公开(公告)号：EP0696633A1

公开(公告)日：1996-02-14

申请号：EP95305547.2

申请日：1995-08-08

申请人： TEXACO DEVELOPMENT CORPORATION

发明人： Sudhakar, Chakka ,  Dolfinger, Frank Jr. ,  Cesar, Max Raphael ,  Patel, Mahendra Somabhai

IPC分类号： C10G45/50 ,  B01J27/188 ,  B01J21/18

CPC分类号： B01J27/188 ,  B01J21/18 ,  C10G45/50

摘要： A process is disclosed for treating a charge hydrocarbon oil containing undesired aromatic components, sulphur and nitrogen compounds. The process comprises:
   maintaining a bed of a sulphided catalyst on an activated carbon support;
   passing a charge hydrocarbon feed in the presence of a gas selected from pure hydrogen and a gas mixture comprising greater than 60% by volume pure hydrogen into contact with said catalyst at hydrotreating conditions in order to effect hydrodearomatisation, hydrodesulphurisation and hydrodenitrogenation of the charge hydrocarbon feed;
   forming a product stream of hydrocarbon containing a lesser quantity of undesired aromatic components, sulphur and nitrogen, and
   recovering said product stream.
The process is characterised in that the sulphided catalyst comprises 0.1 to 15% by weight of nickel, from 1 to 50% by weight of tungsten and 0.01 to 10% by weight of phosphorus, and in that the activated carbon support has a BET surface area of 600 to 2000m/g, a pore volume for nitrogen of at least 0.3 cc/g and an average pore diameter of 12 to 100Å.

公开(公告)号：EP0582403A1

公开(公告)日：1994-02-09

申请号：EP93305734.1

申请日：1993-07-21

申请人： TEXACO DEVELOPMENT CORPORATION

发明人： Sudhakar, Chakka ,  Sandford, Gerald Glen ,  Dahlstrom, Phillip Landon ,  Patel, Mahendra Somabhai ,  Patmore, Edwin Lee

IPC分类号： C10G45/08 ,  B01J23/85

CPC分类号： B01J23/85 ,  B01J23/8871 ,  B01J23/8872 ,  C10G45/08

摘要： Hydrodesulfurization of cracked naphtha, with minimum attendant hydrogenation of olefins, is effected over a sulfided carbon support catalyst bearing (i) a non-noble Group VIII metal, (ii) a Group VI-B metal, and (iii) a metal of Group IA, II A, III A, or the lanthanide Group of rare earths.

摘要翻译： 裂化石脑油的加氢脱硫，最少伴随着烯烃的氢化，是通过硫化碳载体催化剂（i）非贵金属Ⅷ族金属，（ⅱ）ⅥB族金属和（ⅲ） IA，IIA，IIIA或稀土的镧系元素组。

公开(公告)号：EP0731156A3

公开(公告)日：1996-11-27

申请号：EP96301727.2

申请日：1996-03-07

申请人： TEXACO DEVELOPMENT CORPORATION

发明人： Sudhakar, Chakka

IPC分类号： C10G45/50 ,  B01J23/85

CPC分类号： C10G45/50 ,  B01J23/85 ,  B01J35/0026 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/108

摘要： A process for treating a charge hydrocarbon feed containing undesired aromatics, sulphur and nitrogen comprises:
   maintaining a sulphided catalyst bed comprising 0.1-15% by weight of one or more Group VIII metals selected from nickel, cobalt and iron; from 1-50% by weight of tungsten and/or from 1-20% by weight of molybdenum or chromium, and 0.01-10% by weight of zinc, on an activated carbon support, said support having a B.E.T. surface area of at least 600 m 2 /g, a pore volume of at least 0.3 cm 3 /g and an average pore diameter of at least 12 Angstroms;
   passing a charge hydrocarbon feed in the presence of a gas comprising greater than 60% by volume pure hydrogen into contact with said catalyst under hydrotreating conditions, thereby effecting hydrogenation, hydrodearomatisation, hydrodesulphurisation and hydrodenitrogenation of said feed and forming a hydrocarbon product stream containing a lesser concentration of undesired aromatics, sulphur and nitrogen, and
   recovering said product stream.

