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公开(公告)号：EP0371411A3
公开(公告)日：1992-03-18
申请号：EP89121758.0
申请日：1989-11-24
CPC分类号： C08F10/00 , C08F4/68 , C08F4/6094 , C08F4/6028
摘要： A method for producing olefin polymers by using a catalyst system comprising
catalyst component (A): a vanadium compound represented by the formula VOX₃ in which X represents a halogen atom, or VO(OR)₃ in which R represents a C₁-C₂₀ hydrocarbon group,
catalyst component (B): an aluminoxane obtained by the reaction of a trialkylaluminum with water, or a mixture of said aluminoxane and an aluminum compound represented by the formula AlR′ n X′ 3-n in which R′ represents a C₁-C₁₀ alkyl group, X′ represents a hlaogen atom and n represents a number selected from 0, 1, 2 and 3, and optionally
catalyst component (C): an organic compound having at least two hydroxyl groups.-
公开(公告)号：EP0382547A3
公开(公告)日：1992-02-26
申请号：EP90301369.6
申请日：1990-02-08
IPC分类号： C08L71/12 , C08L77/00 , C08F283/08
CPC分类号： C08L71/12 , C08G65/485 , C08L67/00 , C08L71/00 , C08L75/00 , C08L77/00 , C08L81/00 , Y10S525/905 , C08L2666/22
摘要： A thermoplastic resin composition which comprises:
(A) 5 - 95% by weight of a polyamide resin which has a relative viscosity of 3.1 - 4.5 and a ratio (α) of terminal amino groups to terminal carboxyl groups such that 0:1 (B) 95 - 5% by weight of a modified polyphenylene ether resin, which is a polyphenylene ether resin whioh has been modified with at least one compound having at least one functional group, or a mixture of said modified polyphenylene ether resin and a polyphenylene ether resin.-
3.发明授权Alpha-olefin block copolymer particles and process for the production thereof 失效ALPHA-OLEFIN嵌段共聚物颗粒及其生产方法
公开(公告)号：EP0202946B1
公开(公告)日：1992-01-22
申请号：EP86303915.2
申请日：1986-05-22
发明人： Shiga, Akinobu , Kakugo, Masahiro , Sadatoshi, Hajime , Kora, Hiroyuki , Sasaki, Toshio , Kojima, Junpei , Wakamatsu, Kazuki , Kawamata, Syozo
IPC分类号： C08F297/08
CPC分类号： C08F297/083
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公开(公告)号：EP0368577A3
公开(公告)日：1991-04-03
申请号：EP89311433.0
申请日：1989-11-03
发明人： Kakugo, Masahiro , Sadatoshi, Hajime , Sakai, Jiro , Wakamatsu, Kazuki , Chikaishi, Kazuhiro , Kojima, Toshiro , Nomura, Hideo , Fukao, Tomohisa
IPC分类号： C08L23/10
CPC分类号： C08L23/142 , C08F297/08 , C08F297/086 , C08L23/10 , C08L2205/02 , C08L2308/00 , C08L2666/04
摘要： A crystalline polypropylene has a ratio of weight average molecular weight to number average molecular weight of 10 or more, preferably 15 or more, an intrinsic viscosity (η) of from 0.8 to 5.0 dl/g (measured in tetralin at 135°C), a cold xylene-soluble content of not more than 4% by weight, a density (d) of 0.910 g/cm or more (measured at 23°C), and a long period (L) (Å) (measured at 25°C by a small-angle X-ray scattering method) satisfying:
L ≦ Lc = 6667d - 5894
wherein d is the density at 23°C and Lc is a value (Å) obtained by Lc =6667d - 5894. The crystalline polymer can be compounded with 1 ppm to 20 wt% of an alpha-olefin or vinylcyloalkane whose homopolymer melts at at least 270°C, the composition produced having (d) and (L) as above; part of the composition can be block copolymerized. Catalysts for producing the polymer are described. The product as a powder is melted and moulded to shape. The mouldings have good rigidity, heat resistance and surface hardness.-
5.发明公开Crystalline polypropylene and compositions thereof 无效Kristallines Polypropylen und daraus gefertigte Zusammensetzungen。
公开(公告)号：EP0368577A2
公开(公告)日：1990-05-16
申请号：EP89311433.0
申请日：1989-11-03
发明人： Kakugo, Masahiro , Sadatoshi, Hajime , Sakai, Jiro , Wakamatsu, Kazuki , Chikaishi, Kazuhiro , Kojima, Toshiro , Nomura, Hideo , Fukao, Tomohisa
IPC分类号： C08L23/10
CPC分类号： C08L23/142 , C08F297/08 , C08F297/086 , C08L23/10 , C08L2205/02 , C08L2308/00 , C08L2666/04
摘要： A crystalline polypropylene has a ratio of weight average molecular weight to number average molecular weight of 10 or more, preferably 15 or more, an intrinsic viscosity (η) of from 0.8 to 5.0 dl/g (measured in tetralin at 135°C), a cold xylene-soluble content of not more than 4% by weight, a density (d) of 0.910 g/cm or more (measured at 23°C), and a long period (L) (Å) (measured at 25°C by a small-angle X-ray scattering method) satisfying:
L ≦ Lc = 6667d - 5894
wherein d is the density at 23°C and Lc is a value (Å) obtained by Lc =6667d - 5894.
The crystalline polymer can be compounded with 1 ppm to 20 wt% of an alpha-olefin or vinylcyloalkane whose homopolymer melts at at least 270°C, the composition produced having (d) and (L) as above; part of the composition can be block copolymerized.
