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1.发明公开Process for producing epsilon-caprolactam by Beckmann-rearrangement in the gas phase in the presence of a zeolite catalyst and water 失效一种用于在沸石催化剂和水的存在下制备的ε-己内酰胺的由贝克曼重排中的气相方法。
公开(公告)号：EP0544530A1
公开(公告)日：1993-06-02
申请号：EP92310818.7
申请日：1992-11-26
IPC分类号： C07D201/04 , B01J29/04
CPC分类号： B01J29/04 , C07D201/04 , Y02P20/52
摘要： ε -Caprolactam is prepared by subjecting cyclohexanone oxime in a gas phase to a catalytic reaction using zeolite catalysts in the presence of water and at least one compound selected from alcohols and ether compounds.
摘要翻译： ε-己内酰胺是通过在水和至少一种化合物选自醇和醚化合物中存在下，使用沸石催化剂在气相中进行环己酮肟的催化反应制备。
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2.发明授权Process for producing epsilon-caprolactam by Beckmann-rearrangement in the gas phase in the presence of a zeolite catalyst and water 失效一种用于在沸石催化剂和水的存在下制备的ε-己内酰胺的由贝克曼重排中的气相方法
公开(公告)号：EP0544530B1
公开(公告)日：2000-03-22
申请号：EP92310818.7
申请日：1992-11-26
IPC分类号： C07D201/04 , B01J29/04
CPC分类号： B01J29/04 , C07D201/04 , Y02P20/52
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公开(公告)号：EP0550965B1
公开(公告)日：1996-10-09
申请号：EP92310820.3
申请日：1992-11-26
IPC分类号： C07C249/14 , C07C251/44
CPC分类号： C07C249/14
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公开(公告)号：EP0550965A3
公开(公告)日：1995-02-15
申请号：EP92310820.3
申请日：1992-11-26
IPC分类号： C07C249/14 , C07C251/44
CPC分类号： C07C249/14
摘要： Thermal decomposition of cycloalkanone oximes is inhibited by allowing nitrogen-containing compounds represented by the following formula (1) to coexist with the cycloalkanone oximes:
NR₁R₂R₃ (1)
(wherein R₁, R₂ and R₃ each represents a hydrogen atom or a lower alkyl group).-
5.发明公开Process for the preparation of epsilon-caprolactam by Deckamnn-rearrangement in the phase in the presence of a zeolite catalyst and nitrogen-containing compounds 失效一种用于在沸石催化剂和含氮化合物的存在下制备的ε-己内酰胺的由贝克曼重排中的气相方法。
公开(公告)号：EP0544531A1
公开(公告)日：1993-06-02
申请号：EP92310819.5
申请日：1992-11-26
IPC分类号： C07D201/04 , B01J29/04
CPC分类号： B01J29/06 , C07D201/04 , Y02P20/52
摘要： ε -Caprolactam is prepared by bringing cyclohexanone oxime into contact in gas phase with solid catalysts such as a zeolite catalyst in the presence of at least one nitrogen-containing compound selected from the group consisting of ammonia, methylamines and ε -caprolactam.
摘要翻译： ε-己内酰胺是通过使环己酮肟进在气相中与固体催化剂接触而制备：如在至少一种含氮化合物的选自氨，甲基cardamines和ε-己内酰胺的选择存在的沸石催化剂。
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6.发明授权Process for the preparation of epsilon-caprolactam by Deckamnn-rearrangement in the phase in the presence of a zeolite catalyst and nitrogen-containing compounds 失效一种用于在沸石催化剂的存在下制备的ε-己内酰胺的由贝克曼重排在气相和含氮化合物的方法
公开(公告)号：EP0544531B1
公开(公告)日：2000-04-05
申请号：EP92310819.5
申请日：1992-11-26
IPC分类号： C07D201/04 , B01J29/04
CPC分类号： B01J29/06 , C07D201/04 , Y02P20/52
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公开(公告)号：EP0641778A1
公开(公告)日：1995-03-08
申请号：EP94306137.4
申请日：1994-08-19
IPC分类号： C07D201/16
CPC分类号： C07D201/16
摘要： The invention provides a process for producing high quality ε-caprolactam which comprises allowing crude ε-caprolactam obtained by gas phase Beckmann rearrangement of cyclohexanone oxime to contact with hydrogen at 100-200°C in the presence of a hydrogenation catalyst.
摘要翻译： 本发明提供了一种生产高品质ε-己内酰胺的方法，其包括在氢化催化剂存在下，使得通过环己酮肟气相贝克曼重排获得的粗ε-己内酰胺在100-200℃下与氢气接触。
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8.发明公开
公开(公告)号：EP0570110A1
公开(公告)日：1993-11-18
申请号：EP93302948.0
申请日：1993-04-15
IPC分类号： C07D201/16
CPC分类号： C07D201/16
摘要： A process for producing a high purity caprolactam is disclosed in which a crude caprolactam obtained by a catalytic rearrangement of cyclohexanone oxime is subjected
(1) to mixing, while stirring, with at least one hydrocarbon selected from the group consisting of aliphatic hydrocarbons and alicyclic hydrocarbons to form a liquid-liquid , two-layer liquid mixture, and then crystallizing caprolactam out of the liquid mixture;
(2) to mixing with both at least one hydrocarbon selected from the group consisting of aliphatic hydrocarbons and alicyclic hydrocarbons, and water to form a liquid mixture, separating the liquid mixture into a hydrocarbon layer and a water layer, and then recovering caprolactam from the water layer; or
(3) to distillation in the co-presence of at least one aliphatic saturated hydrocarbon of 10 to 18 carbon atoms.摘要翻译： 公开了一种制备高纯度己内酰胺的方法，其中通过环己酮肟的催化重排获得的粗己内酰胺在搅拌下与至少一种选自脂族烃和脂环族烃的烃进行混合 形成液液两层液体混合物，然后从己烷溶液中混合出己内酰胺; （2）与选自脂族烃和脂环族烃的至少一种烃和水混合以形成液体混合物，将液体混合物分离成烃层和水层，然后从其中回收己内酰胺 水层; 或（3）在至少一种10至18个碳原子的脂族饱和烃的共存下进行蒸馏。
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9.发明公开Method for inhibiting thermal decomposition of cycloalkanone oximes 失效Verfahren zur Verhinderung thermischer Zersetzung von Cycloalkanonoximen。
公开(公告)号：EP0550965A2
公开(公告)日：1993-07-14
申请号：EP92310820.3
申请日：1992-11-26
IPC分类号： C07C249/14 , C07C251/44
CPC分类号： C07C249/14
摘要： Thermal decomposition of cycloalkanone oximes is inhibited by allowing nitrogen-containing compounds represented by the following formula (1) to coexist with the cycloalkanone oximes:
NR₁R₂R₃ (1)
(wherein R₁, R₂ and R₃ each represents a hydrogen atom or a lower alkyl group).摘要翻译： 通过使由下式（1）表示的含氮化合物与环烷酮肟共存，可以抑制环烷酮肟的热分解：NR1R2R3（1>（其中R1，R2和R3各自表示氢原子或低级烷基） 。
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