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公开(公告)号：EP0602861A2
公开(公告)日：1994-06-22
申请号：EP93309744.6
申请日：1993-12-06
CPC分类号： C08G8/24 , C08L7/00 , C08L21/00 , C08L2666/14 , C08L65/02
摘要： There is provided a co-condensation product obtainable by subjecting a p-alkylphenol to reaction with formaldehyde in the presence of an alkali catalyst to prepare a resol type condensate, and subjecting the resulting resol type condensate to reaction with a m-substituted phenol such as resorcin in the presence of an acid catalyst, wherein the content of the m-substituted phenol is not higher than 4% by weight, and the content of a component having a molecular weight not higher than 1,000 excluding both the p-alkylphenol and the m-substituted phenol is at least 25% by weight based on the total weight of the co-condensation product. This co-condensation product is low in fuming and in hygroscopic properties, exhibits excellent adhesiveness in vulcanizing adhesion between rubber and a reinforcing material, and further provides a vulcanized rubber article of high hardness.
摘要翻译： 本发明提供一种在碱催化剂存在下使对烷基苯酚与甲醛反应而制备甲阶型缩合物，并将所得甲阶型缩合物与间位取代的苯酚如 间苯二酚在酸催化剂存在下反应，其中间位取代苯酚的含量不高于4重量％，分子量不高于1,000的组分的含量不包括对烷基苯酚和m 取代的苯酚基于共缩合产物的总重量为至少25重量％。 该共缩合物的发烟性和吸湿性低，橡胶和增强材料之间的硫化粘合性优异，进一步提供高硬度的硫化橡胶制品。
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公开(公告)号：EP0602861B1
公开(公告)日：1999-05-06
申请号：EP93309744.6
申请日：1993-12-06
CPC分类号： C08G8/24 , C08L7/00 , C08L21/00 , C08L2666/14 , C08L65/02
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公开(公告)号：EP0581618B1
公开(公告)日：1997-06-18
申请号：EP93306113.7
申请日：1993-07-30
CPC分类号： C08K5/23 , B60C1/0016 , C08K3/04 , C08K5/47 , Y02T10/862 , Y10S152/905 , C08L25/10 , C08L9/06
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公开(公告)号：EP0602861A3
公开(公告)日：1994-10-12
申请号：EP93309744.6
申请日：1993-12-06
CPC分类号： C08G8/24 , C08L7/00 , C08L21/00 , C08L2666/14 , C08L65/02
摘要： There is provided a co-condensation product obtainable by subjecting a p-alkylphenol to reaction with formaldehyde in the presence of an alkali catalyst to prepare a resol type condensate, and subjecting the resulting resol type condensate to reaction with a m-substituted phenol such as resorcin in the presence of an acid catalyst, wherein the content of the m-substituted phenol is not higher than 4% by weight, and the content of a component having a molecular weight not higher than 1,000 excluding both the p-alkylphenol and the m-substituted phenol is at least 25% by weight based on the total weight of the co-condensation product. This co-condensation product is low in fuming and in hygroscopic properties, exhibits excellent adhesiveness in vulcanizing adhesion between rubber and a reinforcing material, and further provides a vulcanized rubber article of high hardness.
