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公开(公告)号:EP4234589A2
公开(公告)日:2023-08-30
申请号:EP23172626.6
申请日:2017-04-17
发明人: LESTER, Charles D. , GOODE, Mark G. , LYNN, Timothy R. , CANN, Kevin J. , MOORHOUSE, John H. , MATTHEWS, William A. , SUN, Kefu , ALEXANDRE, Francois
IPC分类号: C08F2/34
摘要: Embodiments of the present disclosure are directed towards method for modifying a polymer flow index. As an example, a method for modifying a polymer flow index can include providing monomers to a polymerization reactor, providing a chromium catalyst to the polymerization reactor, and providing an active amount of a flow index modifier to the polymerization reactor, wherein the flow index modifier is selected from carbon dioxide, carbon monoxide, 2,4-hexadiene, and combinations thereof.
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公开(公告)号:EP3105257B1
公开(公告)日:2020-10-21
申请号:EP15705878.5
申请日:2015-02-10
发明人: LUE, Ching-Tai , RIX, Francis C. , BOLLER, Timothy M. , GIESBRECHT, Garth R. , GOODE, Mark G. , KAO, Sun-Chueh , LI, Dongming , PEQUENO, R. Eric , ZILKER, JR. Daniel P.
IPC分类号: C08F2/34 , C08F210/02 , C08F210/16 , C08F4/6592 , C08J5/18
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公开(公告)号:EP3223943A1
公开(公告)日:2017-10-04
申请号:EP15808834.4
申请日:2015-11-23
发明人: CANN, Kevin J. , MOORHOUSE, John H. , KHOKHANI, Parul A. , TAMARGO, Tomas T. , GROSS, Kevin R. , GOODE, Mark G.
CPC分类号: C08F110/02 , B01J21/08 , B01J23/26 , B01J2229/34 , C08F2410/01 , C08F2410/02 , C08F4/78 , C08F4/69
摘要: Modified chromium-based catalyst compositions for olefin polymerization are disclosed. The modifiers prevent or reduce catalyst particle aggregation providing improved catalyst particle dispersion and consistent flow index response of the compositions in olefin polymerization.
摘要翻译: 公开了用于烯烃聚合的改性铬基催化剂组合物。 改性剂阻止或减少催化剂颗粒聚集,提供改进的催化剂颗粒分散和组合物在烯烃聚合中的一致的流动指数响应。
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公开(公告)号:EP3188831A1
公开(公告)日:2017-07-12
申请号:EP15760619.5
申请日:2015-09-01
摘要: A method including contacting a chromium-based catalyst with a reducing agent in a solvent to lower an oxidation state of at least some chromium in the chromium-based catalyst to give a reduced chromium-based catalyst, drying the reduced chromium-based catalyst at a temperature, and adjusting the temperature to affect the flow index response of the reduced chromium-based catalyst.
摘要翻译: 一种方法包括使铬基催化剂与还原剂在溶剂中接触以降低铬基催化剂中至少一些铬的氧化态以得到还原的铬基催化剂,将还原后的铬基催化剂在 温度,并调节温度以影响还原的铬基催化剂的流动指数响应。
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公开(公告)号:EP3041888A1
公开(公告)日:2016-07-13
申请号:EP14766321.5
申请日:2014-09-02
IPC分类号: C08J5/18 , C08F110/02
CPC分类号: C08F210/16 , C08J5/18 , C08J2323/08 , C08F10/00 , C08F4/025 , C08F4/6565 , C08F4/6555 , C08F4/646 , C08F4/6495 , C08F210/14 , C08F2500/12 , C08F2500/11 , C08F210/08
摘要: Methods for making olefin polymerization catalysts and methods for making polyethylene polymers using the catalysts are provided. The polyethylenes can have a molecular weight distribution (MWD) of about 4.5 to about 14, a slope of strain hardening greater than about 0.75, and a melt flow ratio (MFR) greater than or equal to 8.33+(4.17×MWD).
