公开(公告)号：EP2881436A4

公开(公告)日：2015-08-12

申请号：EP13825246

申请日：2013-07-31

申请人： TEIJIN LTD ,  KANEKA CORP

发明人： OKAMOTO HIROSHI ,  FUJIMOTO TOYOHISA

IPC分类号： C08L69/00 ,  C08F279/02 ,  C08L51/04

CPC分类号： C08L69/00 ,  C08F279/02 ,  C08L2201/02 ,  C08L2201/10 ,  C08L2207/53 ,  C08L51/04

公开(公告)号：EP2963075A4

公开(公告)日：2016-05-25

申请号：EP14756701

申请日：2014-02-21

申请人： TEIJIN LTD

发明人： IMAZATO KENTA ,  TAKEDA TSUYOSHI ,  OKAMOTO HIROSHI ,  MOTOYOSHI TETSUYA ,  TANI TAKUSHI ,  YAMANAKA KATSUHIRO

IPC分类号： C08G64/02 ,  C08L69/00 ,  F21S8/10

CPC分类号： C08G64/00 ,  C08G64/0208 ,  F21S41/20 ,  F21S43/20 ,  G02B1/041

摘要： A molded article such as a resin window or a lamp lens for vehicles which is formed from a polycarbonate and excellent in heat resistance, weather resistance, low water absorption, surface hardness and low-temperature impact properties. The molded article is formed from a polycarbonate which contains a unit (A) represented by the following formula (A) in an amount of 50 mol% or more based on the total of all recurring units and has a maximum impact energy of 20 J or more in a high-speed surface impact test based on ASTM D3763 in a -20°C environment and a brittle fracture rate of 50 % or less.

公开(公告)号：EP3135727A4

公开(公告)日：2017-05-03

申请号：EP15783907

申请日：2015-04-20

申请人： TEIJIN LTD

发明人： TANI TAKUSHI ,  OKAMOTO HIROSHI ,  YAMANAKA KATSUHIRO

IPC分类号： C08L69/00 ,  C08G63/64 ,  C08G64/02 ,  C08G64/30 ,  C08K5/00 ,  C08K5/3435 ,  C08K5/3472 ,  C08K5/49

CPC分类号： C08K5/3435 ,  C08G63/64 ,  C08G64/0208 ,  C08G64/305 ,  C08K5/1345 ,  C08K5/3475 ,  C08K5/526 ,  C08K13/00 ,  C08L69/00

摘要： A polycarbonate resin composition comprising a polycarbonate resin and 0.001 to 1 parts by weight of an N-R type (R represents an alkyl group) hindered amine-based optical stabilizer per 100 parts by weight of the polycarbonate resin, wherein the polycarbonate resin comprises 40 mol% or more of a recurring unit (A) represented by the following formula and satisfies the following formulas (i) to (v), and the resin composition has excellent heat resistance, a low water absorption coefficient and high transparency, and suppresses deterioration during long-term use: (i) a metal compound comprising a negative ion represented by the following formula (B) and a positive ion constituted by a metal is used as a polymerization catalyst in an amount of 1 × 10 -9 to 1 × 10 -5 molar equivalent relative to the total diol compounds used for polymerization; (ii) the specific viscosity measured with a methylene chloride solution at 20°C is 0.23 to 0.60; (iii) the glass transition temperature is 100°C to 160°C; (iv) the saturated water absorption coefficient is 2.5% or less; and (v) the relationship between the glass transition temperature (Tg°C) and the saturated water absorption coefficient (Wa%) satisfies the following formula (I): 2.5 ‰¤ Tw value = Tg × 0.04 ˆ’ Wa wherein R 1 is an alkylene group, a cycloalkylene group, or an arylalkylene group which has 1 to 22 carbon atoms and may be linear or branched.

摘要翻译： 一种聚碳酸酯树脂组合物，其中，相对于聚碳酸酯树脂100重量份，含有聚碳酸酯树脂和0.001〜1重量份NR型（R为烷基）受阻胺系光稳定剂的聚碳酸酯树脂组合物，其中，聚碳酸酯树脂含有40摩尔％ 或更多的由下式表示的重复单元（A）并且满足下式（i）至（v），并且该树脂组合物具有优异的耐热性，低吸水系数和高透明性，并且抑制长期 （1）作为聚合催化剂，使用含有下述式（B）所示的负离子和金属构成的正离子的金属化合物，其量为1×10 -9〜1×10 -3〜 相对于用于聚合的全部二醇化合物为5摩尔当量; （ii）用二氯甲烷溶液在20℃下测定的比粘度为0.23〜0.60， （iii）玻璃化转变温度为100℃至160℃; （iv）饱和吸水率为2.5％以下， （v）玻璃化转变温度（Tg℃）与饱和吸水率（Wa％）之间的关系满足下式（I）：2.5‰¤Tw= Tg×0.04'Wa其中R 1为 亚烷基，亚环烷基或具有1至22个碳原子且可以是直链或支链的芳基亚烷基。