摘要:
The present invention relates to a process for preparing an activating support for metallocene complexes in the polymerisation of olefins comprising the steps of: I) providing a support consisting in particles formed from at least one porous mineral oxide; II) optionally fixing the rate of silanols on the surface of the support; III) functionalising the support with a solution containing a metallic salt; IV) heating the functionalised support of step c) under an inert gas or hydrogen; V) oxidising the support of step IV by treatment under N 2 O and then under oxygen; Vl) retrieving an active support having a controlled number of OH groups. That activating support is used to activate a metallocene catalyst component for the polymerisation of olefins.
摘要:
The present invention discloses an active supported catalyst system comprising: a) an iron-based non-metallocene catalyst component; b) an alkylating agent; c) an activating functionalised and fluorinated support. It also discloses a method for preparing said active supported catalyst system and its use in the polymerisation of olefins.
摘要:
The present invention discloses an active supported catalyst system comprising: a) an iron-based non-metallocene catalyst component; b) an alkylating agent; c) an activating functionalised and fluorinated support. It also discloses a method for preparing said active supported catalyst system and its use in the polymerisation of olefins.
摘要:
The present invention discloses an active supported catalyst system comprising: a) one or more non-metallocene catalyst component; b) an alkylating agent; c) an activating functionalised and fluorinated support. It also discloses a method for preparing said active support and its use in the polymerisation of polar and non polar monomers.
摘要:
The present invention discloses activating supports based on perfluorinated boronic acids and aluminium alkyls and their use in the activation of metallocene and post- metallocene complexes for the polymerisation of ethylene and alpha-olefins.
摘要:
The present invention relates to a process for preparing an activating support for metallocene complexes in the polymerisation of olefins comprising the steps of: I) providing a support prepared consisting in particles formed from at least one porous mineral oxide; II) optionally fixing the rate of silanols on the surface of the support; III) functionalising the support with a solution containing a fluorinated functionalising agent; IV) heating the functionalised and fluorinated support of step c) under an inert gas and then under oxygen; V) retrieving an active fluorinated support. That activating support is used to activate a metallocene catalyst component for the polymerisation of olefins.
摘要:
The present invention discloses a supported catalyst system that comprises a supported Keim-type nickel complex. It further discloses a method for preparing said supported catalyst system and its use for homo- or co-polymerising polar and non polar monomers.