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公开(公告)号：EP1489676A3
公开(公告)日：2005-05-25
申请号：EP04019941.6
申请日：1994-10-18
发明人： Surampudi, Subbarao , Narayanan, Sekharipuram R. , Vamos, Eugene , Frank, Harvey A. , Halpert, Gerald , Olah, George A. , Prakash, G.K. Surya Univ. of Southern California
CPC分类号： H01M4/8605 , H01M4/8853 , H01M4/8892 , H01M4/921 , H01M4/926 , H01M4/928 , H01M8/04119 , H01M8/04186 , H01M8/1004 , H01M8/1009 , H01M8/1023 , H01M8/1039 , H01M8/1041 , H01M8/1046 , H01M8/22 , H01M8/2455 , H01M2004/8684 , H01M2300/0082 , Y02P70/56
摘要： A liquid organic fuel cell is provided which employs a solid electrolyte membrane. An organic fuel, such as a methanol/water mixture, is circulated past an anode of a cell while oxygen or air is circulated past a cathode of the cell. The cell solid electrolyte membrane is preferably fabricated from Nafion™. Additionally, a method for improving the performance of carbon electrode structures for use in organic fuel cells is provided wherein a high surface-area carbon particle/Teflon™-binder structure is immersed within a Nafion™/methanol bath to impregnate the electrode with Nafion™. A method for fabricating an anode for use in a organic fuel cell is described wherein metal alloys are deposited onto the electrode in an electrodeposition solution containing perfluorooctanesulfonic acid. A fuel additive containing perfluorooctanesulfonic acid for use with fuel cells employing a sulfuric acid electrolyte is also disclosed. New organic fuels, namely, trimethoxymethane, dimethoxymethane, and trioxane are also described for use with either conventional or improved fuel cells.
摘要翻译： 提供一种操作具有阳极，阴极和电解质的直接进料型燃料电池的方法，其包括：使用由多层复合结构形成的膜 - 电极组件与阳极，阴极和固体聚合物 电解质膜; 以及将所述燃料基本上不含酸组分的液体有机甲醇燃料循环到所述膜电极组件的部分，以电化学发电。 优选地，所述膜电极组件的至少部分用亲水材料，优选特氟隆或Nafion浸渍。 此外，公开了一种方法，其包括：形成具有阳极，阴极和电解质的燃料电池; 以及使用在所述燃料电池中基本上不含酸性电解质的甲醇燃料从所述燃料电池电化学发电。
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公开(公告)号：EP1508931A1
公开(公告)日：2005-02-23
申请号：EP04019947.3
申请日：1994-10-18
发明人： Surampudi, Subbarao , Narayanan, Sekharipuram R. , Vamos, Eugene , Frank, Harvey A. , Halpert, Gerald , Olah, George A. , Prakash, G.K. Surya
CPC分类号： H01M4/8605 , H01M4/8853 , H01M4/8892 , H01M4/921 , H01M4/926 , H01M4/928 , H01M8/04119 , H01M8/04186 , H01M8/1004 , H01M8/1009 , H01M8/1023 , H01M8/1039 , H01M8/1041 , H01M8/1046 , H01M8/22 , H01M8/2455 , H01M2004/8684 , H01M2300/0082 , Y02P70/56
摘要： A liquid organic fuel cell is provided which employs a solid electrolyte membrane. An organic fuel, such as a methanol/water mixture, is circulated past an anode of a cell while oxygen or air is circulated past a cathode of the cell. The cell solid electrolyte membrane is preferably fabricated from Nafion™. Additionally, a method for improving the performance of carbon electrode structures for use in organic fuel cells is provided wherein a high surface-area carbon particle/Teflon™-binder structure is immersed within a Nafion™/methanol bath to impregnate the electrode with Nafion™. A method for fabricating an anode for use in a organic fuel cell is described wherein metal alloys are deposited onto the electrode in an electrodeposition solution containing perfluorooctanesulfonic acid. A fuel additive containing perfluorooctanesulfonic acid for use with fuel cells employing a sulfuric acid electrolyte is also disclosed. New organic fuels, namely, trimethoxymethane, dimethoxymethane, and trioxane are also described for use with either conventional or improved fuel cells.
