公开(公告)号：EP1808726B1

公开(公告)日：2011-11-23

申请号：EP05800041.5

申请日：2005-10-28

申请人： Teijin Chemicals, Ltd.

发明人： ARIKI, Jiro, c/o Teijin Chemicals Ltd. ,  TANABE, Seiichi, c/o Teijin Chemicals Ltd.

IPC分类号： G02C7/02 ,  C08K5/103 ,  C08K5/3475 ,  C08K5/49 ,  C08L69/00

CPC分类号： G02B1/041 ,  C08K5/103 ,  C08K5/3475 ,  C08K5/49 ,  C08K2201/014 ,  C08L69/00

摘要： Eyeglass lenses made from a polycarbonate resin composition which comprises (1) 100 parts by weight of a polycarbonate resin, (2) 0.05 to 0.5 part by weight of at least one ultraviolet absorber (A) selected from the group consisting of 2-(2'-hydroxy-5' -methylphenyl)benzotriazole and 2-(2'-hydroxy-5'-tert-octyl- phenyl)benzotriazole, (3) 0.01 to 0.3 part by weight of at least one ultraviolet absorber (B) selected from the group consisting of 2-(3-tert-butyl-5-methyl-2-hydroxyphenyl)-5-chlorobenzo- triazole, 2,2'-methylenebis[4-(1,1,3,3-tetramethylbutyl)-6- (2H-benzotriazol)-2-ylphenol] and 2-[2-hydroxy-3,5-bis(α,α- dimethylbenzyl)phenyl]-2H-benzotriazole, and (4) 0.01 to 0.5 part by weight of a full ester (C) which is made from a tetra- to octa-hydric aliphatic C5-30 alcohol and an aliphatic C10-22 carboxylic acid and which has an acid value of 4 to 20. The polycarbonate resin composition has satisfactory heat resistance to withstand the long-term exposure to high -temperature conditions employed in molding lenses by extrusion compression molding or the like and causes little hue change even when has undergone a thermal history (such as re-extrusion) for the re-use of scrap. Further, the composition can give polycarbonate resin eyeglass lenses with excellent mold release characteristics.

公开(公告)号：EP1808726A1

公开(公告)日：2007-07-18

申请号：EP05800041.5

申请日：2005-10-28

申请人： Teijin Chemicals, Ltd.

发明人： ARIKI, Jiro, c/o Teijin Chemicals, Ltd. ,  TANABE, Seiichi, c/o Teijin Chemicals Ltd.

IPC分类号： G02C7/02 ,  C08K5/103 ,  C08K5/3475 ,  C08K5/49 ,  C08L69/00

CPC分类号： G02B1/041 ,  C08K5/103 ,  C08K5/3475 ,  C08K5/49 ,  C08K2201/014 ,  C08L69/00

摘要： A spectacle lens made of a polycarbonate resin composition which comprises (1) 100 parts by weight of a polycarbonate resin, (2) 0.05 to 0.5 part by weight of (A) at least one ultraviolet light absorber selected from the group consisting of 2-(2'-hydroxy-5'-methylphenyl)benzotriazole and 2-(2'-hydroxy-5'-tert-octylphenyl)benzotriazole, (3) 0.01 to 0.3 part by weight of (B) at least one ultraviolet light absorber selected from the group consisting of 2-(3-tert-butyl-5-methyl-2-hydroxyphenyl)-5-chlorobenzotriazole, 2,2'-methylenebis[4-(1,1,3,3-tetramethylbutyl)-6-(2H-benzotraizole)-2-ylphenol] and 2-[2-hydroxy-3,5-bis(α,α,-dimethylbenzyl)phenyl]-2H-benzotriazole, and (4) 0.01 to 0.5 part by weight of (C) a full ester of a tetravalent to octavalent aliphatic polyhydric alcohol having 5 to 30 carbon atoms and an aliphatic carboxylic acid having 10 to 22 carbon atoms, having an acid value of 4 to 20.
According to the present invention, the spectacle lens made of the above polycarbonate resin composition has molding heat resistance which enables it to be kept at a high temperature for a long time when the lens is formed by extrusion compression molding, a small change in hue when heat history such as re-extrusion is applied so as to recycle product waste and excellent releasability.

