摘要:
The present invention relates to positive electrode active substance particles for non-aqueous electrolyte secondary batteries, comprising an oxide having a spinel structure and comprising at least Li and Mn as main components and an oxide comprising at least Li and Zr, in which the oxide comprising at least Li and Zr forms a mixed phase comprising two or more phases, and a content of the oxide comprising at least Li and Zr in the positive electrode active substance particles is 0.1 to 4% by weight. The present invention provides positive electrode active substance particles for non-aqueous electrolyte secondary batteries which are excellent in high-temperature characteristics and a process for producing the positive electrode active substance particles, and a non-aqueous electrolyte secondary battery.
摘要:
The present invention relates to positive electrode active substance particles for non-aqueous electrolyte secondary batteries, comprising an oxide having a spinel structure and comprising at least Li and Mn as main components and an oxide comprising at least Li and Zr, in which the oxide comprising at least Li and Zr forms a mixed phase comprising two or more phases, and a content of the oxide comprising at least Li and Zr in the positive electrode active substance particles is 0.1 to 4% by weight. The present invention provides positive electrode active substance particles for non-aqueous electrolyte secondary batteries which are excellent in high-temperature characteristics and a process for producing the positive electrode active substance particles, and a non-aqueous electrolyte secondary battery.
摘要:
The present invention relates to cobalt oxyhydroxide particles and lithium cobaltate particles which have a high density and a uniformly grown crystal structure. These objects of the present invention can be achieved by cobalt oxyhydroxide particles having an average secondary particle diameter (D50) of 3.0 to 25.0 µm, a BET specific surface area (BET) of 0.1 to 20.0 m 2 /g, a tap density (TD) of 1.0 to 3.5 g/cm 3 in which the average secondary particle diameter (D50) and the BET specific surface area (BET) of the cobalt oxyhydroxide particles satisfy the relational formula; and by lithium cobaltate particles having an average secondary particle diameter (D50) of 15.0 to 25.0 µm, a specific surface area (BET) of 0.10 to 0.30 m 2 /g, a compressed density (CD; as measured by applying a pressure of 2.5 t/cm 2 thereto) of 3.65 to 4.00 g/cm 3 . The cobalt oxyhydroxide particles are useful as a precursor of a positive electrode active substance (lithium cobaltate particles) used in a non-aqueous electrolyte secondary battery, and the lithium cobaltate particles are useful as a the positive electrode active substance used in a non-aqueous electrolyte secondary battery.
摘要:
The present invention aims at providing lithium manganate having a high output and an excellent high-temperature stability. The above aim can be achieved by lithium manganate particles having a primary particle diameter of not less than 1 µm and an average particle diameter (D 50 ) of kinetic particles of not less than 1 µm and not more than 10 µm, which are substantially in the form of single crystal particles and have a composition represented by the following chemical formula: Li 1+x Mn 2-x-y Y y O 4 in which Y is at least one element selected from the group consisting of Al, Mg and Co; x and y satisfy 0.03 ‰¤ x ‰¤ 0.15 and 0.05 ‰¤ y ‰¤ 0.20, respectively, wherein the Y element is uniformly dispersed within the respective particles, and an intensity ratio of I(400)/I(111) thereof is not less than 33% and an intensity ratio of I(440)/I(111) thereof is not less than 16%.
摘要:
In accordance with the present invention, there are provided positive electrode active substance particles for non-aqueous electrolyte secondary batteries which is excellent in life characteristics of a battery with respect to a repeated charging and discharging performance thereof, as well as a non-aqueous electrolyte secondary battery. The present invention relates to a positive electrode active substance for non-aqueous electrolyte secondary batteries comprising lithium transition metal layered oxide having a composition represented by the formula: Li a (Ni x Co y Mn 1-x-y )O 2 wherein a is 1.0 ≤ a ≤ 1.15; x is 0
摘要:
The present invention relates to lithium manganate particles for non-aqueous electrolyte secondary batteries, having a spinel structure, an average primary particle diameter of 0.4 to 1.8 µm and an average secondary particle diameter (D50) of 8 to 20 µm, a ratio of the average secondary particle diameter (D50) to the average primary particle diameter (D50/average primary particle diameter) being in the range of 10 to 30, and pore diameters of pores in the lithium manganate particles as measured by a mercury intrusion porosimetry method being in the range of 100 to 500 nm, and a process for producing the lithium manganate particles, and a non-aqueous electrolyte secondary battery. The lithium manganate particles according to the present invention are excellent in high-temperature storage characteristics.