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公开(公告)号：EP0158496A2
公开(公告)日：1985-10-16
申请号：EP85302256.4
申请日：1985-04-01
申请人： UNIROYAL, INC.
IPC分类号： C07D333/48 , C07D333/22 , C07D409/06 , A01N43/10
CPC分类号： C07D333/48 , A01N43/10 , C07C323/00 , C07D333/22 , C07D409/06
摘要： A compound having the formula
wherein R is C 1 -C 4 alkyl, cyclopropyl, C 2 -C 4 alkoxyalkyl, C 4 -C 8 dialkylaminoalkyl, C 2 -C 4 alkylthioalkyl, C 2 -C 4 alkylsulfinylalkyl, C 2 -C 4 alkylsulfonylalkyl, phenyl, C 7 -C 9 aralkyl, C 7 -C 9 alkaryl, furyl, thienyl or pyridyl; R 1 is hydrogen or C 1 -C 4 alkyl; R 2 is hydrogen or C 1 -C 4 alkyl; R 3 , R 4 and R 5 are the same or different and the hydrogen or C 1 -C 4 alkyl; R 6 and R 7 are the same or different and are hydrogen, C 1 -C 4 alkyl, allyl, benzyl or tolyl with the proviso that both R 6 and R 7 are not hydrogen; and n is 0, 1 or 2 and methods of making same are disclosed. This compound is useful as a pesticide.
Intermediates useful in synthesizing this pesticidally effective compound are also taught. These intermediate compounds have the structural formulas
where R, R', R 2 , R 3 , R 4 , R 5 and n have the same meanings as the pesticidally effective compound recited above; and Q is a leaving group. Methods of making these intermediate compounds are described.-
公开(公告)号：EP0156638A3
公开(公告)日：1986-05-07
申请号：EP85302034
申请日：1985-03-25
申请人： UNIROYAL, INC.
IPC分类号： C07F09/65 , A01N57/16 , C07D261/06
CPC分类号： C07D271/10 , A01N57/16 , C07D413/04 , C07F9/65312
摘要： A compound of the formula
wherein R is allyl, halocyclopropyl, C 3 -C 5 -alkoxycarbonylmethyl, CrCg aralkyl, styryl, phenyl, naphthyl, furanyl, pyridyl, thienyl, phenyl substituted with halogen, C 1 -C 4 alkyl, trihalomethyl, C 1 -C 4 alkoxy, trihalomethoxy, trihalomethylthio, C 1 -C 4 alkylthio, phenyl, phenoxy, cyano or nitro or C 7 -C 9 aralkyl substituted with halogen, C 1 -C 4 alkyl, trihalomethyl, C 1 -C 4 alkoxy, trihalomethoxy, trihalomethylthio, C 1 -C 4 alkylthio, phenyl, phenoxy, cyano or nitro; R is hydrogen, C 1 -C 3 alkyl, C 7 -C 9 aralkyl, phenyl , C 7 -C 9 aralkyl substituted with halogen, C 1 -C 4 alkyl, trihalomethyl, C 1 -C 4 alkoxy, trihalomethoxy, trihalomethylthio, C 1 -C 4 alkylthio, phenyl, phenoxy, cyano or nitro or phenyl substituted with halogen, C,-C, alkyl, trihalomethyl, C 1 -C 4 alkoxy, trihalomethoxy, trihalomethylthio, C,-C 4 alkylthio, phenyl phenoxy, cyano or nitro, however, if R is substituted phenyl or substituted C 7 -C 9 aralkyl. then R' cannot be hydrogen; R 2 is C 1 -C 4 alkyl, however, if R or R' is 4-chlorophenyl, R 2 cannot be isopropyl; and X, Y and Z are the same or different and are oxygen or sulfur, is disclosed. A method is provided for protection against pests by employing a pesticidally effective amount of the compound above. A composition comprising the compound above and an inert carrier therefor, for pesticidal use, is also taught. The disclosure also recites a compound of the formula
where R and R' have the meanings of the first mentioned compound. The compound, effective as an intermediate in .the synthesis of the above compound, is produced by the reaction of a compound of the formula
where R has the meanings given above with a compound of the formula
where R' has the meanings given above.-
公开(公告)号：EP0158496A3
公开(公告)日：1986-03-26
申请号：EP85302256
申请日：1985-04-01
申请人： UNIROYAL, INC.
