摘要:
The present invention relates to a positive electrode active substance for non-aqueous electrolyte secondary batteries which comprises particles comprising a polyanionic compound and carbon, and a lipophilic treatment agent with which the respective particles are coated, wherein the positive electrode active substance has an average particle diameter of 1 to 50 µm. The positive electrode active substance preferably has an oil absorption of not more than 20 mL/100 g. The positive electrode active substance according to the present invention exhibits a good compatibility with a resin and is excellent in packing property and dispersibility in the resin, and therefore can provide an electrode sheet in which the positive electrode active substance is filled with a high packing density.
摘要:
The present invention relates to Li-Ni-based composite oxide particles comprising Mn, and Co and/or Al, wherein Co and Al are uniformly dispersed within the particles, and Mn is present with a gradient of its concentration in a radial direction of the respective particles such that a concentration of Mn on a surface of the respective particles is higher than that at a central portion thereof. The Li-Ni-based composite oxide particles can be produced by allowing an oxide and a hydroxide comprising Mn to mechanically adhere to Li-Ni-based oxide comprising Co and/or Al; and then heat-treating the obtained material at a temperature of not lower than 400°C and not higher than 1,000°C. The Li-Ni-based composite oxide particles of the present invention are improved in thermal stability and alkalinity.
摘要:
The present invention relates to Li-Ni composite oxide particles that exhibit a high initial discharge capacity and are excellent in thermal stability when used as a positive electrode active substance for non-aqueous electrolyte secondary batteries, and a process for producing the Li-Ni composite oxide particles. The Li-Ni composite oxide particles of the present invention have a composition of Li x Ni 1-y-a-b Co y M1 a M2 b O 2 wherein x, y, a and b represent 1.00 ‰¤ x ‰¤ 1.10; 0
摘要:
The present invention provides lithium composite compound particles having good high-temperature storage property and excellent cycle characteristics as an active substance for a non-aqueous electrolyte secondary battery, and a secondary battery using the lithium composite compound particles. The Li-Ni composite oxide particles for a non-aqueous electrolyte secondary battery according to the present invention have a BET specific surface area of 0.05 to 0.8 m 2 /g; an atomic ratio (Ma/Ni) of a concentration of an amphoteric metal to a concentration of Ni on an outermost surface of the respective Li-Ni composite oxide particles is 2 to 6; and the concentration of the amphoteric metal on the outermost surface of the respective Li-Ni composite oxide particles is higher than a concentration of the amphoteric metal at a position spaced by 50 nm from the outermost surface toward a center of the respective Li-Ni composite oxide particles.
摘要:
The present invention relates to Li-Ni composite oxide particles having a composition of Li x (Ni y Co 2(1-y)/5 Mn 3(1-y)/5 ) 1-z M z O 2 wherein x, y and z represent 1.00 ‰¤ x ‰¤ 1.10; 0.65
摘要:
The present invention provides lithium manganate which has a high output and is excellent in high-temperature stability. The present invention relates to lithium manganate particles which are produced by mixing a lithium compound, a manganese compound, a Y compound and an A compound with each other and then calcining the resulting mixture, and have a composition represented by the following chemical formula 1 and an average secondary particle diameter (D 50 ) of 1 to 15 µm, €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ(Chemical Formula)€ƒ€ƒ€ƒ€ƒ€ƒLi 1+x Mn 2-x-y Y y O 4 + zA in which Y is at least one element selected from the group consisting of Al and Mg; A is a sintering aid element having a melting point of not higher than 850°C; x and y satisfy 0.03 ‰¤ x s 0.15 and 0 ‰¤ y ‰¤ 0.20, respectively; z is in the range of 0 to 2.5 mol% based on Mn, wherein the lithium manganate particles have a sulfur content of not more than 100 ppm.
摘要翻译:本发明提供的锰酸锂,其具有高输出且具有优异的高温稳定性。 本发明涉及的锂其通过混合锂化合物,锰化合物,Y化合物和在海誓山盟的化合物,然后煅烧所得混合物产生的锰颗粒,以及具有由以下化学式1表示的组合物和 的平均二次粒子直径为1至15微米(D 50),€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ(化学式)€ƒ€ƒ€ƒ€ƒ€ƒLi1 + X的Mn 2 其中Y是选自Al和Mg的组中的至少一种元素Y-XY Y 2 O 4 + Z A; A是具有不高于850℃的熔点的烧结助剂元素; x和y满足12:03‰¤个S 12:15 0‰¤ý‰分别¤0:20; z是0〜2.5摩尔%,基于锰,worin锰酸锂颗粒具有不超过100ppm的硫含量的范围内。
摘要:
The present invention relates to lithium manganate particles having a primary particle diameter of 1 to 8 µm and forming substantially single-phase particles, which have a composition represented by the following chemical formula: €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒLi 1+x Mn 2-x-y Y1 y O 4 + Y2 in which Y1 is at least one element selected from the group consisting of Ni, Co, Mg, Fe, Al, Cr and Ti; Y2 is P and is present in an amount of 0.01 to 0.6 mol% based on Mn; and x and y satisfy 0.03 ‰¤ x ‰¤ 0.15 and 0.05 ‰¤ y ‰¤ 0.20, respectively, and which lithium manganate particles have a specific surface area of the lithium manganate particles of 0.3 to 0.9 m 2 /g (as measured by BET method); and have an average particle diameter (D 50 ) of the lithium manganate particles of 3 to 10 µm. A positive electrode active substance of a lithium ion secondary battery using the lithium manganate particles of the present invention has a high output and is excellent in high-temperature stability.