公开(公告)号：EP0582403B1

公开(公告)日：1997-12-10

申请号：EP93305734.1

申请日：1993-07-21

申请人： TEXACO DEVELOPMENT CORPORATION

发明人： Sudhakar, Chakka ,  Sandford, Gerald Glen ,  Dahlstrom, Phillip Landon ,  Patel, Mahendra Somabhai ,  Patmore, Edwin Lee

IPC分类号： C10G45/08 ,  B01J23/85

CPC分类号： B01J23/85 ,  B01J23/8871 ,  B01J23/8872 ,  C10G45/08

公开(公告)号：EP0731156A2

公开(公告)日：1996-09-11

申请号：EP96301727.2

申请日：1996-03-07

申请人： TEXACO DEVELOPMENT CORPORATION

发明人： Sudhakar, Chakka

IPC分类号： C10G45/50 ,  B01J23/85

CPC分类号： C10G45/50 ,  B01J23/85 ,  B01J35/0026 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/108

摘要： A process for treating a charge hydrocarbon feed containing undesired aromatics, sulphur and nitrogen comprises:
   maintaining a sulphided catalyst bed comprising 0.1-15% by weight of one or more Group VIII metals selected from nickel, cobalt and iron; from 1-50% by weight of tungsten and/or from 1-20% by weight of molybdenum or chromium, and 0.01-10% by weight of zinc, on an activated carbon support, said support having a B.E.T. surface area of at least 600 m 2 /g, a pore volume of at least 0.3 cm 3 /g and an average pore diameter of at least 12 Angstroms;
   passing a charge hydrocarbon feed in the presence of a gas comprising greater than 60% by volume pure hydrogen into contact with said catalyst under hydrotreating conditions, thereby effecting hydrogenation, hydrodearomatisation, hydrodesulphurisation and hydrodenitrogenation of said feed and forming a hydrocarbon product stream containing a lesser concentration of undesired aromatics, sulphur and nitrogen, and
   recovering said product stream.

摘要翻译： 一种用于治疗的电荷烃进料包含不期望的芳族化合物，硫和氮的方法包括：维护一个硫化的催化剂床，其包括0.1-15％重量的一种或多种VIII族金属的选自镍，钴和铁; 从重量的钨1-50％，和/或1至20重量％的钼或铬，和0.01-10％（重量）的锌，上活性炭载体，所述具有B.E.T.支撑 的至少600米<2> /克，至少0.3 CM <3> / g，且至少12埃的平均孔径的孔体积的表面积; 传递电荷的烃进料以气体包含大于60％的存在下，通过体积纯氢气接触到所述催化剂的加氢处理条件下，由此实现所述进料的加氢，hydrodearomatisation，加氢脱硫和加氢脱氮和形成含有较少的烃产物流 不期望的芳族化合物，硫和氮，并回收所述产物流的浓度。 茶

公开(公告)号：EP0696632A1

公开(公告)日：1996-02-14

申请号：EP95305546.4

申请日：1995-08-09

申请人： TEXACO DEVELOPMENT CORPORATION

发明人： Sudhakar, Chakka ,  Dolfinger, Frank, Jr. ,  Cesar, Max Raphael ,  Patel, Mahendra Somabhai ,  Fritz, Paul Otto

IPC分类号： C10G45/50 ,  B01J27/188 ,  B01J21/18 ,  B01J37/28

CPC分类号： B01J27/188 ,  B01J23/85 ,  C10G45/50

摘要： A process is disclosed for treating a charge hydrocarbon such as a naphtha or middle distillate hydrocarbon containing undesired aromatic components, sulphur and nitrogen compounds. The process comprises:
   maintaining a bed of metal sulphide catalyst comprising a non-noble metal of Group VIII and a metal of Group VIA on a carbon support;
   passing a charge hydrocarbon feed in the presence of hydrogen into contact with said metal sulphide catalyst at hydrotreating conditions in order to effect hydrodearomatisation, hydrodesulphurisation and hydrodenitrogenation of said charge hydrocarbon containing undesired aromatic components, sulphur and nitrogen compounds;
   forming a product stream of hydrocarbon containing lesser quantities of undesired aromatic components, sulphur and nitrogen, and
   recovering said product stream.
The process is characterised in that the carbon support is a phosphorus-treated carbon support prepared by heat treating mixtures of activated carbon and phosphorus compounds at temperatures greater than 450°C. It is further characterised in that the phosphorus in the phosphorus-treated carbon support exists predominantly as polyphosphate species bound to the carbon surface, being characterised by peaks between -5 and -30 ppm in the solid-state magic angle spinning ³¹P nuclear magnetic resonance spectrum.