摘要:
A polycarbonate resin composition or a copolymer, comprising, as main repeating units, a carbonate unit (a-1) having a fluorene ring in a side chain, a carbonate unit (a-2) represented by the following formula (a-2):
(wherein W represents an alkylene group having 1 to 20 carbon atoms or a cycloalkylene group having 6 to 20 carbon atoms, R represents a branched or linear-chain alkyl group having 1 to 20 carbon atoms or a cycloalkyl group having 6 to 20 carbon atoms optionally having a substituent, and u represents an integer of 0 to 3), and a carbonate unit (a-3) derived from 2,2-bis(4-hydroxyphenyl)propane, wherein 1) a molar ratio of the carbonate unit (a-1) to the carbonate unit (a-2) is from 50/50 to 80/20, and 2) a molar ratio of the total of the carbonate unit (a-1) and the carbonate unit (a-2) to the carbonate unit (a-3) is from 1:99 to 70:30. This polycarbonate resin composition or copolymer has excellent heat resistance, transparency, and bending resistance and has low retardation.
摘要:
Provided is a resin composition comprising: a polycarbonate resin (A) containing, as main repeating units, a unit (a-1) represented by the following formula (a-1)
and a unit (a-2) represented by the following formula (a-2)
(wherein, W represents a C 1-20 alkylene group or a C 6-20 cycloalkylene group, R represents a branched or linear-chain C 1-20 alkyl group or a C 6-20 cycloalkyl group optionally substituted, and m represents an integer of 0 to 10) and an acrylic resin (B), and the polycarbonate resin and the acrylic resin are in a weight ratio of 40:60 to 99:1, wherein the resin composition has a single glass transition temperature, which is in the range of 90°C to 150°C, and the resin composition has excellent transparency, chemical resistance, surface hardness and heat resistance, and has a low photoelastic coefficient.
摘要:
A film having high transparency, weather resistance and moist heat resistance, excellent tensile characteristics, a good hue and high surface hardness. The film comprises: (a) 100 parts by weight of a polycarbonate resin (component a) containing a carbonate unit (A) represented by the following formula (A) and having a specific viscosity measured from a 20°C methylene chloride solution of 0.2 to 0.5; (b) 0.03 to 2.5 parts by weight of at least one ultraviolet absorbent (component b) selected from the group consisting of an ultraviolet absorbent having a benzotriazole skeleton and an ultraviolet absorbent having a triazine skeleton; (c) 0.0001 to 0.02 part by weight of a coloring agent (component c); and (d) 0.01 to 1 part by weight of a hindered amine-based optical stabilizer (component d).
摘要:
A multi-layer film having excellent surface hardness and transparency, a small heat shrinkage factor and such high brittleness that it is easily trimmed after decorative molding. The multi-layer film comprises a layer (layer A) which contains a polycarbonate resin having a viscosity average molecular weight of 13,000 or more to less than 20,000 and layers (layer B-1 and layer B-2) which contain an acrylic resin and are formed on both sides of the layer A, respectively, wherein the total thickness of the multi-layer film is 50 to 200 µm, and the thickness of the layer A accounts for 5 to 30 % of the total thickness.