摘要翻译： 提供一种使用固体电解质膜的液体有机燃料电池。 诸如甲醇/水混合物的有机燃料循环通过电池的阳极，同时氧气或空气循环通过电池的阴极。 细胞固体电解质膜优选由Nafion TM制造。 另外，提供了一种用于改善用于有机燃料电池的碳电极结构的性能的方法，其中将高表面积碳颗粒/ Teflon TM粘合剂结构浸入Nafion TM /甲醇浴中以用Nafion TM浸渍电极 。 描述了一种用于制造用于有机燃料电池的阳极的方法，其中将金属合金沉积在含有全氟辛烷磺酸的电沉积溶液中的电极上。 还公开了一种用于与使用硫酸电解质的燃料电池一起使用的全氟辛烷磺酸的燃料添加剂。 还描述了新的有机燃料，即三甲氧基甲烷，二甲氧基甲烷和三恶烷，用于常规或改进的燃料电池。
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3.发明公开Organic fuel cell with reduced crossover 失效Organische Brennstoffzelle mit gemindertemReaktantenübertritt
公开(公告)号：EP1498975A2
公开(公告)日：2005-01-19
申请号：EP04019945.7
申请日：1994-10-18
发明人： Surampudi, Subbarao , Narayanan, Sekharipuram R. , Vamos, Eugene , Frank, Harvey A. , Halpert, Gerald , Olah, George A. , Prakash, G.K. Surya
CPC分类号： H01M4/8605 , H01M4/8853 , H01M4/8892 , H01M4/921 , H01M4/926 , H01M4/928 , H01M8/04119 , H01M8/04186 , H01M8/1004 , H01M8/1009 , H01M8/1023 , H01M8/1039 , H01M8/1041 , H01M8/1046 , H01M8/22 , H01M8/2455 , H01M2004/8684 , H01M2300/0082 , Y02P70/56
摘要： A liquid organic fuel cell is provided which employs a solid electrolyte membrane. An organic fuel, such as a methanol/water mixture, is circulated past an anode of a cell while oxygen or air is circulated past a cathode of the cell. The cell solid electrolyte membrane is preferably fabricated from Nafion™. Additionally, a method for improving the performance of carbon electrode structures for use in organic fuel cells is provided wherein a high surface-area carbon particle/Teflon™-binder structure is immersed within a Nafion™/methanol bath to impregnate the electrode with Nafion™. A method for fabricating an anode for use in a organic fuel cell is described wherein metal alloys are deposited onto the electrode in an electrodeposition solution containing perfluorooctanesulfonic acid. A fuel additive containing perfluorooctanesulfonic acid for use with fuel cells employing a sulfuric acid electrolyte is also disclosed. New organic fuels, namely, trimethoxymethane, dimethoxymethane, and trioxane are also described for use with either conventional or improved fuel cells.
摘要翻译： 提供一种使用固体电解质膜的液体有机燃料电池。 诸如甲醇/水混合物的有机燃料循环通过电池的阳极，同时氧气或空气循环通过电池的阴极。 细胞固体电解质膜优选由Nafion TM制造。 另外，提供了一种用于改善用于有机燃料电池的碳电极结构的性能的方法，其中将高表面积碳颗粒/ Teflon TM粘合剂结构浸入Nafion TM /甲醇浴中以用Nafion TM浸渍电极 。 描述了一种用于制造用于有机燃料电池的阳极的方法，其中将金属合金沉积在含有全氟辛烷磺酸的电沉积溶液中的电极上。 还公开了一种用于与使用硫酸电解质的燃料电池一起使用的全氟辛烷磺酸的燃料添加剂。 还描述了新的有机燃料，即三甲氧基甲烷，二甲氧基甲烷和三恶烷，用于常规或改进的燃料电池。
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公开(公告)号：EP1489674A3
公开(公告)日：2005-01-12
申请号：EP04019940.8
申请日：1994-10-18
发明人： Surampudi, Subbarao , Narayanan, Sekharipuram R. , Vamos, Eugene , Frank, Harvey A. , Halpert, Gerald , Olah, George A. , Prakash, G.K. Surya
CPC分类号： H01M4/8605 , H01M4/8853 , H01M4/8892 , H01M4/921 , H01M4/926 , H01M4/928 , H01M8/04119 , H01M8/04186 , H01M8/1004 , H01M8/1009 , H01M8/1023 , H01M8/1039 , H01M8/1041 , H01M8/1046 , H01M8/22 , H01M8/2455 , H01M2004/8684 , H01M2300/0082 , Y02P70/56
摘要： A liquid organic fuel cell is provided which employs a solid electrolyte membrane. An organic fuel, such as a methanol/water mixture, is circulated past an anode of a cell while oxygen or air is circulated past a cathode of the cell. The cell solid electrolyte membrane is preferably fabricated from Nafion™. Additionally, a method for improving the performance of carbon electrode structures for use in organic fuel cells is provided wherein a high surface-area carbon particle/Teflon™-binder structure is immersed within a Nafion™/methanol bath to impregnate the electrode with Nafion™. A method for fabricating an anode for use in a organic fuel cell is described wherein metal alloys are deposited onto the electrode in an electrodeposition solution containing perfluorooctanesulfonic acid. A fuel additive containing perfluorooctanesulfonic acid for use with fuel cells employing a sulfuric acid electrolyte is also disclosed. New organic fuels, namely, trimethoxymethane, dimethoxymethane, and trioxane are also described for use with either conventional or improved fuel cells.
