摘要:
A novel ethylene-α-olefin copolymer and a molded article formed therefrom, wherein
(A) a density is 0.870 to 0.945 g/cm 3, (B) a relation between an activation energy of flow Ea (J/mole K) obtained by measurement of viscoelasticity at at least three temperatures in the molten state and a melt flow rate MFR (g/10 min) satisfies the following equation (1): logEa ≧ 4.6 - 0.04 × logMFR (C) a coefficient Cx of variation of chemical composition distribution represented by the following equation (2) is 0.40 to 0.80: Cx = σ/SCB ave wherein σ is a standard deviation of chemical composition distribution (1/1,000 C) and SCB ave is the average of short chain branchings per 1,000 C (1/1,000 C), and (D) a ratio of a weight average molecular weight Mw to a number average molecular weight Mn (Mw/Mn) is 3 to 20.
摘要:
A non-anchor extrusion coating process for producing a laminate, which process comprises the steps of:
(a) subjecting at least one surface of a substrate to surface activation in an atmosphere of an inert gas, (b) melt-extruding a resin to form an extrudate in the form of film, and (c) placing at least one surface of the extrudate in contact with said at least one activated surface of the substrate, and adhering the extrudate to the substrate by pressure to obtain a laminate. The laminate of resin and metal or plastic substrate which is produced is improved in film adhesive strength and is usable as a packaging material.
摘要:
A resin composition for extrusion molding which has a melt flow rate (MFR) of from 0.5 to 30 g/10 min., having (A) 1 to 80 parts by weight of an ethylenic polymer which gives an endothermic peak in a temperature range of from 80 to 120°C in a temperature rise thermogram as measured by a differential scanning calorimeter, has a melt flow rate (MFR) of from 0.5 to 50 g/10 min., and is prepared by high-pressure radical polymerization, (B) 5 to 80 parts by weight of a copolymer of ethylene and an α-olefine containing 3 to 12 carbon atoms which gives at least one endothermic peak in a temperature range of from 110 to 130°C in the temperature rise thermogram as described above, has a melt flow rate (MFR) of from 0.5 to 30 g/10 min. and a density of from 0.900 to 0.935 g/cm³, and (C) 5 to 70 parts by weight of the copolymer of ethylene and an α-olefine containing 3 to 12 carbon atoms which has a melt flow rate (MFR) of from 0.5 to 30 g/10 min. and a density of from 0.870 to 0.920 g/cm³ in an unannealed state, and gives no endothermic peak at temperatures above 110°C in the temperature rise thermogram as described above, and in which a ratio of a main component is not less than 80 %; which gives a packaging material having significantly improved properties such as heat sealability at low temperature, heat-sealing strength, hot tacking property and bag breaking strength, and exhibits an excellent extrusion processability such as film forming property and extrusion loading.