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1.发明公开
公开(公告)号：EP0122782A1
公开(公告)日：1984-10-24
申请号：EP84302512.3
申请日：1984-04-12
Applicant: The British Petroleum Company p.l.c.
Inventor： Barlow, Michael Thomas, c/o , Stewart, David Gordon
IPC: C07C69/54 , C07C57/04 , C07C67/343 , C07C51/353
CPC classification number: C07C51/353 , C07C57/04
Abstract: Unsaturatea carboxylic acids and/or esters thereof are produced by reacting an aldehyde comprising formaldehyde or acetaldehyce with either a saturated carboxylic acid ester or anhydride in the vapour phase in the presence as catalyst of a high silica crystalline aluminosilicate zeolite in which the cation is H + and/or a transition metal and/or a rare earth metal. In a modification of the process instead of formaldehyde there is used methanol/molecular oxygen and in the catalyst there is included either an oxidative or an oxidative/ dehydrogenative component.
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公开(公告)号：EP0038682B1
公开(公告)日：1984-08-08
申请号：EP81301684.7
申请日：1981-04-16
Applicant: The British Petroleum Company p.l.c.
Inventor： Ball, William John , Stewart, David Gordon
CPC classification number: C01B3/26 , B01J23/75 , B01J29/04 , C01B2203/0277 , C01B2203/1052 , C01B2203/1064 , C01B2203/1076 , C01B2203/1223
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3.发明公开Process for the production of catalysts based on crystalline aluminosilicates and the use of catalysts so-produced 失效基于结晶铝氧化物生产催化剂的方法和所生产的催化剂的使用
公开(公告)号：EP0071382A3
公开(公告)日：1984-01-18
申请号：EP82303778
申请日：1982-07-19
Applicant: The British Petroleum Company p.l.c.
Inventor： Ball, William John , Stewart, David Gordon
Abstract: A process for the production of a catalyst based on a crystalline aluminosilicate having a silica to alumina molar ratio greater than 12:1 which is obtained by mixing a source of silica, a source of alumina, a source of alkali metal, water and a source of ammonium ions in defined proportions, crystallising the mixture, recovering the crystalline aluminosilicate so-formed, cation-exchanging and/or impregnating the recovered crystalline aluminosilicate and finally calcining, wherein either the recovered crystalline aluminosilicate or the cation-exchanged aluminosilicate or the impregnated aluminosilicate is washed with a solution containing either an organic base, a carboxylic acid, an alcohol, a glycol, a phenol or an ester. The washing treatment results in a reduction in the rate of decline in catalytic activity in reactions such as the conversion of aliphatic to aromatic hydrocarbons.
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4.发明授权Process for the production of amorphous aluminosilicates and their use as catalysts 失效生产非晶态铝酸钠的方法及其作为催化剂的用途
公开(公告)号：EP0009976B1
公开(公告)日：1982-09-15
申请号：EP79302108.0
申请日：1979-10-04
Applicant: The British Petroleum Company p.l.c.
Inventor： Ball, William John , Palmer, Keith William , Stewart, David Gordon
CPC classification number: B01J23/72 , B01J21/12 , B01J29/041 , C01B3/22 , C01B33/26 , Y10S502/511
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5.发明授权Process for the production of ethanol and/or acetaldehyde by reacting methanol with synthesis gas 失效通过合成气反应甲醇生产乙醇和/或乙炔的方法
公开(公告)号：EP0010373B1
公开(公告)日：1982-09-01
申请号：EP79302053.8
申请日：1979-10-01
Applicant: The British Petroleum Company p.l.c.
Inventor： Gane, Brian Richard , Stewart, David Gordon
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Patent Agency Ranking6.发明公开Process for the production of oxygenated hydrocarbons from synthesis gas 失效Verfahren zur Herstellung sauerstoffhaltiger Kohlenstoffverbindungen aus Synthesegas。
公开(公告)号：EP0033212A2
公开(公告)日：1981-08-05
申请号：EP81300240.9
申请日：1981-01-20
Applicant: The British Petroleum Company p.l.c.
