction of hydrolysable groups Y of said pre-gelled metal compound [compound (M)], so as to obtain a fluoropolymer hybrid organic/inorganic composite. The invention also pertains to uses of said fluoropolymer hybrid organic/inorganic composite in several applications.
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公开(公告)号：EP3900100A1
公开(公告)日：2021-10-27
申请号：EP19818084.6
申请日：2019-12-16
申请人： SOLVAY SA , Politecnico Di Torino
发明人： FRACHE, Alberto , SANTANGELETTA, Silvia , BATTEGAZZORE, Daniele , ABUSLEME, Julio A. , HAMON, Christine , BESANA, Giambattista , BRUSSEAU, Ségolène
IPC分类号： H01M10/0565 , H01M14/00
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公开(公告)号：EP3401356A1
公开(公告)日：2018-11-14
申请号：EP17305539.3
申请日：2017-05-12
申请人： Solvay SA
发明人： FRACHE, Alberto , ABUSLEME, Julio A. , CISTERNINO, Alberto , HAMON, Christine , BESANA, Giambattista , BRUSSEAU, Ségolène , LAVASELLI, Matteo , CAMINO, Giovanni
IPC分类号： C08J5/22 , B01D71/34 , C08L27/16 , C08L71/02 , H01M10/0525 , H01M10/0565
CPC分类号： C08J5/2237 , B01D67/0079 , B01D69/148 , B01D71/30 , C08J2327/16 , C08L27/16 , C08L71/02 , H01M10/0525 , H01M10/0565 , C08K5/5415
摘要： The present invention pertains to a fluoropolymer hybrid organic/inorganic composite, to a film comprising said fluoropolymer hybrid organic/inorganic composite and to uses of said film in various applications, especially in electrochemical and in photo-electrochemical applications.
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公开(公告)号：EP3022341A1
公开(公告)日：2016-05-25
申请号：EP14741836.2
申请日：2014-07-15
申请人： Solvay SA
发明人： ABUSLEME, Julio A. , BESANA, Giambattista , BASSI, Mattia , HAMON, Christine , GUALANDI, Chiara , FOCARETE, Maria Letizia , ZUCCHELLI, Andrea
IPC分类号： D01F6/32 , D01F6/48 , D01D5/00 , D04H1/728 , D04H1/4318 , D01F1/10 , C08G83/00 , C08F214/18
CPC分类号： D01F6/32 , B01D67/0079 , B01D71/32 , B01D71/76 , C08F214/18 , D01D5/003 , D01D5/0038 , D01F1/10 , D01F6/48 , D02J1/00 , D04H1/4318 , D04H1/728 , D10B2321/042 , D10B2321/08 , D10B2401/06 , D10B2401/061 , D10B2401/16 , D10B2505/00 , D10B2505/04 , H01M2/162 , H01M2/1686 , H01M10/052 , H01M10/0525
摘要： The present invention pertains to a process for manufacturing one or more fluoropolymer fibres, said process comprising the following steps: (i) providing a liquid composition [composition (C1)] comprising: —at least one fluoropolymer comprising at least one hydroxyl end group [polymer (FOH)L and—a liquid medium comprising at least one organic solvent [solvent (S)]; (ii) contacting the composition (C1) provided in step (i) with at least one metal compound [compound (M)] of formula (I) here below: X4-mAYm (I) wherein X is a hydrocarbon group, optionally comprising one or more functional groups, m is an integer from 1 to 4, A is a metal selected from the group consisting of Si, Ti and Zr, and Y is a hydrolysable group selected from the group consisting of an alkoxy group, an acyloxy group and a hydroxyl group, thereby providing a liquid composition [composition (C2)]; (iii) submitting to at least partial hydrolysis and/or polycondensation the composition (C2) provided in step (ii) thereby providing a liquid composition [composition (C3)] comprising at least one fluoropolymer hybrid organic/inorganic composite; (iv) processing the composition (C3) provided in step (iii) by electrospinning thereby providing one or more fluoropolymer fibres; (v) drying the fluoropolymer fibre(s) provided in step (iv); and (vi) optionally, submitting to compression the fluoropolymer fibre(s) provided in step (v) at a temperature comprised between 50° C. and 300° C. The invention also pertains to a process for the manufacture of said fluoropolymer fibre(s) and to uses of said fluoropolymer fibre(s) in various applications.
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公开(公告)号：EP2914647A1
公开(公告)日：2015-09-09
申请号：EP13779613.2
申请日：2013-10-22
申请人： Solvay SA
发明人： FRACHE, Alberto , TATA, Jennifer Katty , CAMINO, Giovanni , BESANA, Giambattista , ABUSLEME, Julio A.
CPC分类号： C08J5/00 , C08J3/201 , C08J3/2056 , C08J2327/16 , C08J2327/18 , C08K5/05
摘要： The invention pertains to a process for manufacturing a fluoropolymer hybrid organic/inorganic composite comprising: (i) partially hydrolyzing and/or polycondensing, in the presence of an aqueous medium, a metal compound of formula (I): X4-mAYim, wherein X is a hydrocarbon group, Y is a hydrolysable group selected from the group consisting of an alkoxy group, an acyloxy group and a hydroxyl group, A is a metal selected from the group consisting of Si, Ti and Zr, and m is an integer from 1 to 4, so as to obtain an aqueous medium comprising a pre-gelled metal compound comprising one or more inorganic domains consisting of ≡A-O-A≡ bonds and one or more residual hydrolysable groups Y [compound (M)], and then (ii) reacting in the molten state at least a fraction of hydroxyl groups of a functional fluoropolymer [polymer (F)] with at least a fraction of hydrolysable groups Y of said pre-gelled metal compound [compound (M)], so as to obtain a fluoropolymer hybrid organic/inorganic composite. The invention also pertains to uses of said fluoropolymer hybrid organic/inorganic composite in several applications.
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