IPC分类号： C07D333/48 , C07D333/22 , C07D409/06 , A01N43/10
CPC分类号： C07D333/48 , A01N43/10 , C07C323/00 , C07D333/22 , C07D409/06
摘要： A compound having the formula
wherein R is C 1 -C 4 alkyl, cyclopropyl, C 2 -C 4 alkoxyalkyl, C 4 -C 8 dialkylaminoalkyl, C 2 -C 4 alkylthioalkyl, C 2 -C 4 alkylsulfinylalkyl, C 2 -C 4 alkylsulfonylalkyl, phenyl, C 7 -C 9 aralkyl, C 7 -C 9 alkaryl, furyl, thienyl or pyridyl; R 1 is hydrogen or C 1 -C 4 alkyl; R 2 is hydrogen or C 1 -C 4 alkyl; R 3 , R 4 and R 5 are the same or different and the hydrogen or C 1 -C 4 alkyl; R 6 and R 7 are the same or different and are hydrogen, C 1 -C 4 alkyl, allyl, benzyl or tolyl with the proviso that both R 6 and R 7 are not hydrogen; and n is 0, 1 or 2 and methods of making same are disclosed. This compound is useful as a pesticide. Intermediates useful in synthesizing this pesticidally effective compound are also taught. These intermediate compounds have the structural formulas
where R, R', R 2 , R 3 , R 4 , R 5 and n have the same meanings as the pesticidally effective compound recited above; and Q is a leaving group. Methods of making these intermediate compounds are described.-
公开(公告)号：EP0156638A2
公开(公告)日：1985-10-02
申请号：EP85302034.5
申请日：1985-03-25
申请人： UNIROYAL, INC.
IPC分类号： C07F9/65 , C07D271/10 , C07D261/06 , A01N57/16
CPC分类号： C07D271/10 , A01N57/16 , C07D413/04 , C07F9/65312
摘要： A compound of the formula
wherein R is allyl, halocyclopropyl, C 3 -C 5 -alkoxycarbonylmethyl, CrCg aralkyl, styryl, phenyl, naphthyl, furanyl, pyridyl, thienyl, phenyl substituted with halogen, C 1 -C 4 alkyl, trihalomethyl, C 1 -C 4 alkoxy, trihalomethoxy, trihalomethylthio, C 1 -C 4 alkylthio, phenyl, phenoxy, cyano or nitro or C 7 -C 9 aralkyl substituted with halogen, C 1 -C 4 alkyl, trihalomethyl, C 1 -C 4 alkoxy, trihalomethoxy, trihalomethylthio, C 1 -C 4 alkylthio, phenyl, phenoxy, cyano or nitro; R is hydrogen, C 1 -C 3 alkyl, C 7 -C 9 aralkyl, phenyl , C 7 -C 9 aralkyl substituted with halogen, C 1 -C 4 alkyl, trihalomethyl, C 1 -C 4 alkoxy, trihalomethoxy, trihalomethylthio, C 1 -C 4 alkylthio, phenyl, phenoxy, cyano or nitro or phenyl substituted with halogen, C,-C, alkyl, trihalomethyl, C 1 -C 4 alkoxy, trihalomethoxy, trihalomethylthio, C,-C 4 alkylthio, phenyl phenoxy, cyano or nitro, however, if R is substituted phenyl or substituted C 7 -C 9 aralkyl. then R' cannot be hydrogen; R 2 is C 1 -C 4 alkyl, however, if R or R' is 4-chlorophenyl, R 2 cannot be isopropyl; and X, Y and Z are the same or different and are oxygen or sulfur, is disclosed. A method is provided for protection against pests by employing a pesticidally effective amount of the compound above. A composition comprising the compound above and an inert carrier therefor, for pesticidal use, is also taught.
The disclosure also recites a compound of the formula
where R and R' have the meanings of the first mentioned compound. The compound, effective as an intermediate in .the synthesis of the above compound, is produced by the reaction of a compound of the formula
where R has the meanings given above with a compound of the formula
where R' has the meanings given above.-
公开(公告)号：EP0145328A3
公开(公告)日：1985-07-10
申请号：EP84307910
申请日：1984-11-14
申请人： UNIROYAL, INC.
CPC分类号： A01N57/08 , C07F9/6524
摘要： A compound having the formula
where X, X' and X 2 are oxygen or sulfur; Y is oxygen, sulfur or NH; R' is C 1 -C 12 alkyl, C 1 -C 9 aralkyl, phenyl, C 2 -C 4 alkenyl, phenyl substituted with halogen, C 1 -C 4 alkyl, C 1 -C 2 haloalkyl, C 1 -C 4 alkoxy, C 1 -C 4 haloalkoxy, C 1 -C 4 alkylthio, C 1 -C 4 haloalkylthio, C 2 -C 5 alkoxycarbonyl, phenoxy, nitro or cyano, phenoxy substituted with halogen, C 1 -C 4 alkyl, C 1 -C 2 haloalkyl, C,-C alkoxy, C 1 -C 4 haloalkoxy, C 1 -C 4 alkylthio, C 1 -C 4 haloalkylthio, C 2 -C 5 alkoxycarbonyl, nitro or cyano or C 7 -C 9 aralkyl substituted on the phenyl ring with halogen, C,-C alkyl, C 1 -C 2 haloalkyl, C,-C alkoxy, methylenedioxy, nitro or cyano; R 2 is hydrogen, C 1 -C 4 alkyl, phenyl or phenyl substituted with C 1 -C 4 alkyl, C 1 -C 4 alkoxy, halogen nitro or cyano; and R 3 and R 4 may be the same or different and are C 1 -C 4 alkyl is disclosed. The application is also directed to a pesticidal composition comprising the above-recited compound and a carrier. Finally, a method for controlling pests by employing a pesticidally effective amount of the above-recited compound is described.
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