摘要:
Disclosed is a metal complex represented by the following formula (1).
(In the formula, M represents a metal atom; R 1 -R 8 respectively represent a hydrogen atom, a halogen atom or a monovalent group; or alternatively R 3 and R 4 , or R 5 and R 6 may combine together to form a ring. In this connection, at least one of R 2 and R 7 is a group represented by the following formula (2):
wherein m represents an integer of 1-3; n represents an integer of 0-2; and Z 1 -Z 5 respectively represent a carbon atom or a nitrogen atom provided that at least two of Z 1 -Z 5 are nitrogen atoms. When one of Z 1 -Z 5 is a carbon atom, the hydrogen atom bonded to the carbon atom may be substituted by a substituent. The moiety expressed by the following formula (3):
represents a monoanionic bidentate ligand. In the formula (3), R x and R y respectively represent an atom bonded to the metal atom M, namely a carbon atom, an oxygen atom or a nitrogen atom.)
摘要:
A composition comprising a phosphorescent compound, and a compound having a structure containing three or more repeating units having a dipole moment dimension of 1.0 Debye or more connected in series, wherein, based on the total number of dimer structures composed of any two repeating units connected in series contained in the above-described structure, the proportion of the number of dimer structures in which the dimension D 2 of the dipole moment of the dimer structure, the dimension D 1a of the dipole moment of the first repeating unit constituting the dimer structure and the dimension D 1b of the dipole moment of the second repeating unit constituting the dimer structure satisfy a relation represented by the following formula (A): D 1 a D 2 and D 1 b D 2 is 50% or more.
摘要:
Disclosed is a composition comprising a compound having a pyrazine ring structure and a phosphorescent compound, wherein the compound having a pyrazine ring structure has a pyrazine ring structure represented by the general formula (1), (2) or (3):
wherein R and R 1 independently represent a hydrogen atom or a univalent group and multiple R's and multiple R 1 's may be the same as or different from one another. Also disclosed is a polymer having a residue derived from the phosphorescent compound and the pyrazine ring structure.
摘要翻译:公开了包含具有吡嗪环结构的化合物和磷光化合物的组合物,其中具有吡嗪环结构的化合物具有由通式(1),(2)或(3)表示的吡嗪环结构:其中R和 R 1独立地表示氢原子或一价基团,多个R和多个R 1可以彼此相同或不同。 还公开了具有衍生自磷光化合物和吡嗪环结构的残基的聚合物。
摘要:
To provide a light emitting device excellent in light emission efficiency. A light emitting device comprising a cathode, a first organic layer containing a compound having a cross-linkable group and a phosphorescent transition metal complex, a second organic layer containing a crosslinked body of the same compound as the above-described compound having a cross-linkable group, and an anode in this order, wherein the ratio of the above-described compound having a cross-linkable group contained in the above-described first organic layer is 2 to 10% by mass with respect to the total mass of the first organic layer. The compound having a cross-linkable group may be a compound having at least one cross-linkable group selected from Group of cross-linkable group consisting of cross-linkable groups represented by the formula (XL-1) to the formula (XL-19) .
(wherein, X represents a nitrogen atom or a group represented by =C(R X )-; R 1 represents an alkyl group having 4 or more carbon atoms; R 2 represents an alkyl group, a cycloalkyl group, an alkoxy group, a cycloalkoxy group, an aryl group, an aryloxy group, a monovalent heterocyclic group, a substituted amino group, or a halogen atom; ring A and ring B each independently represent an aromatic hydrocarbon ring or an aromatic heterocyclic ring; M represents a rhodium atom, a palladium atom, an iridium atom, or a platinum atom; n 1 represents an integer of 1 or more, n 2 represents an integer of 0 or more, and n 1 + n 2 is 2 or 3; A 1 -G 1 -A 2 represents an anionic bidentate ligand; A 1 and A 2 each independently represent a carbon atom, an oxygen atom, or a nitrogen atom; G 1 represents a single bond or an atomic group constituting a bidentate ligand together with A 1 and A 2 ).