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    CATALYTIC CRACKING CATALYST HAVING RICH MESOPOROUS STRUCTURE AND PREPARATION METHOD THEREFOR
    1.
    发明公开
    CATALYTIC CRACKING CATALYST HAVING RICH MESOPOROUS STRUCTURE AND PREPARATION METHOD THEREFOR 审中-实审

    公开(公告)号：EP4414072A1

    公开(公告)日：2024-08-14

    申请号：EP22877882.5

    申请日：2022-09-28

    申请人： China Petroleum & Chemical Corporation ,  Sinopec Research Institute of Petroleum Processing Co., Ltd.

    发明人： YU, Shanqing ,  LIN, Wei ,  YUAN, Shuai ,  LIU, Yuqing ,  ZHANG, Jiexiao

    IPC分类号： B01J29/08 ,  B01J35/10 ,  C10G11/05

    CPC分类号： Y02P20/52 ,  B01J29/08 ,  C10G11/05 ,  B01J35/60

    摘要： A catalytic cracking catalyst having a rich mesoporous structure and a preparation method therefor. The catalyst, on a dry basis, comprises: 10-35% by weight of a meso and macro pore aluminum oxide based on aluminum oxide, 5-30% by weight of an acidifying binder based on oxide, 2-20% by weight of a second binder based on oxide, 20-60% by weight of a zeolite, and 5-50% by weight of a clay; the meso and macro pore aluminum oxide is an aluminum oxide with a pseudo boehmite structure, which has a total pore volume of 0.5-2.0 mL/g, an average pore size of 5-30 nm, and a specific surface area of 250-450 m 2/g, wherein the pore volume of 5-100 nm pores accounts for 80% or more of the total pore volume; the weight ratio of the acidifying binder to the meso and macro pore aluminum oxide is 0.5-1.0. The catalytic cracking catalyst according to the present invention has a rich mesopore structure, a total pore volume not less than 0.200 mL/g, the pore volume of 2-100 nm meso and macro pores accounting for 70% or more of the total pore volume, and the pore volume of 4-50 nm mesoporous pores accounting for 60% or more of the total pore volume, as measured by a low-temperature nitrogen adsorption method. Therefore, it has a great attrition resistance strength, an enhanced heavy oil conversion capacity, a significantly improved coke selectivity.

    CATALYST FOR USE IN PRODUCTION OF METHYL METHACRYLATE, AND METHOD FOR PRODUCING METHYL METHACRYLATE
    3.
    发明公开
    CATALYST FOR USE IN PRODUCTION OF METHYL METHACRYLATE, AND METHOD FOR PRODUCING METHYL METHACRYLATE 审中-公开
    催化剂的使用在甲基用于生产甲基组成的制造，加工

    公开(公告)号：EP3088079A4

    公开(公告)日：2017-06-14

    申请号：EP14875833

    申请日：2014-12-22

    申请人： MITSUBISHI GAS CHEMICAL CO

    发明人： HIGUCHI KATSUMI ,  HIROKAWA SAORI ,  SUGANO YUUICHI

    IPC分类号： B01J29/08 ,  C07B61/00 ,  C07C67/327 ,  C07C69/54

    CPC分类号： C07C67/327 ,  B01J29/08 ,  B01J2229/42 ,  C07C69/54

    摘要： According to the present invention, a molded catalyst for use in the production of methyl methacrylate can be provided. The molded catalyst comprises synthetic faujasite-type zeolite and a layered magnesium silicate compound, wherein the sulfur content in the layered magnesium silicate compound is 0.10% by weight or less. According to the present invention, a method for producing methyl methacrylate can also be provided. The method is characterized by comprising a step of carrying out a gas-phase catalytic reaction of methyl ±-hydroxyisobutyrate using the above-mentioned molded catalyst for use in the production of methyl methacrylate.

    摘要翻译： 。根据本发明，可以提供用于生产甲基丙烯酸甲酯的使用的模制催化剂。 模制的催化剂包括合成八面型沸石和层状硅酸镁化合物，重量或更少worin在层状硅酸镁化合物的硫含量≤0.10％。 。根据本发明，因此可以提供一种用于生产甲基丙烯酸甲酯的方法。 该方法通过包括使用用于生产甲基丙烯酸甲酯的使用上述成型体催化剂进行甲基的气相催化反应±羟基异丁的步骤为特征。