Lithium iron oxide, synthesis of the same, and lithium cell utilizing the same
    3.
    发明公开
    Lithium iron oxide, synthesis of the same, and lithium cell utilizing the same 失效
    Lithiumeisenoxyd,Verfahren zu seiner Herstellung und eine dieses Oxyd verwendende Lithiumzelle

    公开(公告)号:EP0728702A1

    公开(公告)日:1996-08-28

    申请号:EP96102851.1

    申请日:1996-02-26

    IPC分类号: C01G49/00

    摘要: A method of synthesizing a lithium iron oxide applicable for an active material of lithium batteries is disclosed. The method includes a step of heating a starting material, which comprises an iron(III) oxyhydroxide and a lithium compound, in a water vapor-containing atmosphere to yield a lithium iron oxide. An example of the iron(III) oxyhydroxide is γ-FeOOH, whereas any one or mixture of Li 2 O, LiOH, and LiOH·H 2 O is used as the lithium compound. The heating temperature is not higher than 350°C and the water vapor pressure is lower than the saturated water vapor pressure at the heating temperature. The method preferably includes a step of immersing the reaction product obtained by the heating step in water having a temperature of not higher than 30°C.

    摘要翻译: 公开了适用于锂电池的活性物质的锂铁氧化物的合成方法。 该方法包括在含水蒸汽的气氛中加热包含羟基氧化铁(III)和锂化合物的原料的步骤,得到氧化铁锂。 羟基氧化铁(III)的实例是γ-FeOOH,而Li 2 O,LiOH和LiOH.H 2 O的任何一种或其混合物用作锂化合物。 加热温度不高于350℃,水蒸气压低于加热温度下的饱和水蒸气压。 该方法优选包括将通过加热步骤获得的反应产物浸入温度不高于30℃的水中的步骤。

    Lithium ion-conductive solid electrolyte and method for producing the same
    5.
    发明公开
    Lithium ion-conductive solid electrolyte and method for producing the same 失效
    锂离子传导性固体电解质及其制造方法

    公开(公告)号:EP0994071A3

    公开(公告)日:2000-05-24

    申请号:EP00100203.9

    申请日:1997-04-14

    摘要: A method for producing an electrochemically advantageous lithium ion-conductive solid electrolyte with high ionic conductivity, low electronic conduction and electrochemical stability is disclosed. The method comprises the steps of synthesizing lithium sulfide by reacting lithium hydroxide with a gaseous sulfur source at a temperature of not less than 130°C and not more than 445°C, thermally melting plural compounds containing at least silicon sulfide and the synthesized lithium sulfide, and cooling the molten mixture. The silicon sulfide is synthesized by the steps of adding a silicon powder to molten sulfur while stirring to disperse the silicon powder in the molten sulfur and heating the silicon powder-dispersed sulfur in a reaction chamber under reduced pressure.

    摘要翻译: 公开了一种用于生产具有高离子电导率,低电子传导性和电化学稳定性的电化学有利的锂离子传导固体电解质的方法。 该方法包括以下步骤:通过使氢氧化锂与气态硫源在不低于130℃且不高于445℃的温度下反应,将至少含有硫化硅的多种化合物和合成的硫化锂 ,并冷却熔融混合物。 通过在搅拌下将硅粉添加到熔融硫中以将硅粉分散在熔融硫中并在减压下将硅粉分散硫加热到反应室中来合成硫化硅。