摘要翻译： 提供了一种共缩合产物，其可通过在碱催化剂存在下使对烷基酚与甲醛反应以制备甲阶型缩合物，并将得到的甲阶酚醛型缩合物与间取代的苯酚如 在酸催化剂存在下的间苯二酚，其中m取代酚的含量不高于4重量％，除了对烷基酚和m之外，分子量不高于1,000的组分的含量 取代苯酚占共缩合产物总重量的至少25重量％。 这种共缩合产物发烟量低，吸湿性好，在橡胶与增强材料之间的硫化粘合性方面表现出优异的粘合性，并且还提供了高硬度的硫化橡胶制品。
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公开(公告)号：EP0500323B1
公开(公告)日：1997-01-15
申请号：EP92301324.7
申请日：1992-02-18
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公开(公告)号：EP0500323A3
公开(公告)日：1994-06-01
申请号：EP92301324.7
申请日：1992-02-18
摘要： A bisphenol monoester represented by the formula (I) :
wherein R 1 is hydrogen or alkyl, R 2 and R 3 are each alkyl, and R 4 is alkyl, alkenyl or phenyl, is produced by continuous two step reactions in which an aldehyde R 1 -CHO and 2,4-dialkylphenol are subjected to a condensation reaction in a C 6 -C 10 aliphatic or C 6 -C 12 aromatic hydrocarbon solvent, and then a resulting bisphenol compound dissolved in the solvent is subjected to an esterification with a carboxylic acid R 4- COOH or its derivative. Prior to the esterification, the organic layer containing the bisphenol compound is subjected to a dehydration treatment, thereby enabling the two steps to proceed continuously without isolating the intermediate bisphenol compound. A purification process for the bisphenol monoester of the formula (I) is also disclosed in which the monoester is purified from a mixed solvent comprising a C 6 -C 12 aromatic hydrocarbon solvent and a C 1 -C S alcohol or C 2 -C 3 aliphatic nitrile solvent.-
公开(公告)号：EP0581618A1
公开(公告)日：1994-02-02
申请号：EP93306113.7
申请日：1993-07-30
CPC分类号： C08K5/23 , B60C1/0016 , C08K3/04 , C08K5/47 , Y02T10/862 , Y10S152/905 , C08L25/10 , C08L9/06
摘要： A rubber composition for use in production of automobile tires comprising the following components :
(A) a rubber component comprising at least 50% by weight of styrene/butadiene copolymer rubber ;
(B) azodicarboxylic ester compound represented by the formula
wherein X is alkyl of 3 to 8 carbon atoms, unsubstituted or substituted phenyl, or unsubstituted or substituted benzyl ;
(C) carbon black having a nitrogen absorption specific surface area of 100 to 250 m 2 /g and a dibutyl phthalate absorption number of 110 to 170 ml/100 g ;
(D) sulfur; and
(E) benzothiazole vulcanization accelerator.摘要翻译： 一种用于生产汽车轮胎的橡胶组合物，其包含以下组分：（A）包含至少50重量％的苯乙烯/丁二烯共聚物橡胶的橡胶组分; （B）由式
表示的偶氮二羧酸酯化合物，其中X为3-8个碳原子的烷基，未取代或取代的苯基，或未取代或取代的苄基; （C）氮吸收比表面积为100〜250m 2 / g的炭黑和邻苯二甲酸二丁酯吸收值为110〜170ml / 100g; （D）硫; 和（E）苯并噻唑硫化促进剂。 C -
公开(公告)号：EP0500323A2
公开(公告)日：1992-08-26
申请号：EP92301324.7
申请日：1992-02-18
摘要： A bisphenol monoester represented by the formula (I) :
wherein R 1 is hydrogen or alkyl, R 2 and R 3 are each alkyl, and R 4 is alkyl, alkenyl or phenyl, is produced by continuous two step reactions in which an aldehyde R 1 -CHO and 2,4-dialkylphenol are subjected to a condensation reaction in a C 6 -C 10 aliphatic or C 6 -C 12 aromatic hydrocarbon solvent, and then a resulting bisphenol compound dissolved in the solvent is subjected to an esterification with a carboxylic acid R 4- COOH or its derivative. Prior to the esterification, the organic layer containing the bisphenol compound is subjected to a dehydration treatment, thereby enabling the two steps to proceed continuously without isolating the intermediate bisphenol compound. A purification process for the bisphenol monoester of the formula (I) is also disclosed in which the monoester is purified from a mixed solvent comprising a C 6 -C 12 aromatic hydrocarbon solvent and a C 1 -C S alcohol or C 2 -C 3 aliphatic nitrile solvent.摘要翻译： 由式（I）表示的双酚单酯：其中R 1为氢或烷基，R 2和R 3各自为烷基，R 4为烷基，烯基或苯基，为 通过连续的两步反应制得，其中醛R 1 -CHO和2,4-二烷基苯酚在C6-C10脂族或C6-C12芳香族烃溶剂中进行缩合反应，然后将得到的双酚化合物溶于 溶剂用羧酸R 4 -COOH或其衍生物进行酯化。 在酯化之前，将含有双酚化合物的有机层进行脱水处理，从而能够在不分离中间体双酚化合物的情况下连续进行两个步骤。 还公开了式（I）的双酚单酯的纯化方法，其中从包含C 6 -C 12芳族烃溶剂和C 1 -C 8醇或C 2 -C 3脂族腈溶剂的混合溶剂中纯化单酯。
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