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    Catalysts and processes useful in producing 1,3-diols and/or 3-hydroxyaldehydes
    2.
    发明公开
    Catalysts and processes useful in producing 1,3-diols and/or 3-hydroxyaldehydes 失效
    催化剂和方法，用于生产1,3-二醇和/或3-羟基醛。

    公开(公告)号：EP0455261A1

    公开(公告)日：1991-11-06

    申请号：EP91107226.2

    申请日：1991-05-03

    申请人： UNION CARBIDE CHEMICALS AND PLASTICS COMPANY INC. (a New York corporation)

    发明人： Briggs, John Robert ,  Maher, John Michael ,  Harrison, Arnold Myron

    IPC分类号： C07C29/36 ,  C07C31/20 ,  C07C45/58 ,  C07C47/19 ,  B01J31/16

    CPC分类号： C07C29/36 ,  B01J31/185 ,  B01J31/20 ,  B01J2531/822 ,  C07C45/58 ,  C07C31/205 ,  C07C47/19

    摘要： A process for producing a 1,3-diol, e.g., 1,3-propanediol, and/or a 3-hydroxyaldehyde, e.g., 3-hydroxypropionaldehyde is disclosed which comprises contacting a combination of an epoxide, carbon monoxide and hydrogen in the presence of a rhodium-containing catalyst composition effective to promote the hydroformylation of the epoxide at conditions effective to form at least one of a 1,3-diol and a 3-hydroxyaldehyde. The rhodium-containing catalyst composition comprises an anionic rhodium-containing complex. A promoter component is preferably provided to enhance at least one of the rate and selectivity of the epoxide hydroformylation reaction. Rhodium-containing compositions and a processes for producing rhodium-containing compositions are also disclosed.

    摘要翻译： 一种制备1,3-二醇，例如，1,3-丙二醇，和/或3-羟基醛，例如过程，3-羟基丙醛是游离缺失盘其包括使在存在环氧化物，一氧化碳和氢气的组合 的含铑催化剂组合物可有效促进环氧化物的羰基化在有效形成1,3-二醇中的至少一种和3-羟基醛的条件。 含铑催化剂组合物包括含铑阴离子配合物。 包括助催化剂成分优选地设置，以提高环氧化物羰基化反应的速率和选择性中的至少一种。 因此组合物和方法用于生产含铑组合物的含铑是游离缺失盘。

    Ethylene polymerization catalyst
    3.
    发明公开
    Ethylene polymerization catalyst 失效
    乙烯聚合催化剂

    公开(公告)号：EP0361520A3

    公开(公告)日：1991-08-28

    申请号：EP89118092.9

    申请日：1989-09-29

    申请人： UNION CARBIDE CHEMICALS AND PLASTICS COMPANY INC. (a New York corporation)

    发明人： Cann, Kevin Joseph ,  Karol, Frederick Joseph ,  Lee, Hiu Hee ,  Marcinkowsky, Arthur Ernest

    IPC分类号： C08F4/68 ,  C08F10/02

    CPC分类号： C08F10/02 ,  C08F4/68

    摘要： A vanadium catalyst composition comprising:
    (i) the reaction product of a vanadium compound and an electron donor, which is a liquid, organic Lewis base in which the vanadium compound is soluble; (ii) a hydrocarbyl aluminum cocatalyst; and (iii) a promoter having the following formula:
    C₃(X) a (F) b (H) c
    wherein X is chlorine, bromine, or iodine, and each X can be alike or different
    a = an integer from 6 to 8
    b = an integer from 0 to 2
    c = an integer from 0 to 2
    a + b + c = 8

    摘要翻译： 一种钒催化剂组合物，它包含：（ⅰ）钒化合物和电子给体的反应产物，它是钒化合物可溶于其中的液体有机路易斯碱; （ii）烃基铝助催化剂; 和（ⅲ）具有下式的助催化剂：C 3（X）a（F）b（H）c其中X是氯，溴或碘，每个X可以相同或不同，a = 6至8的整数 b = 0至2的整数c = 0至2的整数a + b + c = 8

    Wet set additives for high resilience foam
    6.
    发明公开
    Wet set additives for high resilience foam 失效
    添加剂ür。。on on on on。。。。。。。。。。。。。。。。

    公开(公告)号：EP0367283A2

    公开(公告)日：1990-05-09

    申请号：EP89120384.6

    申请日：1989-11-03

    申请人： UNION CARBIDE CHEMICALS AND PLASTICS COMPANY INC. (a New York corporation)

    发明人： Whitman, Robert Don ,  Argento, Benny John

    IPC分类号： C08G18/48 ,  C08G18/40 ,  C08G18/65

    CPC分类号： C08G18/4072 ,  A61K8/44 ,  A61Q11/00 ,  C08G18/4804 ,  C08G18/4833 ,  C08G18/4841 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0058

    摘要： Ethylene oxide (EO) adducts of di- ard tri-functional starters, such as, trimethylolpropane and glycerine, provide unexpected improvements in the "wet compression set" properties of high resilience (HR) urethane foams. Heretofore, wet set improvements have been achieved through the use of EO adducts of tetrols because of the high degree of crosslink density which these materials impart to a urethane polymeric composition. One commercial wet set additive, which is an EO adduct of pentaerythritol and diglycerine, is an effective wet set improver. Surprisingly, EO adducts of di- and tri-functional starters provide improvements in foam wet set properties, which are comparable to those obtained with such commercial wet set additive. Specifically, EO adducts of glycerine in the 500 to 10,000 molecular weight range yield foam wet set improvements equal to those of such commercial wet set additive at as low as 20 percent of the use level on an equivalent weight basis. Moreover, the EO adducts of glycerine yield foams having improved elongation properties and improved processing (stability) characteristics as compared to those observed with such commercial wet set additives. An EO adduct of glycerine having a number average MW of 1,000 is particularly useful in the invention.

