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2.发明授权
公开(公告)号：EP2833445B1
公开(公告)日：2017-11-29
申请号：EP13767403.2
申请日：2013-03-14
申请人： TODA KOGYO CORP.
CPC分类号： H01M4/505 , C01G51/50 , C01G51/56 , C01G53/006 , C01G53/50 , C01G53/56 , C01P2002/50 , C01P2002/52 , C01P2002/76 , C01P2004/03 , C01P2004/50 , C01P2004/61 , C01P2006/11 , C01P2006/12 , C01P2006/80 , H01M4/525 , H01M10/052 , H01M2004/021 , H01M2004/028 , Y02E60/122 , Y02P70/54
摘要： The present invention relates to positive electrode active substance particles comprising a compound having at least a crystal system belonging to a space group of R-3m and a crystal system belonging to a space group of C2/m, the positive electrode active substance particles having a specific intensity ratio; a content of Mn in the positive electrode active substance particles being controlled such that a molar ratio of Mn/(Ni + Co + Mn) therein is not less than 0.55; and the positive electrode active substance particles comprising an element A (that is at least one element selected from the group consisting of Si, Zr and Y) in an amount of 0.03 to 5% by weight and having a tap density of 0.8 to 2.4 g/cc and a compressed density of 2.0 to 3.1 g/cc. The positive electrode active substance particles can be produced by calcining a mixture of precursor particles comprising the element A, Mn, Ni and/or Co, and a lithium compound.
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3.发明公开Li-Ni COMPLEX OXIDE PARTICLE POWDER AND NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY 审中-公开李NI LEX LEX TEN EL VER VER TEN TEN TEN TEN TEN TEN TEN TEN TEN TEN TEN TEN TEN TEN TEN TEN TEN TEN
公开(公告)号：EP2910528A1
公开(公告)日：2015-08-26
申请号：EP13846343.5
申请日：2013-10-15
申请人： TODA KOGYO CORP.
CPC分类号： H01M4/131 , C01G53/006 , C01G53/50 , C01P2002/50 , C01P2002/72 , C01P2004/32 , C01P2004/61 , C01P2004/62 , C01P2006/12 , C01P2006/40 , H01M4/505 , H01M4/525 , H01M10/052 , H01M2004/028
摘要： The present invention relates to Li-Ni composite oxide particles having a composition of Li x (Ni y Co 2(1-y)/5 Mn 3(1-y)/5 ) 1-z M z O 2 wherein x, y and z represent 1.00 ≤ x ≤ 1.10; 0.65
摘要翻译： 本发明涉及具有Li x（Ni y Co 2（1-y）/ 5 Mn 3（1-y）/ 5）1-z M z O 2组成的Li-Ni复合氧化物颗粒，其中x，y z代表1.00‰¤x‰¤1.10; 0.65
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4.发明授权POSITIVE ELECTRODE ACTIVE MATERIAL POWDER, METHOD FOR PRODUCING SAME, AND NONAQUEOUS ELECTROLYTE SECONDARY BATTERY 有权正极活性物质粉末，其制造方法以及非水电解质二次电池
公开(公告)号：EP2485305B1
公开(公告)日：2018-04-18
申请号：EP10820498.3
申请日：2010-09-28
申请人： Toda Kogyo Corp.
发明人： YAMAMOTO, Manabu , NISHIKAWA, Daisuke , ISHIZAKI, Kazutoshi , KIKUYA, Kazuhiko , SANTOKI, Teruaki , SASAKI, Osamu , SADAMURA, Hideaki
CPC分类号： C01G51/50 , B82Y30/00 , C01G45/1228 , C01G51/42 , C01G53/42 , C01G53/50 , C01P2002/52 , C01P2002/72 , C01P2002/74 , C01P2002/76 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C01P2006/12 , C01P2006/40 , C01P2006/80 , H01M4/505 , H01M4/525 , Y02E60/122 , Y02P70/54
摘要： The present invention relates to positive electrode active substance particles comprising a compound having at least a crystal system belonging to a space group of R-3m and a crystal system belonging to a space group of C2/m, and boron, wherein the compound is a composite oxide comprising at least Li, Mn, and Co and/or Ni; a relative intensity ratio [(a)/(b)] of a maximum diffraction peak intensity (a) observed at 2¸ = 20.8±1° in a powder X-ray diffraction pattern of the positive electrode active substance as measured using a Cu-K± ray to a maximum diffraction peak intensity (b) observed at 28 = 18.6±1° in the powder X-ray diffraction pattern, is 0.02 to 0.5; a content of Mn in the positive electrode active substance particles is controlled such that a molar ratio of Mn/(Ni + Co + Mn) therein is not less than 0.55; and the positive electrode active substance particles comprise the boron in an amount of 0.001 to 3% by weight. The positive electrode active substance particles of the present invention are produced by calcining a mixture comprising precursor particles comprising Mn, and Ni and/or Co, a lithium compound and a boron compound at a temperature of 500 to 1500°C. The positive electrode active substance particles of the present invention can provide a secondary battery which can be improved in charge/discharge capacity and cycle characteristics.
