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    Process for production of sec-butylbenzene
    2.
    发明公开
    Process for production of sec-butylbenzene 失效
    Verfahren zur Herstellung von sec.-Butylbenzol。

    公开(公告)号：EP0395360A1

    公开(公告)日：1990-10-31

    申请号：EP90304403.0

    申请日：1990-04-24

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Tamura, Mitsuhisa ,  Yamauchi, Kazuhiro ,  Higashio, Yasuhiko ,  Takahashi, Kazuteru

    IPC分类号： C07C15/02 ,  C07C2/68

    CPC分类号： C07C2/70 ,  C07C2527/11 ,  C07C2527/126 ,  C07C2531/02 ,  C07C15/02

    摘要： Benzene and n -butene (1-, cis - and/or trans -) are reacted at a temperature of 20 to 70°C in the presence of a complex catalyst which is a homogeneous liquid of aluminum chloride, hydrogen chloride and an aromatic hydro­carbon, in amount of 0.3 to 5 wt% of the AlCl₃ to the benzene (prepared by stirring for ⅓ - 3 hours); the reaction mixture is separated into fractions containing mainly the desired product sec -butylbenzene with not more than 1% of by-product isobutylbenzene; heavy materials; and (which are recycled) benzene, and dibutyl- and tributylbenzenes.
    The catalyst can be separated, recovered and recycled.
    The reaction can be continuous or batchwise.
    The product sec -butylbenzene can be utilised for production of phenol.

    摘要翻译： 苯和正丁烯（1-，顺 - 和/或反 - ）在20至70℃的温度下在络合催化剂存在下反应，该络合催化剂是氯化铝，氯化氢和芳族烃的均匀液体 ，相对于苯的AlCl 3为0.3〜5重量％（搅拌1/3〜3小时）。 将反应混合物分离成主要含有所需产物仲丁基苯和不超过1％副产物异丁苯的级分; 重材料; 和（其是再循环的）苯，以及二丁基 - 和三丁基苯。 催化剂可以分离，回收和再循环。 反应可以是连续的或分批的。 产物仲丁基苯可用于生产苯酚。

    Method of selective hydrogenation of hydrocarbons
    4.
    发明公开
    Method of selective hydrogenation of hydrocarbons 失效
    Verfahren zur selektiven Hydrierung von Kohlenwasserstoffen。

    公开(公告)号：EP0087980A1

    公开(公告)日：1983-09-07

    申请号：EP83301111.7

    申请日：1983-03-02

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Araki, Masashi ,  Higashio, Yasuhiko

    IPC分类号： C07C5/03 ,  C07C5/08

    CPC分类号： C07C5/08 ,  C07C5/03 ,  C07C2523/44

    摘要： A mixture of (a) highly unsaturated hydrocarbons having at least 2 double bonds or at least 1 triple bond (e.g. 1,3-butadiene, propadiene, vinylacetylene) and (b) hydrocarbons having 4 or more C atoms (e.g. butane, butene) is contacted in a fixed bed reactor containing a catalyst, e.g. palladium, with hydrogen gas in amount of 1 to 3 moles per mole of unsaturated hydrocarbons (a); the H 2 is supplied at at least two, preferably two or three, points along the length of the vessel.
    Two or more vessels can be connected in series, or a single vessel can be divided into separate catalyst zones between which H 2 is fed. Reaction in vapour phase is preferred.
    The method provides hydrogenation of the highly unsaturated hydrocarbons, without isomerization of olefinic double bonds which can reduce the proportion of 1-butene.

    摘要翻译： （a）具有至少2个双键或至少1个三键（例如1,3-丁二烯，丙二烯，乙烯基乙炔）和（b）具有4个或更多个C原子的烃（例如丁烷，丁烯）的高度不饱和烃的混合物， 在含有催化剂的固定床反应器中接触，例如 钯，每摩尔不饱和烃（a）的氢气量为1至3摩尔; H2沿着容器长度的至少两个，优选两个或三个点供应。 两个或更多个容器可以串联连接，或者单个容器可以被分成单独的催化剂区域，在其间供给H 2。 汽相反应为红色。 该方法提供高度不饱和烃的氢化，而不会烯烃双键的异构化，这可以降低1-丁烯的比例。

    Process for producing a high purity caprolactam
    9.
    发明公开
    Process for producing a high purity caprolactam 失效
    Verfahren zur Herstellung von hochreinem己内酰胺。

    公开(公告)号：EP0570110A1

    公开(公告)日：1993-11-18

    申请号：EP93302948.0

    申请日：1993-04-15

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Higashio, Yasuhiko ,  Kajikuri, Hiroshi ,  Sugita, Keisuke ,  Doi, Hideki ,  Matsubara, Masanobu

    IPC分类号： C07D201/16

    CPC分类号： C07D201/16

    摘要： A process for producing a high purity caprolactam is disclosed in which a crude caprolactam obtained by a catalytic rearrangement of cyclohexanone oxime is subjected

    (1) to mixing, while stirring, with at least one hydrocarbon selected from the group consisting of aliphatic hydrocarbons and alicyclic hydrocarbons to form a liquid-liquid , two-layer liquid mixture, and then crystallizing caprolactam out of the liquid mixture;
    (2) to mixing with both at least one hydrocarbon selected from the group consisting of aliphatic hydrocarbons and alicyclic hydrocarbons, and water to form a liquid mixture, separating the liquid mixture into a hydrocarbon layer and a water layer, and then recovering caprolactam from the water layer; or
    (3) to distillation in the co-presence of at least one aliphatic saturated hydrocarbon of 10 to 18 carbon atoms.

    摘要翻译： 公开了一种制备高纯度己内酰胺的方法，其中通过环己酮肟的催化重排获得的粗己内酰胺在搅拌下与至少一种选自脂族烃和脂环族烃的烃进行混合 形成液液两层液体混合物，然后从己烷溶液中混合出己内酰胺; （2）与选自脂族烃和脂环族烃的至少一种烃和水混合以形成液体混合物，将液体混合物分离成烃层和水层，然后从其中回收己内酰胺 水层; 或（3）在至少一种10至18个碳原子的脂族饱和烃的共存下进行蒸馏。

    Method for inhibiting thermal decomposition of cycloalkanone oximes
    10.
    发明公开
    Method for inhibiting thermal decomposition of cycloalkanone oximes 失效
    Verfahren zur Verhinderung thermischer Zersetzung von Cycloalkanonoximen。

    公开(公告)号：EP0550965A2

    公开(公告)日：1993-07-14

    申请号：EP92310820.3

    申请日：1992-11-26

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Kajikuri, Hiroshi ,  Kitamura, Masaru ,  Higashio, Yasuhiko

    IPC分类号： C07C249/14 ,  C07C251/44

    CPC分类号： C07C249/14

    摘要： Thermal decomposition of cycloalkanone oximes is inhibited by allowing nitrogen-containing compounds represented by the following formula (1) to coexist with the cycloalkanone oximes:



            NR₁R₂R₃   (1)



    (wherein R₁, R₂ and R₃ each represents a hydrogen atom or a lower alkyl group).

    摘要翻译： 通过使由下式（1）表示的含氮化合物与环烷酮肟共存，可以抑制环烷酮肟的热分解：NR1R2R3（1>（其中R1，R2和R3各自表示氢原子或低级烷基） 。