公开(公告)号：EP0644600B1

公开(公告)日：1999-04-28

申请号：EP94114435.4

申请日：1994-09-14

申请人： TOHOKU ELECTRIC POWER CO., INC. ,  SUMITOMO ELECTRIC INDUSTRIES, LIMITED ,  MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD. ,  INTERNATIONAL SUPERCONDUCTIVITY TECHNOLOGY CENTER

发明人： Isawa, Kazuyuki ,  Yamamoto, Ayako ,  Itoh, Makoto ,  Adachi, Seiji ,  Yamauchi, Hisao

IPC分类号： H01L39/12

CPC分类号： H01L39/126 ,  Y10S505/739 ,  Y10S505/776 ,  Y10S505/785

公开(公告)号：EP0644600A3

公开(公告)日：1996-12-18

申请号：EP94114435.4

申请日：1994-09-14

申请人： TOHOKU ELECTRIC POWER CO., INC. ,  SUMITOMO ELECTRIC INDUSTRIES, LIMITED ,  MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD. ,  INTERNATIONAL SUPERCONDUCTIVITY TECHNOLOGY CENTER

发明人： Isawa, Kazuyuki ,  Yamamoto, Ayako ,  Itoh, Makoto ,  Adachi, Seiji ,  Yamauchi, Hisao

IPC分类号： H01L39/12

CPC分类号： H01L39/126 ,  Y10S505/739 ,  Y10S505/776 ,  Y10S505/785

摘要： The oxide superconductor according to the present invention is represented by (Hg 1-x Pb x )Ba 2 Ca 2 Cu 3 O δ (0.08 ≦ x ≦ 0.41, 7.625 ≦ δ ≦ 9.15), and has a crystal structure in which a lamination unit of (Hg, Pb)O z -BaO-CuO 2 -Ca-CuO 2 -Ca-CuO 2 -BaO is laminated in a c-axial direction of the crystal structure (0.625 ≦ z ≦ 2.15). Further, the method of manufacturing an oxide superconductor, according to the present invention, includes the steps of: mixing material powders of HgO, PbO, BaO, CaO and CuO at a mole ratio of (Hg 1-x Pb x ):Ba:Ca:Cu = a:2:b:c (1 ≦ a ≦ 2.5, 2 ≦ b ≦ 3, 2.5 ≦ c ≦ 4) and compression-molding the mixture powder into a compact; and subjecting the compact to a thermal treatment at 600-750°C.

公开(公告)号：EP0644600A2

公开(公告)日：1995-03-22

申请号：EP94114435.4

申请日：1994-09-14

申请人： TOHOKU ELECTRIC POWER CO., INC. ,  SUMITOMO ELECTRIC INDUSTRIES, LIMITED ,  MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD. ,  INTERNATIONAL SUPERCONDUCTIVITY TECHNOLOGY CENTER

发明人： Isawa, Kazuyuki ,  Yamamoto, Ayako ,  Itoh, Makoto ,  Adachi, Seiji ,  Yamauchi, Hisao

IPC分类号： H01L39/12

CPC分类号： H01L39/126 ,  Y10S505/739 ,  Y10S505/776 ,  Y10S505/785

摘要： The oxide superconductor according to the present invention is represented by (Hg 1-x Pb x )Ba 2 Ca 2 Cu 3 O δ (0.08 ≦ x ≦ 0.41, 7.625 ≦ δ ≦ 9.15), and has a crystal structure in which a lamination unit of (Hg, Pb)O z -BaO-CuO 2 -Ca-CuO 2 -Ca-CuO 2 -BaO is laminated in a c-axial direction of the crystal structure (0.625 ≦ z ≦ 2.15). Further, the method of manufacturing an oxide superconductor, according to the present invention, includes the steps of: mixing material powders of HgO, PbO, BaO, CaO and CuO at a mole ratio of (Hg 1-x Pb x ):Ba:Ca:Cu = a:2:b:c (1 ≦ a ≦ 2.5, 2 ≦ b ≦ 3, 2.5 ≦ c ≦ 4) and compression-molding the mixture powder into a compact; and subjecting the compact to a thermal treatment at 600-750°C.

摘要翻译： 根据本发明的氧化物超导体由（Hg1-xPbx）Ba2Ca2Cu3Oδ（0.08

公开(公告)号：EP0659704B1

公开(公告)日：1998-05-27

申请号：EP94120596.5

申请日：1994-12-23

申请人： INTERNATIONAL SUPERCONDUCTIVITY TECHNOLOGY CENTER ,  Tohoku Electric Power Company, Incorporated ,  Sumitomo Electric Industries, Ltd.

发明人： Isawa, Kazuyuki ,  Yamamoto, Ayako ,  Adachi, Seiji ,  Itoh, Makoto ,  Yamauchi, Hisao

IPC分类号： C04B35/01 ,  H01L39/12

CPC分类号： C04B35/45 ,  H01L39/2419

公开(公告)号：EP0659704A1

公开(公告)日：1995-06-28

申请号：EP94120596.5

申请日：1994-12-23

申请人： INTERNATIONAL SUPERCONDUCTIVITY TECHNOLOGY CENTER ,  Tohoku Electric Power Company, Incorporated ,  Sumitomo Electric Industries, Ltd.

发明人： Isawa, Kazuyuki ,  Yamamoto, Ayako ,  Adachi, Seiji ,  Itoh, Makoto ,  Yamauchi, Hisao

IPC分类号： C04B35/01 ,  H01L39/12

CPC分类号： C04B35/45 ,  H01L39/2419

摘要： The present invention provides a method of manufacturing an oxide superconductor, including the steps of mixing oxide materials of the metals contained in an oxide superconductor represented by HgBa₂Ca₂Cu₃O 8+y to prepare a powder mixture of the composition noted above, molding the powder mixture to prepare a molded body of a desired shape, and applying a heat treatment to the molded body within a hermetic container at a temperature sufficient for bringing about a solid phase reaction of the oxide materials for at least 20 hours. Also provided is a method of manufacturing an oxide superconductor, including the steps of mixing at least one additive element selected from the group consisting of Pb, Bi, Tl, Au, Pt, Ag, Cd and In with oxide materials of the metals contained in a Hg-series 1223 type oxide superconductor to prepare a powder mixture, molding the powder mixture to prepare a molded body of a desired shape, and applying a heat treatment to the molded body within a hermetic container at a temperature sufficient for bringing about a solid phase reaction of the oxide materials for at least 10 hours.

摘要翻译： 本发明提供一种氧化物超导体的制造方法，包括以下步骤：将由HgBa2Ca2Cu3O8 + y表示的氧化物超导体中所含的金属的氧化物材料混合，制备上述组成的粉末混合物， 成型体，并且在足以使氧化物材料的固相反应至少20小时的温度下对密闭容器内的成型体进行热处理。 还提供了一种制造氧化物超导体的方法，包括以下步骤：将选自Pb，Bi，Tl，Au，Pt，Ag，Cd和In中的至少一种添加元素与包含在其中的金属的氧化物材料混合 制备粉末混合物的Hg系1223型氧化物超导体，将粉末混合物成型以制备所需形状的成型体，并且在足以产生固体的温度下在密封容器内对成型体进行热处理 氧化物材料的相位反应至少10小时。