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1.发明公开Coupling of nucleophiles, vinyl compounds or CO with water, alcohols or amines to organic compounds 有权通过亲核试剂的偶联，乙烯基化合物或与水，醇或胺CO有机化合物
公开(公告)号：EP1132361A1
公开(公告)日：2001-09-12
申请号：EP01105511.8
申请日：2001-03-05
申请人： Solvias AG
发明人： Indolese, Adriano , Schnyder, Anita
CPC分类号： C07F15/006 , B01J31/1805 , B01J31/181 , B01J31/2226 , B01J31/24 , B01J31/2404 , B01J2231/42 , B01J2231/4211 , B01J2231/4261 , B01J2531/824 , C07B37/04 , C07C2/861 , C07C41/30 , C07C45/68 , C07C67/343 , C07C67/36 , C07C201/12 , C07C209/10 , C07C227/10 , C07C253/30 , C07C2531/24 , C07D213/57 , C07D295/192 , C07C49/782 , C07C69/734 , C07C69/65 , C07C69/76 , C07C69/738 , C07C69/618 , C07C211/55 , C07C229/44 , C07C255/33 , C07C255/57 , C07C205/06 , C07C205/56 , C07C43/205
摘要： Process for the coupling of
a) nucleophiles selected from the group alcohols, thioles, amines, metallised hydrocarbons, CH-acidic compounds and metal cyanides, or of
b) carbon monoxide mixed with water, alcohols, ammonia, primary or secondary amines, to organic compounds selected from the group of leaving-group-containing aromatics, hetero-aromatics with a C-bonded leaving group, aromatic or hetero-aromatic methyl compounds with a leaving group bonded to the methyl group, ethylenically unsaturated organic compounds with a C-bonded leaving group, or organic allyl compounds with a leaving group in allyl position, or
c) vinyl compounds with leaving-group-containing aromatics,
whilst cleaving the leaving group in the presence of Pd complexes with monophospholine ligands as the catalyst, whereby variants b) and c) are carried out in the presence of an inorganic base or organic nitrogen base, the process being characterised in that the Pd complex contains secondary monophosphines with aliphatic, branched or cyclic substituents as ligands.摘要翻译： 对的一连接器）处理的亲核试剂选自醇，thioles，cardamines，镀金属烃，CH-酸性化合物和金属氰化物，或b）将一氧化碳与水，醇，氨，伯或仲cardamines，混合有机 从以下组中选择的化合物含有离去基团的芳族化合物，杂芳族化合物与C键合的离去基团，芳族或杂芳族甲基化合物与键合至甲基，烯属不饱和有机化合物具有结合的C-离去基团 离去基团，或有机烯丙基化合物与离去基团在烯丙基位置上，或c）与含有离去基团的芳族化合物的乙烯基化合物，而裂解离去基团在钯复合物的存在与monophospholine配体作为催化剂，由此，变体b）中 和c）在无机碱或有机氮碱的存在下进行，该方法是DASS中的钯络合物包含具有alipha次级单膦 抽动，支链或环状的取代基作为配体。
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2.发明授权Coupling of nucleophiles, vinyl compounds or CO with water, alcohols or amines to organic compounds 有权通过亲核试剂的偶联，乙烯基化合物或与水，醇或胺CO有机化合物
公开(公告)号：EP1132361B1
公开(公告)日：2003-05-14
申请号：EP01105511.8
申请日：2001-03-05
申请人： Solvias AG
发明人： Indolese, Adriano , Schnyder, Anita
CPC分类号： C07F15/006 , B01J31/1805 , B01J31/181 , B01J31/2226 , B01J31/24 , B01J31/2404 , B01J2231/42 , B01J2231/4211 , B01J2231/4261 , B01J2531/824 , C07B37/04 , C07C2/861 , C07C41/30 , C07C45/68 , C07C67/343 , C07C67/36 , C07C201/12 , C07C209/10 , C07C227/10 , C07C253/30 , C07C2531/24 , C07D213/57 , C07D295/192 , C07C49/782 , C07C69/734 , C07C69/65 , C07C69/76 , C07C69/738 , C07C69/618 , C07C211/55 , C07C229/44 , C07C255/33 , C07C255/57 , C07C205/06 , C07C205/56 , C07C43/205
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