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1.发明公开
公开(公告)号：EP3998293A1
公开(公告)日：2022-05-18
申请号：EP22150190.1
申请日：2015-02-10
发明人： LUE, Ching-Tai , RIX, Francis C. , BOLLER, Timothy M. , GIESBRECHT, Garth R. , GOODE, Mark G. , FARLEY, James M. , KAO, Sun-Chueh , LI, Dongming , PEQUENO, R. Eric , ZILKER, Daniel P. Jr.
IPC分类号： C08F210/16 , C08F4/6592
摘要： The invention relates to a polymer, comprising ethylene and at least one alpha olefin having 4 carbon atoms, wherein the polymer has:
a total haze of less than about 30 %;
an average modulus of greater than about 30,000 psi;
a dart impact strength of greater than about 120 g for a 1 mil film;
a melt index ratio (MIR) greater than about 25; and
an Elmendorf machine direction tear of greater than about 170 g at 1 mil film gauge.-
2.发明公开
公开(公告)号：EP3998292A1
公开(公告)日：2022-05-18
申请号：EP22150196.8
申请日：2015-02-10
发明人： LUE, Ching-Tai , RIX, Francis C. , BOLLER, Timothy M. , GIESBRECHT, Garth R. , GOODE, Mark G. , FARLEY, James M. , KAO, Sun-Chueh , LI, Dongming , PEQUENO, R. Eric , ZILKER, Daniel P. Jr.
IPC分类号： C08F210/02 , C08F4/6592 , C08F2/34
摘要： The invention relates to a polymer, comprising ethylene and at least one alpha olefin having from 4 to 20 carbon atoms, wherein the polymer has:
an absence of a negative inflection point in a van Gurp Palmen (vGP) plot at a frequency of between about 0.1 rad/s and 300 rad/s at 190 °C;
a melt index ratio (MIR) greater than about 40;
a relationship between average modulus (M) and dart impact strength in g/mil (DIS) complying with the formula: DIS ≥ 0.8 x 100 + e 11.71 − 0.000268 xM + 2.183 x 10 − 9 xM 2 .-
公开(公告)号：EP3105265A1
公开(公告)日：2016-12-21
申请号：EP15705883.5
申请日：2015-02-10
发明人： VANDERLENDE, Daniel D. , HARLAN, Jeff C. , PENG, Haiqing , AWE, Michael D. , KUHLMAN, Roger L. , LUE, Ching-Tai , LYNN, Timothy R. , MARIOTT, Wesley R. , ZILKER, Daniel P. Jr.
IPC分类号： C08F210/16 , C08F4/6592 , C08F2/00
CPC分类号： C08F210/16 , C07F17/00 , C08F2/00 , C08F2/34 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F4/65927 , C08F4/76 , C08F210/02 , C08F210/08 , C08F210/14 , C08F2410/02 , C08F2420/00 , C08F2420/01 , C08F2500/01 , C08F2500/02 , C08F2500/08 , C08F2500/09 , C08F2500/10 , C08F2500/11 , C08F2500/12 , C08F2500/13 , C08F2500/18 , C08F2800/20 , C08J5/18 , C08J2323/08 , C08L23/0815 , C08F2500/03
摘要： Polymers, and systems and methods for making and using the same are described herein. A polymer includes ethylene and at least one alpha olefin having from 4 to 20 carbon atoms. The polymer has a melt index ratio (MIR) greater than about 40. The polymer also has a value for Mw1/Mw2 of at least about 2.0, wherein Mw1/Mw2 is a ratio of a weight average molecular weight (Mw) for a first half of a temperature rising elution (TREF) curve from a cross-fractionation (CFC) analysis to an Mw for a second half of the TREF curve. The polymer also has a value for Tw1−Tw2 of less than about −15° C., wherein Tw1−Tw2 is a difference of a weight average elution temperature (Tw) for the first half of the TREF curve to a Tw for the second half of the TREF curve.
摘要翻译： 催化剂系统及其制造和使用方法。 聚合烯烃以制备具有多峰组成分布的聚烯烃聚合物的方法包括使乙烯和共聚单体与催化剂体系接触。 催化剂体系包括第一催化剂化合物和第二催化剂化合物，其共同负载以形成通常负载的催化剂体系。 第一催化剂化合物包括具有通式（C5HaR1b）（C5HcR2d）HfX2的化合物。 第二催化剂化合物包括以下通式中的至少一种：在两种催化剂体系中，R基团可以独立地选自任意数量的取代基，包括例如H，烃基，取代的烃基或 杂原子基团等。
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公开(公告)号：EP1781713A2
公开(公告)日：2007-05-09
申请号：EP05764488.2
申请日：2005-07-19
发明人： LI, Dongming , LUE, Ching-Tai
CPC分类号： C08F8/00 , B29B9/06 , B29B9/12 , B29C47/0004 , B29C47/0023 , B29C47/1072 , B29K2023/06 , B29K2105/256 , C08F10/02
摘要： Methods of tailoring polyethylenes are contemplated utilizing 0.5 to 70 volume percent oxygen containing gases. The tailoring occurs in a melt-conveying zone of a mixer/extruder, and not in the feed or melting zones of a mixer/extruder. The effect of tailoring is to decrease the haze and/or increase the gloss of blown films made from the tailored polyethylenes compared to similar polyethylenes that are extruded/mixed in the substantial absence of oxygen or oxygen containing gases.
