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1.发明公开Li-Ni COMPOSITE OXIDE PARTICLE POWDER AND PROCESS FOR PRODUCING SAME, AND NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY 有权LI-NI MISCHOXIDPARTIKELPULVER及其制造方法相同，并且二次电池的非水电解质
公开(公告)号：EP2698351A4
公开(公告)日：2014-10-01
申请号：EP12770752
申请日：2012-04-12
申请人： TODA KOGYO CORP
CPC分类号： C01D15/02 , C01G53/42 , C01G53/50 , C01P2002/52 , C01P2004/04 , C01P2004/61 , C01P2006/12 , C01P2006/80 , H01M4/505 , H01M4/525
摘要： The present invention provides lithium composite compound particles having good high-temperature storage property and excellent cycle characteristics as an active substance for a non-aqueous electrolyte secondary battery, and a secondary battery using the lithium composite compound particles. The Li-Ni composite oxide particles for a non-aqueous electrolyte secondary battery according to the present invention have a BET specific surface area of 0.05 to 0.8 m 2 /g; an atomic ratio (Ma/Ni) of a concentration of an amphoteric metal to a concentration of Ni on an outermost surface of the respective Li-Ni composite oxide particles is 2 to 6; and the concentration of the amphoteric metal on the outermost surface of the respective Li-Ni composite oxide particles is higher than a concentration of the amphoteric metal at a position spaced by 50 nm from the outermost surface toward a center of the respective Li-Ni composite oxide particles.
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2.发明公开LI-NI-BASED COMPOSITE OXIDE PARTICLE POWDER FOR RECHARGEABLE BATTERY WITH NONAQUEOUS ELCTROLYTE, PROCESS FOR PRODUCING THE POWDER, AND RECHARGEABLE BATTERY WITH NONAQUEOUS ELECTROLYTE 有权VERBUNDOXIDPARTIKELPULVER ON LI-NI-BASE与水游离电解液，用于生产无水ELEKTROLYT粉末与电池的电池
公开(公告)号：EP2214234A4
公开(公告)日：2012-03-21
申请号：EP08849214
申请日：2008-11-11
申请人： TODA KOGYO CORP
发明人： KAJIYAMA AKIHISA , KIKUYA KAZUHIKO , SANTOKI TERUAKI , SASAKI OSAMU , NAKAMURA SATOSHI , IMAHASHI TAIKI , SADAMURA HIDEAKI
CPC分类号： H01M4/48 , C01F7/141 , C01G45/1228 , C01G51/50 , C01G53/00 , C01G53/42 , C01G53/50 , C01P2002/52 , C01P2002/54 , C01P2004/03 , C01P2004/61 , C01P2004/84 , C01P2006/32 , C01P2006/40 , H01M4/505 , H01M4/525 , H01M10/052
摘要： The present invention relates to Li-Ni-based composite oxide particles comprising Mn, and Co and/or Al, wherein Co and Al are uniformly dispersed within the particles, and Mn is present with a gradient of its concentration in a radial direction of the respective particles such that a concentration of Mn on a surface of the respective particles is higher than that at a central portion thereof. The Li-Ni-based composite oxide particles can be produced by allowing an oxide and a hydroxide comprising Mn to mechanically adhere to Li-Ni-based oxide comprising Co and/or Al; and then heat-treating the obtained material at a temperature of not lower than 400°C and not higher than 1,000°C. The Li-Ni-based composite oxide particles of the present invention are improved in thermal stability and alkalinity.
摘要翻译： 本发明涉及包含Mn和Co和/或Al，worin钴和铝的Li-Ni类复合氧化物颗粒均匀地分散在颗粒内，Mn为存在与它的浓度的梯度，在该径向方向上 检查respectivement颗粒没有Mn的respectivement颗粒的表面上的浓度是在中心部分高于其。 的Li-Ni类复合氧化物颗粒可以通过允许对氧化物和氢氧化物，包括Mn对机械附着来制造Li-Ni类氧化物包含Co和/或Al; 然后热处理该材料获得在不低于400℃的温度和不高于1000℃ 本发明的基于Li-Ni类复合氧化物颗粒粉末的热稳定性和碱度提高。
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3.发明公开POWDER OF LITHIUM COMPLEX COMPOUND PARTICLES, METHOD FOR PRODUCING THE SAME, AND NONAQUEOUS ELECTROLYTE SECONDARY CELL 有权粉复合锂基复合颗粒的生产方法和二次电池用无水ELEKTROLYT
公开(公告)号：EP2368851A4
公开(公告)日：2015-05-13
申请号：EP09830210
申请日：2009-12-03
申请人： TODA KOGYO CORP
IPC分类号： C01G53/00 , C01B35/12 , H01M4/1391 , H01M4/525 , H01M10/052 , H01M10/0566
CPC分类号： H01M4/525 , C01G53/42 , C01P2002/52 , C01P2002/72 , C01P2004/04 , C01P2004/61 , C01P2006/12 , C01P2006/40 , C01P2006/80 , H01M4/1391 , H01M10/052 , H01M10/0566 , Y02E60/122 , Y02P70/54
摘要： The present invention relates to lithium composite compound particles having a composition represented by the formula: Li 1+x Ni 1-y-z Co y M z O 2 (M = B or Al), wherein the lithium composite compound particles have an ionic strength ratio A (LiO - /NiO 2 - ) of not more than 0.3 and an ionic strength ratio B (Li 3 CO 3 + /Ni + ) of not more than 20 as measured on a surface of the respective lithium composite compound particles using a time-of-flight secondary ion mass spectrometer. The lithium composite compound particles of the present invention can be used as a positive electrode active substance of a secondary battery which has good cycle characteristics and an excellent high-temperature storage property.
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4.发明公开
公开(公告)号：EP2581343A4
公开(公告)日：2015-05-13
申请号：EP11792480
申请日：2011-06-08
申请人： TODA KOGYO CORP
CPC分类号： H01M4/525 , C01G53/50 , C01P2004/03 , C01P2004/61 , C01P2006/12 , C01P2006/80 , H01M4/505 , Y02E60/122 , Y02P70/54
摘要： The present invention aims to provide lithium composite compound particles which can exhibit good cycle characteristics and an excellent high-temperature storage property when used as a positive electrode active substance of a secondary battery, and a secondary battery using the lithium composite compound particles. The present invention relates to lithium composite compound particles having a composition represented by the compositional formula: Li 1+x Ni 1-y-z-a Co y Mn z M a O 2 , in which the lithium composite compound particles have an ionic strength ratio A (LiO - /NiO 2 - ) of not more than 0.5 and an ionic strength ratio B (Li 3 CO 3 + /Ni + ) of not more than 20 as measured on a surface of the respective lithium composite compound particles using a time-of-flight secondary ion mass spectrometer.
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