Inventor： Ball, William John , Stewart, David Gordon
CPC classification number: C07C51/10 , B01J21/08 , B01J23/464 , B01J23/683 , B01J23/685 , B01J23/686 , C07C29/1514 , C07C29/158 , C07C29/32 , C07C45/49 , C07C51/12 , Y02P20/52 , C07C53/08 , C07C31/04 , C07C31/08 , C07C31/10
Abstract: Oxygenated hydrocarbons are produced by reacting in a liquid medium carbon monoxide and hydrogen in the presence of a particulate catalyst comprising a supported rhodium component at an elevated temperature, typically in the range 150 to 300°C and an elevated pressure, typically greater than 50 bars. Suitable liquid media include water, an alcohol, a Carboxylic acid, an ester, a ketone, an ether or an aromatic hydrocarbon. The rhodium catalyst may be supported on silica and is desirably combined with other metals.
Abstract translation: 氧化烃通过在液体介质中一氧化碳和氢气在包含负载的铑组分的颗粒催化剂的存在下在升高的温度（通常在150-300℃）和升高的压力（通常大于50巴） 。 合适的液体介质包括水，醇，羧酸，酯，酮，醚或芳族烃。 铑催化剂可以负载在二氧化硅上，并且期望与其它金属组合。
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7.发明公开Process for the hydrocarbonylation of methanol to ethanol in the presence of an inert liquid 失效对于甲醇的hydrocarbonylation过程在惰性液体存在乙醇。
公开(公告)号：EP0001937A1
公开(公告)日：1979-05-16
申请号：EP78300608.3
申请日：1978-11-08
Applicant: The British Petroleum Company p.l.c.
Inventor： Gane, Brian Richard , Stewart, David Gordon
CPC classification number: B01J31/2404 , B01J31/0267 , B01J31/20 , B01J2531/845 , C07C29/32 , C07C45/49 , Y02P20/52 , C07C47/06 , C07C31/08 , C07C31/10 , C07C31/12
Abstract: Ethanol is produced by reacting methanol with hydrogen and carbon monoxide at elevated temperature and pressure in the presence of a catalyst comprising cobalt, an iodide or a bromide and a compound having the formula X(A)(B)(C) in which formula X is nitrogen or phosphorus and A, B and C are individually monovalent organic radicals, or X is phosphorus and any two of A, B and C together form an organic divalent cyclic ring system bonded to the X atom, or X is nitrogen and all of A, B and C form an organic trivalent cyclic ring system bonded to the X atom, and in the additional presence of an added inert liquid which is characterised as a compound capable of forming, under normal conditions of temperature and pressure, a separate phase in the presence of methanol containing up to 20% w/w water, which compound contains in its structure bonds other than carbon/carbon and carbon/hydrogen. Typical of the inert liquids which may be employed are chlorobenzene, decanoic acid, polydimethylsiloxane fluid and methyl phenyl silicone fluid. The addition of the inert liquid suppresses' side-reactions and thereby increases the total yield and selectivity to ethanol.
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8.发明授权Process for the production of crystalline aluminosilicates and their use as catalysts and catalyst supports 失效生产结晶铝氧化物的方法及其作为催化剂和催化剂的使用
公开(公告)号：EP0030811B2
公开(公告)日：1988-03-30
申请号：EP80304334.8
申请日：1980-12-02
Applicant: The British Petroleum Company p.l.c.
Inventor： Ball, William John , Stewart, David Gordon
CPC classification number: C07C4/06 , B01J29/70 , B01J2229/36 , C01B39/38 , C07C2/00 , C07C2529/06 , C07C15/00
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9.发明授权
公开(公告)号：EP0030110B1
公开(公告)日：1984-07-25
申请号：EP80304194.6
申请日：1980-11-21
Applicant: The British Petroleum Company p.l.c.
Inventor： Ball, William John , Cotton, Leonard , Stewart, David Gordon
CPC classification number: C07C51/12 , B01J23/464 , C07C29/158 , C07C45/49 , C07C51/10 , Y02P20/52 , C07C53/08 , C07C31/04 , C07C31/08 , C07C31/10
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公开(公告)号：EP0014023B1
公开(公告)日：1984-07-11
申请号：EP80300010.8
申请日：1980-01-03
Applicant: The British Petroleum Company p.l.c.
Inventor： Stewart, David Gordon , Ball, William John
CPC classification number: C01B33/2876 , B01J29/18 , B01J29/40 , B01J29/80 , C07C1/20 , C07C2529/06 , Y10S423/22 , Y10S423/25
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