公开(公告)号：EP0455261A1

公开(公告)日：1991-11-06

申请号：EP91107226.2

申请日：1991-05-03

申请人： UNION CARBIDE CHEMICALS AND PLASTICS COMPANY INC. (a New York corporation)

发明人： Briggs, John Robert ,  Maher, John Michael ,  Harrison, Arnold Myron

IPC分类号： C07C29/36 ,  C07C31/20 ,  C07C45/58 ,  C07C47/19 ,  B01J31/16

CPC分类号： C07C29/36 ,  B01J31/185 ,  B01J31/20 ,  B01J2531/822 ,  C07C45/58 ,  C07C31/205 ,  C07C47/19

摘要： A process for producing a 1,3-diol, e.g., 1,3-propanediol, and/or a 3-hydroxyaldehyde, e.g., 3-hydroxypropionaldehyde is disclosed which comprises contacting a combination of an epoxide, carbon monoxide and hydrogen in the presence of a rhodium-containing catalyst composition effective to promote the hydroformylation of the epoxide at conditions effective to form at least one of a 1,3-diol and a 3-hydroxyaldehyde. The rhodium-containing catalyst composition comprises an anionic rhodium-containing complex. A promoter component is preferably provided to enhance at least one of the rate and selectivity of the epoxide hydroformylation reaction. Rhodium-containing compositions and a processes for producing rhodium-containing compositions are also disclosed.

摘要翻译： 一种制备1,3-二醇，例如，1,3-丙二醇，和/或3-羟基醛，例如过程，3-羟基丙醛是游离缺失盘其包括使在存在环氧化物，一氧化碳和氢气的组合 的含铑催化剂组合物可有效促进环氧化物的羰基化在有效形成1,3-二醇中的至少一种和3-羟基醛的条件。 含铑催化剂组合物包括含铑阴离子配合物。 包括助催化剂成分优选地设置，以提高环氧化物羰基化反应的速率和选择性中的至少一种。 因此组合物和方法用于生产含铑组合物的含铑是游离缺失盘。