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公开(公告)号：EP1519432A3
公开(公告)日：2005-07-13
申请号：EP04019949.9
申请日：1994-10-18
发明人： Surampudi, Subbarao , Narayanan, Sekharipuram R. , Vamos, Eugene , Frank, Harvey A. , Halpert, Gerald , Olah, George A. , Prakash, G.K. Surya Univ. of Southern California
CPC分类号： H01M4/8605 , H01M4/8853 , H01M4/8892 , H01M4/921 , H01M4/926 , H01M4/928 , H01M8/04119 , H01M8/04186 , H01M8/1004 , H01M8/1009 , H01M8/1023 , H01M8/1039 , H01M8/1041 , H01M8/1046 , H01M8/22 , H01M8/2455 , H01M2004/8684 , H01M2300/0082 , Y02P70/56
摘要： A liquid organic fuel cell is provided which employs a solid electrolyte membrane. An organic fuel, such as a methanol/water mixture, is circulated past an anode of a cell while oxygen or air is circulated past a cathode of the cell. The cell solid electrolyte membrane is preferably fabricated from Nafion™. Additionally, a method for improving the performance of carbon electrode structures for use in organic fuel cells is provided wherein a high surface-area carbon particle/Teflon™-binder structure is immersed within a Nafion™/methanol bath to impregnate the electrode with Nafion™. A method for fabricating an anode for use in a organic fuel cell is described wherein metal alloys are deposited onto the electrode in an electrodeposition solution containing perfluorooctanesulfonic acid. A fuel additive containing perfluorooctanesulfonic acid for use with fuel cells employing a sulfuric acid electrolyte is also disclosed. New organic fuels, namely, trimethoxymethane, dimethoxymethane, and trioxane are also described for use with either conventional or improved fuel cells.
摘要翻译： 提供一种操作具有阳极，阴极和电解质的直接进料型燃料电池的方法，其包括：使用由多层复合结构形成的膜 - 电极组件与阳极，阴极和固体聚合物 电解质膜; 以及将所述燃料基本上不含酸组分的液体有机甲醇燃料循环到所述膜电极组件的部分，以电化学发电。 优选地，所述膜电极组件的至少部分用亲水材料，优选特氟隆或Nafion浸渍。 此外，公开了一种方法，其包括：形成具有阳极，阴极和电解质的燃料电池; 以及使用在所述燃料电池中基本上不含酸性电解质的甲醇燃料从所述燃料电池电化学发电。
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6.发明公开Organic fuel cell system and method of operation 失效Organisches Brennstoffzellensystem und dessen Betriebsverfahren
公开(公告)号：EP1507304A1
公开(公告)日：2005-02-16
申请号：EP04019948.1
申请日：1994-10-18
发明人： Surampudi, Subbarao , Narayanan, Sekharipuram R. , Vamos, Eugene , Frank, Harvey A. , Halpert, Gerald , Olah, George A. , Prakash, G.K. Surya
CPC分类号： H01M4/8605 , H01M4/8853 , H01M4/8892 , H01M4/921 , H01M4/926 , H01M4/928 , H01M8/04119 , H01M8/04186 , H01M8/1004 , H01M8/1009 , H01M8/1023 , H01M8/1039 , H01M8/1041 , H01M8/1046 , H01M8/22 , H01M8/2455 , H01M2004/8684 , H01M2300/0082 , Y02P70/56
摘要： A liquid organic fuel cell is provided which employs a solid electrolyte membrane. An organic fuel, such as a methanol/water mixture, is circulated past an anode of a cell while oxygen or air is circulated past a cathode of the cell. The cell solid electrolyte membrane is preferably fabricated from Nafion™. Additionally, a method for improving the performance of carbon electrode structures for use in organic fuel cells is provided wherein a high surface-area carbon particle/Teflon™-binder structure is immersed within a Nafion™/methanol bath to impregnate the electrode with Nafion™. A method for fabricating an anode for use in a organic fuel cell is described wherein metal alloys are deposited onto the electrode in an electrodeposition solution containing perfluorooctanesulfonic acid. A fuel additive containing perfluorooctanesulfonic acid for use with fuel cells employing a sulfuric acid electrolyte is also disclosed. New organic fuels, namely, trimethoxymethane, dimethoxymethane, and trioxane are also described for use with either conventional or improved fuel cells.