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5.发明授权
公开(公告)号：EP2157640B1
公开(公告)日：2018-01-10
申请号：EP08720642.1
申请日：2008-03-27
申请人： Toda Kogyo Corp.
IPC分类号： H01M4/505 , C01G45/12 , H01M4/525 , H01M10/0525 , C01G51/00
CPC分类号： H01M4/505 , C01G45/1242 , C01G51/54 , C01P2002/52 , C01P2002/54 , C01P2002/72 , C01P2002/74 , C01P2002/77 , C01P2004/03 , C01P2004/51 , C01P2004/52 , C01P2004/61 , C01P2006/12 , C01P2006/40 , H01M4/525 , H01M10/0525 , Y02E60/122 , Y02P70/54 , Y10T428/2982
摘要： The present invention aims at providing lithium manganate having a high output and an excellent high-temperature stability. The above aim can be achieved by lithium manganate particles having a primary particle diameter of not less than 1 µm and an average particle diameter (D 50 ) of kinetic particles of not less than 1 µm and not more than 10 µm, which are substantially in the form of single crystal particles and have a composition represented by the following chemical formula: Li 1+x Mn 2-x-y Y y O 4 in which Y is at least one element selected from the group consisting of Al, Mg and Co; x and y satisfy 0.03 ‰¤ x ‰¤ 0.15 and 0.05 ‰¤ y ‰¤ 0.20, respectively, wherein the Y element is uniformly dispersed within the respective particles, and an intensity ratio of I(400)/I(111) thereof is not less than 33% and an intensity ratio of I(440)/I(111) thereof is not less than 16%.
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6.发明公开POSITIVE ELECTRODE ACTIVE MATERIAL PARTICLE POWDER AND METHOD FOR PRODUCING SAME, AND NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY 有权粒子粉末正极活性材料的方法其制造和二次电池用无水ELEKTROLYT
公开(公告)号：EP2833445A1
公开(公告)日：2015-02-04
申请号：EP13767403.2
申请日：2013-03-14
申请人： TODA KOGYO CORP.
CPC分类号： H01M4/505 , C01G51/50 , C01G51/56 , C01G53/006 , C01G53/50 , C01G53/56 , C01P2002/50 , C01P2002/52 , C01P2002/76 , C01P2004/03 , C01P2004/50 , C01P2004/61 , C01P2006/11 , C01P2006/12 , C01P2006/80 , H01M4/525 , H01M10/052 , H01M2004/021 , H01M2004/028 , Y02E60/122 , Y02P70/54
摘要： The present invention relates to positive electrode active substance particles comprising a compound having at least a crystal system belonging to a space group of R-3m and a crystal system belonging to a space group of C2/m, the positive electrode active substance particles having a specific intensity ratio; a content of Mn in the positive electrode active substance particles being controlled such that a molar ratio of Mn/(Ni + Co + Mn) therein is not less than 0.55; and the positive electrode active substance particles comprising an element A (that is at least one element selected from the group consisting of Si, Zr and Y) in an amount of 0.03 to 5% by weight and having a tap density of 0.8 to 2.4 g/cc and a compressed density of 2.0 to 3.1 g/cc. The positive electrode active substance particles can be produced by calcining a mixture of precursor particles comprising the element A, Mn, Ni and/or Co, and a lithium compound.