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公开(公告)号：EP3105257B1
公开(公告)日：2020-10-21
申请号：EP15705878.5
申请日：2015-02-10
发明人： LUE, Ching-Tai , RIX, Francis C. , BOLLER, Timothy M. , GIESBRECHT, Garth R. , GOODE, Mark G. , KAO, Sun-Chueh , LI, Dongming , PEQUENO, R. Eric , ZILKER, JR. Daniel P.
IPC分类号： C08F2/34 , C08F210/02 , C08F210/16 , C08F4/6592 , C08J5/18
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6.发明公开METHODS FOR MAKING POLYOLEFIN PRODUCTS HAVING DIFFERENT SHEAR THINNING PROPERTIES AND HAZE 审中-公开用于生产聚烯烃具有不同的剪切稀化特性和HAZE
公开(公告)号：EP2470573A1
公开(公告)日：2012-07-04
申请号：EP10784378.1
申请日：2010-11-16
IPC分类号： C08F10/00 , C08F4/6592
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65916 , C08F210/16 , C08F2400/02 , C08F4/65927 , C08F2/00 , C08F210/14 , C08F2500/12 , C08F2500/26
摘要： Provided is a method for making a polyolefin comprising contacting one or more olefins in a reactor containing a catalyst; polymerizing the one or more olefins to produce an olefin polymer characterized by a first melt flow ratio (MFR) and a first haze; and altering the reaction temperature in the reactor to shift the first MFR to a MFR that is different than the first MFR and to shift the first haze to a haze that is different than the first haze.
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公开(公告)号：EP1097175B1
公开(公告)日：2007-02-28
申请号：EP99935486.3
申请日：1999-07-09
IPC分类号： C08F4/602 , C08F210/16
CPC分类号： C08F210/16 , C08F4/65925 , C08F4/65927 , C08F10/00 , Y10S526/901 , Y10S526/943 , C08F4/65916 , C08F4/025 , C08F4/65912 , C08F210/14 , C08F2500/12 , C08F2500/03 , C08F4/642
摘要： This invention is directed to a process for the preparation of polyolefins from one or more olefinic monomers comprising combining said olefins under olefin polymerization conditions with an organometallic catalyst compound that is activated for olefin polymerization by reaction with at least one Lewis acid aluminum compound of the formula RnAl(ArHal)3-n, where 'ArHal' is a halogenated aryl group, n=1 or 2, and R is a monoanionic group other than a halogenated aryl group. The invention also relates to a polymer produced using the process and to the polymer itself.
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公开(公告)号：EP1189951A1
公开(公告)日：2002-03-27
申请号：EP00922250.6
申请日：2000-04-14
CPC分类号： C07F17/00 , B01J31/1608 , B01J31/2295 , B01J2531/0288 , B01J2531/48 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F210/16 , Y10S526/901 , Y10S526/943 , C08F4/65927 , C08F210/14 , C08F2500/12 , C08F2500/18 , C08F2500/10
摘要： The present invention relates to a process for polymerizing olefi(s) utilizing a cyclic bridged metallocene-type catalyst system to produce enhanced processability polymers.
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公开(公告)号：EP1097175A1
公开(公告)日：2001-05-09
申请号：EP99935486.3
申请日：1999-07-09
IPC分类号： C08F4/602 , C08F210/16
CPC分类号： C08F210/16 , C08F4/65925 , C08F4/65927 , C08F10/00 , Y10S526/901 , Y10S526/943 , C08F4/65916 , C08F4/025 , C08F4/65912 , C08F210/14 , C08F2500/12 , C08F2500/03 , C08F4/642
摘要： This invention is directed to a process for the preparation of polyolefins from one or more olefinic monomers comprising combining said olefins under olefin polymerization conditions with an organometallic catalyst compound that is activated for olefin polymerization by reaction with at least one Lewis acid aluminum compound of the formula RnAl(ArHal)3-n, where 'ArHal' is a halogenated aryl group, n=1 or 2, and R is a monoanionic group other than a halogenated aryl group. The invention also relates to a polymer produced using the process and to the polymer itself.
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公开(公告)号：EP3805278A1
公开(公告)日：2021-04-14
申请号：EP20209922.2
申请日：2015-02-10
IPC分类号： C08F210/16 , C08F4/6592
摘要： Catalyst systems and methods for making and using the same. A method of polymerizing olefins to produce a polyolefin polymer with a multimodal composition distribution, includes contacting ethylene and a comonomer with a catalyst system. The catalyst system includes a first catalyst compound and a second catalyst compound that are co-supported to form a commonly supported catalyst system. The first catalyst compound includes a compound with the general formula (C 5 H a R 1 b )(C 5 H c R 2 d )HfX 2 . The second catalyst compound comprises the following formula:
wherein each R 3 or R 4 is independently H, a hydrocarbyl group, a substituted hydrocarbyl group, or a heteroatom group, wherein each R 3 or R 4 may be the same or different, and each X is independently a leaving group selected from a labile hydrocarbyl, a substituted hydrocarbyl, a heteroatom group, or a divalent radical that links to an R 3 group.
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