摘要翻译： 提供一种使用固体电解质膜的液体有机燃料电池。 诸如甲醇/水混合物的有机燃料循环通过电池的阳极，同时氧气或空气循环通过电池的阴极。 细胞固体电解质膜优选由Nafion TM制造。 另外，提供了一种用于改善用于有机燃料电池的碳电极结构的性能的方法，其中将高表面积碳颗粒/ Teflon TM粘合剂结构浸入Nafion TM /甲醇浴中以用Nafion TM浸渍电极 。 描述了一种用于制造用于有机燃料电池的阳极的方法，其中将金属合金沉积在含有全氟辛烷磺酸的电沉积溶液中的电极上。 还公开了一种用于与使用硫酸电解质的燃料电池一起使用的全氟辛烷磺酸的燃料添加剂。 还描述了新的有机燃料，即三甲氧基甲烷，二甲氧基甲烷和三恶烷，用于常规或改进的燃料电池。
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公开(公告)号：EP1498975A3
公开(公告)日：2005-01-26
申请号：EP04019945.7
申请日：1994-10-18
发明人： Surampudi, Subbarao , Narayanan, Sekharipuram R. , Vamos, Eugene , Frank, Harvey A. , Halpert, Gerald , Olah, George A. , Prakash, G.K. Surya
CPC分类号： H01M4/8605 , H01M4/8853 , H01M4/8892 , H01M4/921 , H01M4/926 , H01M4/928 , H01M8/04119 , H01M8/04186 , H01M8/1004 , H01M8/1009 , H01M8/1023 , H01M8/1039 , H01M8/1041 , H01M8/1046 , H01M8/22 , H01M8/2455 , H01M2004/8684 , H01M2300/0082 , Y02P70/56
摘要： A liquid organic fuel cell is provided which employs a solid electrolyte membrane. An organic fuel, such as a methanol/water mixture, is circulated past an anode of a cell while oxygen or air is circulated past a cathode of the cell. The cell solid electrolyte membrane is preferably fabricated from Nafion™. Additionally, a method for improving the performance of carbon electrode structures for use in organic fuel cells is provided wherein a high surface-area carbon particle/Teflon™-binder structure is immersed within a Nafion™/methanol bath to impregnate the electrode with Nafion™. A method for fabricating an anode for use in a organic fuel cell is described wherein metal alloys are deposited onto the electrode in an electrodeposition solution containing perfluorooctanesulfonic acid. A fuel additive containing perfluorooctanesulfonic acid for use with fuel cells employing a sulfuric acid electrolyte is also disclosed. New organic fuels, namely, trimethoxymethane, dimethoxymethane, and trioxane are also described for use with either conventional or improved fuel cells.