摘要翻译： 本发明涉及包括具有正极活性物质粒子具有至少属于空间群R-3m的和属于空间群C2 / m的晶体体系的晶体体系的化合物的正极活性物质粒子 特定的强度比; Mn的正极活性物质粒子的含量被控制搜索那样的Mn /（镍+钴+ Mn）的摩尔比。其中不小于0:55; 和正极活性物质粒子，其包括元素A（即是选自硅，锆和Y由......组成中选择的至少一种元素）在0点03分〜5％（重量）和具有0.8的振实密度2.4克 / cc和2.0至3.1克/立方厘米密度的压缩。 另外，正极活性物质颗粒可以通过煅烧包括A元素，Mn，Ni和/或Co，和锂化合物前体粒子的混合物来制造。
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公开(公告)号：EP2214233B1
公开(公告)日：2019-01-16
申请号：EP08849460.4
申请日：2008-11-12
申请人： Toda Kogyo Corp.
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8.发明授权POWDER OF LITHIUM COMPLEX COMPOUND PARTICLES, METHOD FOR PRODUCING THE SAME, AND NONAQUEOUS ELECTROLYTE SECONDARY CELL 有权锂络合物复合粒子的粉末，其制造方法以及非水电解质二次电池
公开(公告)号：EP2368851B1
公开(公告)日：2018-05-16
申请号：EP09830210.2
申请日：2009-12-03
申请人： Toda Kogyo Corp.
IPC分类号： H01M4/525 , C01G53/00 , H01M10/052 , H01M4/1391 , H01M10/0566
CPC分类号： H01M4/525 , C01G53/42 , C01P2002/52 , C01P2002/72 , C01P2004/04 , C01P2004/61 , C01P2006/12 , C01P2006/40 , C01P2006/80 , H01M4/1391 , H01M10/052 , H01M10/0566 , Y02E60/122 , Y02P70/54
摘要： The present invention relates to lithium composite compound particles having a composition represented by the formula: Li 1+x Ni 1-y-z Co y M z O 2 (M = B or Al), wherein the lithium composite compound particles have an ionic strength ratio A (LiO - /NiO 2 - ) of not more than 0.3 and an ionic strength ratio B (Li 3 CO 3 + /Ni + ) of not more than 20 as measured on a surface of the respective lithium composite compound particles using a time-of-flight secondary ion mass spectrometer. The lithium composite compound particles of the present invention can be used as a positive electrode active substance of a secondary battery which has good cycle characteristics and an excellent high-temperature storage property.
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公开(公告)号：EP2911224B1
公开(公告)日：2019-07-03
申请号：EP13847482.0
申请日：2013-10-15
申请人： Toda Kogyo Corp.
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公开(公告)号：EP2226293B1
公开(公告)日：2018-08-08
申请号：EP08867092.2
申请日：2008-12-26
申请人： Toda Kogyo Corp.
IPC分类号： C01G45/00 , C01G45/02 , C01G49/00 , C01G51/00 , C01G53/00 , C01G45/12 , H01M10/052 , C04B35/01 , H01M4/02 , H01M4/505 , H01M4/525 , H01M10/0525
CPC分类号： C01G45/1242 , C01G45/02 , C01G49/0072 , C01G51/54 , C01G53/54 , C01P2002/52 , C01P2002/54 , C01P2002/72 , C01P2002/74 , C01P2004/03 , C01P2004/51 , C01P2004/61 , C01P2004/80 , C01P2004/84 , C01P2006/12 , C01P2006/40 , C04B35/016 , C04B2235/3203 , C04B2235/3206 , C04B2235/3232 , C04B2235/3241 , C04B2235/3272 , C04B2235/3275 , C04B2235/3279 , C04B2235/34 , C04B2235/763 , H01M4/02 , H01M4/505 , H01M4/525 , H01M10/052 , H01M10/0525 , H01M2004/021 , H01M2004/028 , Y10T428/2982
摘要： The present invention relates to lithium manganate particles having a primary particle diameter of 1 to 8 µm and forming substantially single-phase particles, which have a composition represented by the following chemical formula: €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒLi 1+x Mn 2-x-y Y1 y O 4 + Y2 in which Y1 is at least one element selected from the group consisting of Ni, Co, Mg, Fe, Al, Cr and Ti; Y2 is P and is present in an amount of 0.01 to 0.6 mol% based on Mn; and x and y satisfy 0.03 ‰¤ x ‰¤ 0.15 and 0.05 ‰¤ y ‰¤ 0.20, respectively, and which lithium manganate particles have a specific surface area of the lithium manganate particles of 0.3 to 0.9 m 2 /g (as measured by BET method); and have an average particle diameter (D 50 ) of the lithium manganate particles of 3 to 10 µm. A positive electrode active substance of a lithium ion secondary battery using the lithium manganate particles of the present invention has a high output and is excellent in high-temperature stability.
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