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    Flexible propylene polymer
    3.
    发明公开
    Flexible propylene polymer 失效
    Biegsames聚丙烯。

    公开(公告)号：EP0114391A1

    公开(公告)日：1984-08-01

    申请号：EP83113039.8

    申请日：1983-12-23

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Kokubo, Toshiyuki ,  Nakae, Kiyohiko ,  Ogawa, Tadatoshi

    IPC分类号： C08F110/06 ,  C08F2/34 ,  C08F4/64

    CPC分类号： C08F110/06 ,  C08F4/6565 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/20 ,  C08F2500/11 ,  C08F2500/18

    摘要： A flexible propylene polymer which is a propylene polymer obtained by gas-phase polymerization, said polymer being in particle form after polymerization and having a bulk density of at least 0.27 g/ml, wherein

    (1) the ratio of weight average molecular weight to number average molecular weight is from 10 to 100,
    (2) the intrinsic viscosity [η] is from 0.8 to 10 dl/g,
    (3) in the steric pentad fraction as determined by 13 C-NMR, the [mmmm] fraction is from 0.45 to 0.85,
    (4) the melt flow ratio (MFR) satisfies the following equation: wherein MI means melt index,
    (5) the fusion temperature is from 154 to 164°C,
    (6) the heat of fusion is from 5 to 22 cal/g,
    (7) the intrinsic viscosity [η] HSP of the boiling-heptane soluble portion (HSP) and the intrinsic viscosity [η] HIP of the boiling-heptane insoluble portion (HIP) of said polymer satisfies the following equation:
    [η]HSP≧ 0.25 [η] HIP , and
    (8) in the steric pentad fraction of the above boiling-heptane insoluble portion as determined by "C-NMR, the [mmmm] fraction is from 0.60 to 0.90 and the sum of the [mmmr], [rrrm] and [rrrr] fractions is from 0.07 to 0.30.

    摘要翻译： 一种柔性丙烯聚合物，其是通过气相聚合获得的丙烯聚合物，所述聚合物在聚合后为颗粒形式，并且具有至少0.27g / ml的堆积密度，其中（1）重均分子量与数量之比 平均分子量为10至100，（2）特性粘度η为0.8至10dl / g，（3）在通过1 C-NMR测定的空间五单元组分数中，[ mm）分数为0.45〜0.85，（4）熔体流动比（MFR）满足下式：MFR> / = -42 log MI + 133，其中MI表示熔融指数，（5）熔融温度为154 （6）熔融热为5〜22cal / g，（7）沸腾庚烷可溶部分（HSP）的特性粘度ηHSP和特性粘度ηHIP为 所述聚合物的沸腾庚烷不溶部分（HIP）满足以下等式：ηHSP> / = 0.25HIP，和（8）在上述b的空间五单元组分数 通过1 C-NMR测定的油 - 庚烷不溶部分，[mmmm]级分为0.60至0.90，[mmmr]，[rrrm]和[rrrr]分数之和为0.07至0.30 。

    Ethylene-alpha-olefin copolymers and molded article thereof
    4.
    发明公开
    Ethylene-alpha-olefin copolymers and molded article thereof 失效
    乙烯-α-烯烃Copolymere und daraus hergestellte Formteile。

    公开(公告)号：EP0640627A1

    公开(公告)日：1995-03-01

    申请号：EP94306168.9

    申请日：1994-08-22

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Kanda, Yuji ,  Kokubo, Toshiyuki ,  Sato, Yufu ,  Sasaki, Toshio ,  Shiraishi, Hiroyuki ,  Shigematsu, Yuji

    IPC分类号： C08F210/16

    CPC分类号： C08F210/16 ,  C08F210/18 ,  C08F2500/08 ,  C08F2500/20 ,  C08F2500/12 ,  C08F2500/10 ,  C08F2500/11

    摘要： A novel ethylene-α-olefin copolymer and a molded article formed therefrom, wherein

    (A) a density is 0.870 to 0.945 g/cm 3,
    (B) a relation between an activation energy of flow Ea (J/mole K) obtained by measurement of viscoelasticity at at least three temperatures in the molten state and a melt flow rate MFR (g/10 min) satisfies the following equation (1): logEa ≧ 4.6 - 0.04 × logMFR
    (C) a coefficient Cx of variation of chemical composition distribution represented by the following equation (2) is 0.40 to 0.80: Cx = σ/SCB ave wherein σ is a standard deviation of chemical composition distribution (1/1,000 C) and SCB ave is the average of short chain branchings per 1,000 C (1/1,000 C), and
    (D) a ratio of a weight average molecular weight Mw to a number average molecular weight Mn (Mw/Mn) is 3 to 20.

    摘要翻译： 一种新型乙烯-α-烯烃共聚物和由其形成的模塑制品，其中（A）密度为0.870至0.945g / cm 3，（B）流动活化能Ea（J /摩尔K） 通过在熔融状态下至少三个温度下的粘弹性测定得到的熔体流动速率MFR（g / 10分钟）满足下式（1）：（C）表示化学成分分布的变化系数Cx 通过下式（2）为0.40至0.80：其中sigma是化学组成分布的标准偏差（1 / 1,000℃），SCBave是每1000℃（1 / 1,000℃）的短链分支的平均值， 和（D）重均分子量Mw与数均分子量Mn（Mw / Mn）的比例为3〜20。

    Solid catalyst component for olefin polymerization
    6.
    发明公开
    Solid catalyst component for olefin polymerization 失效
    固体催化组分对于Olefinenpolymerisation。

    公开(公告)号：EP0137224A1

    公开(公告)日：1985-04-17

    申请号：EP84109674.6

    申请日：1984-08-14

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Kawai, Kiyoshi ,  Kokubo, Toshiyuki ,  Miyoshi, Yoshihiro

    IPC分类号： C08F10/00 ,  C08F4/62

    CPC分类号： C08F10/00 ,  C08F4/6367

    摘要： A solid catalyst component for olefin polymenzanon which is produced by reacting (A) a silicon compound with (B) a compound of transition metal of Groups IVa, Va and Via of the periodic table to obtain a reaction mixture (I), reacting the reaction mixture (I) with (C) an organomagnesium compound selected from organomagnesium compounds or hydrocarbon-soluble complexes between an organomagnesium compound and an organometal compound capable of allowing said organomagnesium compound to be soluble in hydrocarbons to obtain an intermediate product (II), and contacting the intermediate product (II) with (D) an organoaluminum halide compound represented by the general formula R 1 c AlX 3-c (wherein R 1 is an organic group containing 1 to 20 carbon atoms, X is a halogen and c is a number defined by 0