摘要翻译： 提供了采用固体电解质膜的液体有机燃料电池。 有机燃料如甲醇/水混合物循环通过电池的阳极，而氧气或空气循环通过电池的阴极。 电池固体电解质膜优选由Nafion TM制造。 此外，提供了用于改善用于有机燃料电池的碳电极结构的性能的方法，其中将高表面积碳颗粒/特氟隆TM粘合剂结构浸入Nafion TM /甲醇浴中以用Nafion TM浸渍电极 。 描述了用于制造用于有机燃料电池的阳极的方法，其中金属合金在包含全氟辛烷磺酸的电沉积溶液中沉积到电极上。 还公开了一种含有全氟辛烷磺酸的燃料添加剂，用于使用硫酸电解质的燃料电池。 还描述了新的有机燃料，即三甲氧基甲烷，二甲氧基甲烷和三恶烷与常规或改进的燃料电池一起使用。
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公开(公告)号：EP1519432A2
公开(公告)日：2005-03-30
申请号：EP04019949.9
申请日：1994-10-18
发明人： Surampudi, Subbarao , Narayanan, Sekharipuram R. , Vamos, Eugene , Frank, Harvey A. , Halpert, Gerald , Olah, George A. , Prakash, G.K. Surya Univ. of Southern California
CPC分类号： H01M4/8605 , H01M4/8853 , H01M4/8892 , H01M4/921 , H01M4/926 , H01M4/928 , H01M8/04119 , H01M8/04186 , H01M8/1004 , H01M8/1009 , H01M8/1023 , H01M8/1039 , H01M8/1041 , H01M8/1046 , H01M8/22 , H01M8/2455 , H01M2004/8684 , H01M2300/0082 , Y02P70/56
摘要： A liquid organic fuel cell is provided which employs a solid electrolyte membrane. An organic fuel, such as a methanol/water mixture, is circulated past an anode of a cell while oxygen or air is circulated past a cathode of the cell. The cell solid electrolyte membrane is preferably fabricated from Nafion™. Additionally, a method for improving the performance of carbon electrode structures for use in organic fuel cells is provided wherein a high surface-area carbon particle/Teflon™-binder structure is immersed within a Nafion™/methanol bath to impregnate the electrode with Nafion™. A method for fabricating an anode for use in a organic fuel cell is described wherein metal alloys are deposited onto the electrode in an electrodeposition solution containing perfluorooctanesulfonic acid. A fuel additive containing perfluorooctanesulfonic acid for use with fuel cells employing a sulfuric acid electrolyte is also disclosed. New organic fuels, namely, trimethoxymethane, dimethoxymethane, and trioxane are also described for use with either conventional or improved fuel cells.
摘要翻译： 提供了采用固体电解质膜的液体有机燃料电池。 有机燃料如甲醇/水混合物循环通过电池的阳极，而氧气或空气循环通过电池的阴极。 电池固体电解质膜优选由Nafion TM制造。 此外，提供了用于改善用于有机燃料电池的碳电极结构的性能的方法，其中将高表面积碳颗粒/特氟隆TM粘合剂结构浸入Nafion TM /甲醇浴中以用Nafion TM浸渍电极 。 描述了用于制造用于有机燃料电池的阳极的方法，其中金属合金在包含全氟辛烷磺酸的电沉积溶液中沉积到电极上。 还公开了一种含有全氟辛烷磺酸的燃料添加剂，用于使用硫酸电解质的燃料电池。 还描述了新的有机燃料，即三甲氧基甲烷，二甲氧基甲烷和三恶烷与常规或改进的燃料电池一起使用。
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9.发明公开Organic fuel cell with ion exchange membrane 失效Organische Brennstoffzelle mit ionenaustauschender Membran
公开(公告)号：EP1508930A1
公开(公告)日：2005-02-23
申请号：EP04019946.5
申请日：1994-10-18
发明人： Surampudi, Subbarao , Narayanan, Sekharipuram R. , Vamos, Eugene , Frank, Harvey A. , Halpert, Gerald , Olah, George A. , Prakash, G.K. Surya
CPC分类号： H01M4/8605 , H01M4/8853 , H01M4/8892 , H01M4/921 , H01M4/926 , H01M4/928 , H01M8/04119 , H01M8/04186 , H01M8/1004 , H01M8/1009 , H01M8/1023 , H01M8/1039 , H01M8/1041 , H01M8/1046 , H01M8/22 , H01M8/2455 , H01M2004/8684 , H01M2300/0082 , Y02P70/56
摘要： A liquid organic fuel cell is provided which employs a solid electrolyte membrane. An organic fuel, such as a methanol/water mixture, is circulated past an anode of a cell while oxygen or air is circulated past a cathode of the cell. The cell solid electrolyte membrane is preferably fabricated from Nafion™. Additionally, a method for improving the performance of carbon electrode structures for use in organic fuel cells is provided wherein a high surface-area carbon particle/Teflon™-binder structure is immersed within a Nafion™/methanol bath to impregnate the electrode with Nafion™. A method for fabricating an anode for use in a organic fuel cell is described wherein metal alloys are deposited onto the electrode in an electrodeposition solution containing perfluorooctanesulfonic acid. A fuel additive containing perfluorooctanesulfonic acid for use with fuel cells employing a sulfuric acid electrolyte is also disclosed. New organic fuels, namely, trimethoxymethane, dimethoxymethane, and trioxane are also described for use with either conventional or improved fuel cells.
