摘要:
This invention provides a luminescent composition comprising a polymer and at least one phosphorescent compound, characterized in that the electronic conjunction chain coefficient Z e of the main repeating minimum unit of the polymer falls within the following range: 0 e ≦ 2.00 (1) wherein the electronic conjunction chain coefficient Z e is defined as a slope obtained by linear approximation of function T m = T m (1/n e ) by the least square method wherein n e represents the number of conjugated electrons contained in repeating minimum units; and T m represents, for m-mer obtained by bonding repeating minimum units, the lowest triplet excitation energy in each m-mer when the number m is varied from 1 to 3 by one by one. Here in the number of conjugated electrons, only the conjugated electrons present in the main chain of the repeating minimum units are taken into consideration, provided that, when there are a plurality of main repeating minimum units, the minimum Z e is used.
摘要:
A polymer compound comprising as repeating units an optionally substituted fluorenediyl group and a phenylene group having one or more substituents, and comprising a repeating unit of the following formula (1) and/or a group of the following formula (2):
(in the formula (1), Ar 1 and Ar 2 represent an arylene group or di-valent aromatic heterocyclic group, and Ar 1 and Ar 2 may be the same or different.)
(in the formula (2), Ar 1 represents the same meaning as described above. Ar 3 represents an aryl group or mono-valent aromatic heterocyclic group.).
摘要:
This invention provides a luminescent composition comprising a polymer and at least one phosphorescent compound, characterized in that the electronic conjunction chain coefficient Z e of the main repeating minimum unit of the polymer falls within the following range: 0