    摘要翻译： 二元三官能起始物（如三羟甲基丙烷和甘油）的环氧乙烷（EO）加成物在高弹性（HR）聚氨酯泡沫的“湿压缩永久变形”性能方面提供了意想不到的改进。 迄今为止，由于这些材料赋予氨基甲酸酯聚合物组合物的交联密度高，所以通过使用四元醇的EO加合物已经实现了湿定型改进。 一种商业湿定型添加剂，它是季戊四醇和二甘油的EO加合物，是一种有效的湿定型改良剂。 令人惊讶的是，二官能和三功能起始机的EO加合物提供了泡沫湿固化性能的改进，这与用这种商业湿固定添加剂获得的那些相当。 具体地说，甘油在500至10,000分子量范围内的EO加合物产生等于这种商业湿定型添加剂的泡沫湿固化改进，其用量低于当量重量的20％。 此外，与使用这种商业湿定型添加剂观察到的那些相比，甘油的EO加合物产生具有改善的伸长性能和改进的加工（稳定性）特性的泡沫。 数均分子量为1,000的甘油的EO加成物在本发明中是特别有用的。

    Alkoxylation using modified group IIIB metal-containing bimetallic or polymetallic catalysts
    8.
    发明公开
    Alkoxylation using modified group IIIB metal-containing bimetallic or polymetallic catalysts 失效
    Alkoxylierung mit Verwendung von modifizierten Gruppe-IIIB- Metall enthaltenden biender polymetallischen Katalysatoren。

    公开(公告)号：EP0361620A2

    公开(公告)日：1990-04-04

    申请号：EP89202443.1

    申请日：1989-09-29

    申请人： UNION CARBIDE CHEMICALS AND PLASTICS COMPANY INC. (a New York corporation)

    发明人： King, Stephen Wayne

    IPC分类号： C07C43/11 ,  C07C41/03 ,  B01J31/12 ,  C11D1/72

    CPC分类号： C07C41/03 ,  B01J31/223 ,  B01J2531/37 ,  C07C43/11 ,  C07C43/13

    摘要： This invention relates to modified Group IIIB metal-containing bimetallic or polymetallic catalysts and the use thereof in the preparation of alkoxylation products, i.e., condensation reaction products of alkylene oxides and organic compounds having at least one active hydrogen. In another aspect of this invention, processes are provided for preparing the modified Group IIIB metal-containing bimetallic or polymetallic catalysts for alkoxylation using a Group IIIB metal or a Group IIIB metal-containing compound as sources for the catalytically-active group IIIB metal. In a further aspect of this invention, processes are provided for preparing alkoxylation products that have beneficial, narrow molecular weight ranges using the modified Group IIIB metal-containing bimetallic or polymetallic catalysts.

    摘要翻译： 本发明涉及经修饰的含IIIB族金属的双金属或多金属催化剂及其在制备烷氧基化产物中的用途，即环氧烷烃与具有至少一个活性氢的有机化合物的缩合反应产物。 在本发明的另一方面，提供了使用IIIB族金属或IIIB族金属化合物作为催化活性IIIB族金属的来源来制备用于烷氧基化的改性的含IIIB族金属的双金属或多金属催化剂的方法。 在本发明的另一方面，提供了使用改性的含IIIB族金属的双金属或多金属催化剂制备具有有益的窄分子量范围的烷氧基化产物的方法。

    Alkoxylation using modified calcium-containing bimetallic or polymetallic catalysts
    9.
    发明公开
    Alkoxylation using modified calcium-containing bimetallic or polymetallic catalysts 失效
    Alkoxylierung mit Verwendung von modifizierten Calcium enthaltenden，biender polymetallischen Katalysatoren。

    公开(公告)号：EP0361617A2

    公开(公告)日：1990-04-04

    申请号：EP89202440.7

    申请日：1989-09-29

    申请人： UNION CARBIDE CHEMICALS AND PLASTICS COMPANY INC. (a New York corporation)

    发明人： King, Stephen Wayne

    IPC分类号： C07C43/11 ,  C07C41/03 ,  B01J31/12 ,  C11D1/72

    CPC分类号： C08G65/269 ,  B01J31/223 ,  B01J2531/23 ,  C07C41/03 ,  C08G65/2651 ,  C07C43/11

    摘要： This invention relates to modified calcium-containing bimetallic or polymetallic catalysts and the use thereof in the preparation of alkoxylation products, i.e., condensation reaction products of alkylene oxides and organic compounds having at least one active hydrogen. In another aspect of this invention, processes are provided for preparing modified calcium-containing bimetallic or polymetallic catalysts for alkoxylation using calcium metal or a calcium-containing compound as sources for the catalytically-active calcium. In a further aspect of this invention, processes are provided for preparing alkoxylation products that have beneficial, narrow molecular weight ranges using the modified calcium-containing bimetallic or polymetallic catalysts.

    摘要翻译： 本发明涉及改性含钙双金属或多金属催化剂及其在制备烷氧基化产物中的用途，即环氧烷烃与具有至少一个活性氢的有机化合物的缩合反应产物。 在本发明的另一方面，提供了使用钙金属或含钙化合物作为催化活性钙的来源制备用于烷氧基化的改性含钙双金属或多金属催化剂的方法。 在本发明的另一方面，提供了使用改性的含钙双金属或多金属催化剂制备具有有益的窄分子量范围的烷氧基化产物的方法。