公开(公告)号：EP1087969B1

公开(公告)日：2003-04-09

申请号：EP99957058.3

申请日：1999-06-10

申请人： UNILEVER PLC ,  UNILEVER N.V.

发明人： BANSE, Frédéric, Lab. de Chimie Inorganique ,  CARINA, Riccardo, Unilever Research Port Sunlight ,  DELROISSE, Michel, Unilever Res. Port Sunlight ,  GIRERD, Jean-Jacques, Lab. de Chimie Inorganique ,  HAGE, Ronald, Unilever Research Vlaardingen ,  SIMAAN, Jalila Ariane, Lab. de Chimie Inorganique ,  TETARD, David, Unilever Research Port Sunlight

IPC分类号： C07D471/18 ,  C11D3/39

CPC分类号： C07F13/005 ,  C07F15/025 ,  C11D3/3932 ,  D06L4/13 ,  D06L4/15

摘要： A bleach catalyst in the form of a ligand of formula (I); wherein Z and Z are independently selected from monocyclic or polycyclic aromatic ring structures optionally containing one or more heteroatoms, each aromatic ring structure being optionally substituted by one or more substituents. Y and Y are independently selected from C, N, O, Si, P and S atoms. A and A are independently selected from hydrogen, alkyl, alkenyl and cycloalkyl (each of alkyl, alkenyl and cycloalkyl being optionally substituted, electron donating groups and electron withdrawing groups); i and j are selected from 0, 1 and 2 to complete the valency of the groups Y and Y each of Q -Q is independently selected from groups of formula (a); wherein 10 > a + b + c + d > = 2; each Y is independently selected from O, S, SO, SO2, (G )(G )N-C(O), aryl, heteroaryl, P and P(O) each of A -A is independently selected from the groups hereinbefore defined for A and A ; ion pairs, complexes and the use of such ligands, ion pairs and complexes in cleaning and/or bleaching compositions are also described.

摘要翻译： 本发明涉及新的大环漂白催化剂，包含这些催化剂的制剂，以及采用这些催化剂的漂白方法。 这些催化剂表现出意想不到的水解稳定性，以及金属萃取剂对金属萃取的稳定性。