Catalysts for producing the polymer are described.
The product as a powder is melted and moulded to shape. The mouldings have good rigidity, heat resistance and surface hardness.摘要翻译： 结晶性聚丙烯的重均分子量与数均分子量的比例为10以上，优选为15以上，特性粘度（η）为0.8〜5.0dl / g（在135℃的四氢化萘中测定）， 冷二甲苯可溶物含量不超过4重量％，密度（d）为0.910g / cm 3以上（在23℃下测定）和长时间（L）（ANGSTROM）（25℃测定） C，通过小角X射线散射法）满足：L <= Lc = 6667d-5894其中d是23℃下的密度，Lc是通过Lc = 6667d-5894获得的值（ANGSTROM）。结晶 聚合物可以与1ppm至20wt％的均聚物在至少270℃熔融的α-烯烃或乙烯基环烷烃混合，所制备的组合物具有如上所述的（d）和（L）; 组合物的一部分可以是嵌段共聚的。 描述了用于生产聚合物的催化剂。 将作为粉末的产品熔化并模塑成型。 模具具有良好的刚性，耐热性和表面硬度。
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公开(公告)号：EP0148621A1
公开(公告)日：1985-07-17
申请号：EP84308901.2
申请日：1984-12-19
发明人： Okada, Takayuki , Kakugo, Masahiro , Fukui, Yoshiharu , Wakatsuki, Kizuku , Ima, Seiichiro , Kimura, Junichi
CPC分类号： C08J5/18 , C08J2323/10 , C08L23/12 , C08L23/142 , C08L23/20 , C08L2314/02 , Y10S428/91 , Y10T428/31913 , C08L2666/06
摘要： A stretched polypropylene film having excellent see-through characteristics, which is prepared by stretching in at leastone direction a polypropylene resin sheet containing 0.05 ppm to 1 % by weight of a polymer of a 3-position branched a-olelfin having at least 6 carbon atoms or a polymer of a vinyl cycloalkane.
The olefin or cycloalkane (A) can simbly be mixed with a homo- or co-polymer of propylene; or the mixture of (A) and catalyst used in its production can be used for catalytically polymerizing propylene alone or with another a-olefin, and then more polypropylene can be admixed.
Other additives, e.g. a filler, can be included.
The polymer is pelletized and formed into a sheet and usually biaxially stretched; the streching areal ratio can be 1.2 to 100 times.-
7.发明授权Ethylene-aromatic vinyl compound alternating copolymer and process for the production thereof 失效乙烯和乙烯基芳族化合物和方法的相同的交替共聚物的制备
公开(公告)号：EP0405446B1
公开(公告)日：1998-04-22
申请号：EP90112129.3
申请日：1990-06-26
IPC分类号： C08F210/02 , C08F212/04 , C08F4/609
CPC分类号： C08F212/04 , C08F210/02 , C08F4/6028
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公开(公告)号：EP0371411B1
公开(公告)日：1996-03-06
申请号：EP89121758.0
申请日：1989-11-24
CPC分类号： C08F10/00 , C08F4/68 , C08F4/6094 , C08F4/6028
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公开(公告)号：EP0371411A2
公开(公告)日：1990-06-06
申请号：EP89121758.0
申请日：1989-11-24
CPC分类号： C08F10/00 , C08F4/68 , C08F4/6094 , C08F4/6028
摘要： A method for producing olefin polymers by using a catalyst system comprising
catalyst component (A): a vanadium compound represented by the formula VOX₃ in which X represents a halogen atom, or VO(OR)₃ in which R represents a C₁-C₂₀ hydrocarbon group,
catalyst component (B): an aluminoxane obtained by the reaction of a trialkylaluminum with water, or a mixture of said aluminoxane and an aluminum compound represented by the formula AlR′ n X′ 3-n in which R′ represents a C₁-C₁₀ alkyl group, X′ represents a hlaogen atom and n represents a number selected from 0, 1, 2 and 3, and optionally
catalyst component (C): an organic compound having at least two hydroxyl groups.摘要翻译： 一种通过使用包含催化剂组分（A）的催化剂体系生产烯烃聚合物的方法：其中X表示卤素原子的式VOX 3表示的钒化合物或其中R表示C 1 -C 20烃基的VO（OR）3 ，催化剂组分（B）：由三烷基铝的与水的反应，或所述的混合物获得铝氧烷的铝氧烷和由式AlR'nX'3-n表示的铝化合物，其中R'表示C 1 -C 10烷基 基团，X'表示一种羟基原子并且n表示选自0,1,2和3的数字，并且任选地催化剂组分（C）：具有至少两个羟基的有机化合物。
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公开(公告)号：EP0316187A3
公开(公告)日：1990-03-28
申请号：EP88310623.9
申请日：1988-11-10
发明人： Wakatsuki, Kizuku , Yamaguchi, Norboru , Watamatsu, Kazuki , Kakugo, Masahiro , Ohmae, Tadayuki
CPC分类号： C08L23/10 , C08L23/12 , C08L23/20 , C08L2203/12 , C08L2314/02 , D01F6/06 , C08L2666/06
摘要： Crystalline polypropylene homopolymer or a copolymer with up to 5 mol% of other α-olefin or optionally containing a grafted vinyl compound, preferably of intrinsic viscosity 1.1 to 3.5 dl/g, has incorporated, during polymerization or by blending, 0.05 to 10,000 ppm of a polymer of a vinylcycloalkane, which may be a copolymer with up to 20 mol% of an α-olefin or styrene, preferably obtained with a Ziegler-Natta catalyst. The resultant polypropylene can be spun and stretched.
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