公开(公告)号：EP2697166A2

公开(公告)日：2014-02-19

申请号：EP12864937.3

申请日：2012-04-05

申请人： UOP LLC

发明人： HURST, Jack E. ,  CHENG, Linda S. ,  BROACH, Robert W.

IPC分类号： C01B39/22 ,  B01J20/18 ,  C07C7/12 ,  C07C15/08

CPC分类号： B01J20/183 ,  B01J20/186 ,  B01J20/28004 ,  B01J20/28011 ,  C01B39/22 ,  C07C7/12 ,  C07C15/08

摘要： A zeolitic binder-converted composition comprising (a) a zeolite X composition having at least a first zeolite X having a mean diameter not greater than 2.7 microns, and a second zeolite X, wherein the second zeolite X is obtained by converting a binder material to the second zeolite X and the binder material is in a range from 5 to 50 wt% of the zeolite X composition; and (b) an unconverted binder material content, after conversion to the second zeolite X is complete, in a range from 0 to 3 wt% of the zeolite X composition. The zeolite X composition has an average Si/Al framework mole ratio in a range from 1.0 to 1.5, and a relative LTA intensity not greater than 1.0, as determined by x-ray diffraction (XRD). The zeolitic binder-converted composition is useful in a process for separating para-xylene from a mixture of C
8 alkylaromatics.

公开(公告)号：EP2691170B1

公开(公告)日：2018-03-07

申请号：EP12765521.5

申请日：2012-03-23

申请人： UOP LLC

发明人： HURST, Jack E. ,  CHENG, Linda S.

IPC分类号： B01J20/18 ,  C01B39/18 ,  C01B39/02 ,  B01J19/18 ,  B01D53/02 ,  B01J20/30 ,  C07C7/13

CPC分类号： B01D53/02 ,  B01D2253/1085 ,  B01D2253/25 ,  B01D2256/24 ,  B01D2257/7027 ,  B01J20/183 ,  B01J20/186 ,  B01J20/3028 ,  B01J20/3042 ,  C07C7/13 ,  Y02P20/52 ,  C07C15/08

摘要： Binderless BaKX zeolitic adsorbents, methods for their production, and adsorptive separation using the adsorbents are provided. An adsorbent comprises a first Zeolite X having a silica to alumina molar ratio of from about 2.0 to about 3.0; a binder-converted Zeolite X wherein a ratio of the binder-converted Zeolite X to the first Zeolite X ranges from about 10:90 to about 20:80 by weight; and barium and potassium at cationic exchangeable sites within the binderless BaKX zeolitic adsorbent. Potassium ranges from about 0.9 wt % to about 1.5 wt % and barium ranges from about 30 wt % to about 34 wt % of the binderless BaKX zeolitic adsorbent.

公开(公告)号：EP4147105A1

公开(公告)日：2023-03-15

申请号：EP21799485.4

申请日：2021-04-26

申请人： UOP LLC

发明人： SINKLER, Wharton ,  CHENG, Linda S. ,  ADAMS, Paul ,  HARRIS, James W.

IPC分类号： G05B19/418 ,  G16Y10/25

公开(公告)号：EP2697165A1

公开(公告)日：2014-02-19

申请号：EP12771887.2

申请日：2012-04-05

申请人： UOP LLC

发明人： HURST, Jack E. ,  CHENG, Linda S. ,  BROACH, Robert W.

IPC分类号： C01B39/02 ,  C01B33/06 ,  B01J20/18 ,  B01J20/16

CPC分类号： C01B39/46 ,  B01J20/18 ,  B01J20/183 ,  B01J29/08 ,  C01B39/22 ,  C07C7/12 ,  Y02P20/52 ,  C07C15/08

摘要： A zeolite X having (a) a Si/Al framework mole ratio in a range from 1.0 to 1.5; (b) a mean diameter not greater than 2.7 microns; and (c) a relative LTA intensity not greater than 0.35, as determined by x-ray diffraction (XRD). The relative LTA intensity is calculated as 100 times the quotient of a sample LTA XRD intensity divided by a reference XRD intensity of an LTA-type zeolite material. The intensities are summed for each LTA peak with Miller indices of (2 0 0), (4 2 0), and (6 2 2) at 7.27 ±0.16°, 16.29 ± 0.34° and 24.27 ± 0.50° 2 θ.

公开(公告)号：EP2691170A2

公开(公告)日：2014-02-05

申请号：EP12765521.5

申请日：2012-03-23

申请人： UOP LLC

发明人： HURST, Jack E. ,  CHENG, Linda S.

IPC分类号： B01J20/18 ,  C01B39/18 ,  C01B39/02 ,  B01J19/18

CPC分类号： B01D53/02 ,  B01D2253/1085 ,  B01D2253/25 ,  B01D2256/24 ,  B01D2257/7027 ,  B01J20/183 ,  B01J20/186 ,  B01J20/3028 ,  B01J20/3042 ,  C07C7/13 ,  Y02P20/52 ,  C07C15/08

摘要： Binderless BaKX zeolitic adsorbents, methods for their production, and adsorptive separation using the adsorbents are provided. An adsorbent comprises a first Zeolite X having a silica to alumina molar ratio of from 2.0 to 3.0; a binder-converted Zeolite X wherein a ratio of the binder-converted Zeolite X to the first Zeolite X ranges from 10 : 90 to 20 : 80 by weight; and barium and potassium at cationic exchangeable sites within the binderless BaKX zeolitic adsorbent. Potassium ranges from 0.9 wt% to 1.5 wt% and barium ranges from 30 wt% to 34 wt% of the binderless BaKX zeolitic adsorbent.