摘要翻译： 提供一种使用固体电解质膜的液体有机燃料电池。 诸如甲醇/水混合物的有机燃料循环通过电池的阳极，同时氧气或空气循环通过电池的阴极。 细胞固体电解质膜优选由Nafion TM制造。 另外，提供了一种用于改善用于有机燃料电池的碳电极结构的性能的方法，其中将高表面积碳颗粒/ Teflon TM粘合剂结构浸入Nafion TM /甲醇浴中以用Nafion TM浸渍电极 。 描述了一种用于制造用于有机燃料电池的阳极的方法，其中将金属合金沉积在含有全氟辛烷磺酸的电沉积溶液中的电极上。 还公开了一种用于与使用硫酸电解质的燃料电池一起使用的全氟辛烷磺酸的燃料添加剂。 还描述了新的有机燃料，即三甲氧基甲烷，二甲氧基甲烷和三恶烷，用于常规或改进的燃料电池。
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10.发明公开
公开(公告)号：EP1507303A1
公开(公告)日：2005-02-16
申请号：EP04019943.2
申请日：1994-10-18
发明人： Surampudi, Subbarao , Narayanan, Sekharipuram R. , Vamos, Eugene , Frank, Harvey A. , Halpert, Gerald , Olah, George A. , Prakash, G.K. Surya
CPC分类号： H01M4/8605 , H01M4/8853 , H01M4/8892 , H01M4/921 , H01M4/926 , H01M4/928 , H01M8/04119 , H01M8/04186 , H01M8/1004 , H01M8/1009 , H01M8/1023 , H01M8/1039 , H01M8/1041 , H01M8/1046 , H01M8/22 , H01M8/2455 , H01M2004/8684 , H01M2300/0082 , Y02P70/56
摘要： A liquid organic fuel cell is provided which employs a solid electrolyte membrane. An organic fuel, such as a methanol/water mixture, is circulated past an anode of a cell while oxygen or air is circulated past a cathode of the cell. The cell solid electrolyte membrane is preferably fabricated from Nafion™. Additionally, a method for improving the performance of carbon electrode structures for use in organic fuel cells is provided wherein a high surface-area carbon particle/Teflon™-binder structure is immersed within a Nafion™/methanol bath to impregnate the electrode with Nafion™. A method for fabricating an anode for use in a organic fuel cell is described wherein metal alloys are deposited onto the electrode in an electrodeposition solution containing perfluorooctanesulfonic acid. A fuel additive containing perfluorooctanesulfonic acid for use with fuel cells employing a sulfuric acid electrolyte is also disclosed. New organic fuels, namely, trimethoxymethane, dimethoxymethane, and trioxane are also described for use with either conventional or improved fuel cells.
摘要翻译： 提供一种使用固体电解质膜的液体有机燃料电池。 诸如甲醇/水混合物的有机燃料循环通过电池的阳极，同时氧气或空气循环通过电池的阴极。 细胞固体电解质膜优选由Nafion TM制造。 另外，提供了一种用于改善用于有机燃料电池的碳电极结构的性能的方法，其中将高表面积碳颗粒/ Teflon TM粘合剂结构浸入Nafion TM /甲醇浴中以用Nafion TM浸渍电极 。 描述了一种用于制造用于有机燃料电池的阳极的方法，其中将金属合金沉积在含有全氟辛烷磺酸的电沉积溶液中的电极上。 还公开了一种用于与使用硫酸电解质的燃料电池一起使用的全氟辛烷磺酸的燃料添加剂。 还描述了新的有机燃料，即三甲氧基甲烷，二甲氧基甲烷和三恶烷，用于常规或改进的燃料电池。
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