摘要:
A light emitting device comprising an anode, a cathode, a light emitting layer disposed between the anode and the cathode, and a hole transporting layer disposed between the anode and the light emitting layer, wherein the light emitting layer is a layer comprising an iridium complex (A) and a heterocyclic compound constituted of typical elements (B), the hole transporting layer is a layer comprising a crosslinked body of a crosslinkable material, and the molecular weight (MA) of the iridium complex (A) and the molecular weight (MB) of the heterocyclic compound (B) satisfy the formula (M1-1) and the formula (M2-1): 2700 ≤ MA + MB ≤ 10000 0.35 ≤ MA / MB ≤ 3.00
摘要:
Disclosed is a metal complex represented by the following formula (1).
(In the formula, M represents a metal atom; R 1 -R 8 respectively represent a hydrogen atom, a halogen atom or a monovalent group; or alternatively R 3 and R 4 , or R 5 and R 6 may combine together to form a ring. In this connection, at least one of R 2 and R 7 is a group represented by the following formula (2):
wherein m represents an integer of 1-3; n represents an integer of 0-2; and Z 1 -Z 5 respectively represent a carbon atom or a nitrogen atom provided that at least two of Z 1 -Z 5 are nitrogen atoms. When one of Z 1 -Z 5 is a carbon atom, the hydrogen atom bonded to the carbon atom may be substituted by a substituent. The moiety expressed by the following formula (3):
represents a monoanionic bidentate ligand. In the formula (3), R x and R y respectively represent an atom bonded to the metal atom M, namely a carbon atom, an oxygen atom or a nitrogen atom.)
摘要:
A metal complex represented by the following formula (1) :
wherein R 1 to R 6 , R 8 and R 11 to R 20 represent a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an alkylthio group, an aryl group, an aryloxy group, an arylthio group, an arylalkyl group, an arylalkoxy group, an arylalkylthio group, an acyl group, an acyloxy group, an amide group, an acid imide group, an imine residue, a substituted amino group, a substituted silyl group, a substituted silyloxy group, a substituted silylthio group, a substituted silylamino group, a monovalent heterocyclic group, a heteroaryloxy group, a heteroarylthio group, an arylalkenyl group, an arylalkynyl group, a substituted carboxyl group or a cyano group; Z 1 to Z 5 represent -C(R*)= or a nitrogen atom, wherein R* represents a hydrogen atom or a substituent, provided that at least two of Z 1 to Z 5 are nitrogen atoms; m represents 1 or 2.
摘要:
To provide a light emitting device excellent in luminance life. A light emitting device having an anode, a cathode, a first organic layer disposed between the anode and the cathode and a second organic layer disposed between the anode and the cathode, wherein the first organic layer is a layer containing a compound represented by the formula (C-1), and the second organic layer is a layer containing a compound represented by the formula (C-1) and a cross-linked body of a crosslinkable material:
[wherein, Ring R 1C and Ring R 2C represent an aromatic hydrocarbon ring or an aromatic hetero ring. R C represents an oxygen atom, a sulfur atom or a group represented by the formula (C'-1).]
[wherein, Ring R 3C and Ring R 4C represent an aromatic hydrocarbon ring or an aromatic hetero ring. R C' represents a carbon atom, a silicon atom, a germanium atom, a tin atom or a lead atom.]
摘要:
Disclosed is a metal complex which has a central metal (M) selected from the group consisting of Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Cd, Hf, Ta, W, Re, Pt, Au and Hg. The metal complex has no halogen unidentate ligand. In the metal complex, the sum total of the square values of the orbital coefficients of the outermost d orbitals of the central metal comprises 1/3 or higher of the sum total of the square values of all of the atomic orbital coefficients in the highest occupied molecular orbital (HOMO) given by a computational scientific technique, the energy difference (S1-T1) between the minimum singlet excitation energy (S1) and the minimum triplet excitation energy (T1) given by a computational scientific technique falls within the range from 0.1 (eV) to 1.0 (eV) inclusive, and the oscillator strength (f) falls within the range from 0.005 and 1.0 inclusive.