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公开(公告)号:EP0204217A1
公开(公告)日:1986-12-10
申请号:EP86106932.6
申请日:1986-05-22
IPC分类号: C22B3/00 , C22B61/00 , C22B60/02 , C22B34/12 , C22B34/22 , C22B41/00 , C22B34/36 , C22B34/34
CPC分类号: C22B60/0273 , C22B3/24 , C22B60/0265 , C22B60/0269 , Y02P10/234 , Y10S423/14
摘要: Chelating agents on which metals such as uranium have been adsorbed are brought into contact with an eluent of aqueous solution containing reducing agents and basic compounds, until the metals are eluted. The elution is effected with large speed without degradation of the chelating agents. Preferred chelating agents are rather stable under basic conditions but not under acidic conditions, for example, those having = NOH group in their molecules. The reducing agents and basic compounds in the eluent are, for example, sulfurous acid or salts thereof and sodium hydroxide, respectively.
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公开(公告)号:EP0224209A3
公开(公告)日:1988-04-27
申请号:EP86116136
申请日:1986-11-21
IPC分类号: C22B03/00 , C22B58/00 , C22B60/02 , C22B34/34 , C22B26/00 , C22B59/00 , C22B34/24 , C22B34/36 , C22B11/04 , C22B61/00
CPC分类号: C01F11/005 , C01F17/0006 , C01G15/003 , C01G33/003 , C01G35/003 , C01G39/003 , C01G41/003 , C01G55/001 , C22B3/24 , C22B3/42 , C22B60/0265 , Y02P10/234
摘要: Rare metals are recovered in high yields by contacting a strongly acidic solution containing at least one rare metal selected from the group consisting of gallium, uranium, molybdenum, rubidium, cesium, strontium, yttrium, niobium, tantalum, tungsten, ruthenium, osmium, rhodium, iridium, palladium, platinum, thallium and europium with a chelate resin having at least one phosphorus atom-containing functional group selected from phosphine group, phosphonium salt group, phosphinic acid group, phosphinic acid ester group, phosphonic acid group, phosphonic acid ester group and metal salts of these acids.
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公开(公告)号:EP0224209B1
公开(公告)日:1993-03-17
申请号:EP86116136.2
申请日:1986-11-21
IPC分类号: C22B3/00 , C22B58/00 , C22B60/02 , C22B34/34 , C22B26/00 , C22B59/00 , C22B34/36 , C22B61/00
CPC分类号: C01F11/005 , C01F17/0006 , C01G15/003 , C01G33/003 , C01G35/003 , C01G39/003 , C01G41/003 , C01G55/001 , C22B3/24 , C22B3/42 , C22B60/0265 , Y02P10/234
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公开(公告)号:EP0204217B1
公开(公告)日:1989-09-13
申请号:EP86106932.6
申请日:1986-05-22
IPC分类号: C22B3/00 , C22B61/00 , C22B60/02 , C22B34/12 , C22B34/22 , C22B41/00 , C22B34/36 , C22B34/34
CPC分类号: C22B60/0273 , C22B3/24 , C22B60/0265 , C22B60/0269 , Y02P10/234 , Y10S423/14
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公开(公告)号:EP0224209A2
公开(公告)日:1987-06-03
申请号:EP86116136.2
申请日:1986-11-21
IPC分类号: C22B3/00 , C22B58/00 , C22B60/02 , C22B34/34 , C22B26/00 , C22B59/00 , C22B34/36 , C22B61/00
CPC分类号: C01F11/005 , C01F17/0006 , C01G15/003 , C01G33/003 , C01G35/003 , C01G39/003 , C01G41/003 , C01G55/001 , C22B3/24 , C22B3/42 , C22B60/0265 , Y02P10/234
摘要: Rare metals are recovered in high yields by contacting a strongly acidic solution containing at least one rare metal selected from the group consisting of gallium, uranium, molybdenum, rubidium, cesium, strontium, yttrium, niobium, tantalum, tungsten, ruthenium, osmium, rhodium, iridium, palladium, platinum, thallium and europium with a chelate resin having at least one phosphorus atom-containing functional group selected from phosphine group, phosphonium salt group, phosphinic acid group, phosphinic acid ester group, phosphonic acid group, phosphonic acid ester group and metal salts of these acids.
摘要翻译: 通过使含有至少一种选自镓,铀,钼,铷,铯,锶,钇,铌,钽,钨,钌,锇,铑等的至少一种稀有金属的强酸溶液接触,可以高收率地回收稀有金属。 铱,钯,铂,铊和铕与具有选自膦基,鏻盐基,次膦酸基,次膦酸酯基,膦酸基,膦酸酯基中的至少一个含磷原子的官能团的螯合树脂 和这些酸的金属盐。
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