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公开(公告)号:EP4234589A3
公开(公告)日:2023-09-13
申请号:EP23172626.6
申请日:2017-04-17
发明人: LESTER, Charles D. , GOODE, Mark G. , LYNN, Timothy R. , CANN, Kevin J. , MOORHOUSE, John H. , MATTHEWS, William A. , SUN, Kefu , ALEXANDRE, Francois
摘要: Embodiments of the present disclosure are directed towards method for modifying a polymer flow index. As an example, a method for modifying a polymer flow index can include providing monomers to a polymerization reactor, providing a chromium catalyst to the polymerization reactor, and providing an active amount of a flow index modifier to the polymerization reactor, wherein the flow index modifier is selected from carbon dioxide, carbon monoxide, 2,4-hexadiene, and combinations thereof.
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7.
公开(公告)号:EP3998293A1
公开(公告)日:2022-05-18
申请号:EP22150190.1
申请日:2015-02-10
发明人: LUE, Ching-Tai , RIX, Francis C. , BOLLER, Timothy M. , GIESBRECHT, Garth R. , GOODE, Mark G. , FARLEY, James M. , KAO, Sun-Chueh , LI, Dongming , PEQUENO, R. Eric , ZILKER, Daniel P. Jr.
IPC分类号: C08F210/16 , C08F4/6592
摘要: The invention relates to a polymer, comprising ethylene and at least one alpha olefin having 4 carbon atoms, wherein the polymer has:
a total haze of less than about 30 %;
an average modulus of greater than about 30,000 psi;
a dart impact strength of greater than about 120 g for a 1 mil film;
a melt index ratio (MIR) greater than about 25; and
an Elmendorf machine direction tear of greater than about 170 g at 1 mil film gauge.-
8.
公开(公告)号:EP3998292A1
公开(公告)日:2022-05-18
申请号:EP22150196.8
申请日:2015-02-10
发明人: LUE, Ching-Tai , RIX, Francis C. , BOLLER, Timothy M. , GIESBRECHT, Garth R. , GOODE, Mark G. , FARLEY, James M. , KAO, Sun-Chueh , LI, Dongming , PEQUENO, R. Eric , ZILKER, Daniel P. Jr.
IPC分类号: C08F210/02 , C08F4/6592 , C08F2/34
摘要: The invention relates to a polymer, comprising ethylene and at least one alpha olefin having from 4 to 20 carbon atoms, wherein the polymer has:
an absence of a negative inflection point in a van Gurp Palmen (vGP) plot at a frequency of between about 0.1 rad/s and 300 rad/s at 190 °C;
a melt index ratio (MIR) greater than about 40;
a relationship between average modulus (M) and dart impact strength in g/mil (DIS) complying with the formula: DIS ≥ 0.8 x 100 + e 11.71 − 0.000268 xM + 2.183 x 10 − 9 xM 2 .-
公开(公告)号:EP3700948A1
公开(公告)日:2020-09-02
申请号:EP18796198.2
申请日:2018-10-09
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公开(公告)号:EP3188834A1
公开(公告)日:2017-07-12
申请号:EP15760621.1
申请日:2015-09-01
IPC分类号: B01J37/16 , B01J23/26 , C08F4/69 , C08F210/16
CPC分类号: C08F210/16 , C08F4/69 , C08F2/01 , C08F210/14 , C08F2500/12 , C08F2500/24 , C08F2500/18
摘要: A system and method for feeding a chromium-based catalyst to a polymerization reactor; adding a reducing agent to the chromium-based catalyst, and polymerizing an olefin into a polyolefin in the polymerization reactor in the presence of the chromium-based catalyst.
摘要翻译: 用于将铬基催化剂供给聚合反应器的系统和方法; 在铬系催化剂中添加还原剂,在铬系催化剂的存在下使聚合反应器中的烯烃聚合。
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