摘要翻译： 一种由聚碳酸酯树脂组合物制成的眼镜片，其包含（1）100重量份的聚碳酸酯树脂，（2）0.05至0.5重量份的（A）至少一种选自下组的紫外线吸收剂：2- （2'-羟基-5'-甲基苯基）苯并三唑和2-（2'-羟基-5'-叔辛基苯基）苯并三唑，（3）0.01至0.3重量份的（B）至少一种选自紫外光吸收剂 由2-（3-叔丁基-5-甲基-2-羟基苯基）-5-氯苯并三唑，2,2'-亚甲基双[4-（1,1,3,3-四甲基丁基）-6- （2H-苯并三唑）-2-基苯酚]和2- [2-羟基-3,5-双（±，±， - 二甲基苄基）苯基] -2H-苯并三唑，和（4）0.01至0.5重量份（ C）具有5至30个碳原子的四价至五价脂族多元醇和具有10至22个碳原子的脂肪族羧酸的完全酯，其酸值为4至20.根据本发明，制造的眼镜镜片 的上述聚碳酸酯 sin成分具有成型耐热性，当通过挤出压缩成型形成透镜时，能够长时间保持高温，当再次挤出的热历史被应用时，色调的变化小，从而再循环产品 浪费和优秀的脱模性。

公开(公告)号：EP1693412A1

公开(公告)日：2006-08-23

申请号：EP03778782.7

申请日：2003-12-10

申请人： Teijin Chemicals, Ltd.

发明人： YAMANAKA, Katsuhiro, c/o Teijin Chemicals Ltd. ,  IMAMURA, Koichi, c/o Teijin Chemicals Ltd. ,  TANABE, Seiichi, c/o Teijin Chemicals Ltd. ,  TAKETANI, Yutaka

IPC分类号： C08L25/06 ,  C08L71/12 ,  C08K5/5357 ,  C09K21/12 ,  C07F9/6574

CPC分类号： C08L25/06 ,  C07F9/657181 ,  C08K5/5357 ,  C08L71/12 ,  C09K21/12 ,  C08L25/02 ,  C08L2666/22 ,  C08L2666/04

摘要： It is an object of the present invention to provide a styrene type resin composition excellent in thermal stability, hue, fluidity, and heat resistance, and also having the flame retardant performance, and a molded product excellent in outward appearance, formed therefrom.
The present invention provides a flame retardant styrene type resin composition comprising (A) a styrene type resin (component A) in an amount of 100 parts by weight, (B) a polyphenylene ether type resin (component B) in an amount of 0 to 100 parts by weight, and (C) an organophosphorus compound (component C) represented by the following formula (1) in an amount of 1 to 100 parts by weight, characterized in that the organophosphorus compound (component C) satisfies:

(i) the weight loss residue on heating at 500°C is 10% or less;
(ii) the HPLC purity is 90% or more, and
(iii) the acid value is 0.5 mg KOH/g or less

(where in the formula, Ar 1 and Ar 2 may be the same or different, and is a phenyl group which may have a substituent.)

摘要翻译： 本发明的目的是提供热稳定性，色调，流动性和耐热性优异并且具有阻燃性能的苯乙烯型树脂组合物，以及由其形成的外观优异的模塑制品。 本发明提供一种阻燃苯乙烯类树脂组合物，其包含（A）100重量份的苯乙烯类树脂（组分A），（B）聚苯醚型树脂（组分B），其量为0至 100重量份，和（C）由下式（1）表示的有机磷化合物（组分C）的量为1〜100重量份，其特征在于有机磷化合物（C成分）满足：（i） 在500℃下加热时的减重残留量为10％以下; （ii）HPLC纯度为90％以上，（iii）酸值为0.5mgKOH / g以下（式中，Ar 1和Ar 2可以相同或不同，为苯基 其可以具有取代基。）