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1.发明授权PROCESS AND APPARATUS FOR SIZE SELECTIVE SEPARATION OF MICRO- AND NANO-PARTICLES 有权方法和设备的微型和纳米粒子的GRÖSSSENABHÄNGIGEN分离
公开(公告)号：EP1133345B1
公开(公告)日：2010-06-16
申请号：EP99945612.2
申请日：1999-09-09
CPC分类号： B01D11/0407 , B01D11/0403 , B01D11/0415 , B01D61/14 , C30B7/00 , C30B29/605
摘要： Processes and apparatuses are provided for continuously harvesting particles from organic solution-laden near-critical and supercritical fluids. Broadly, the processes and apparatuses utilize a filter or separator comprising a thin membrane supported on a sintered stainless steel tube. A feed stream comprising the desired particles, a supercritical antisolvent for the particles (preferably CO2), and a solvent for the particles, is contacted with the membrane layer of the filter under supercritical conditions for the mixture of antisolvent and solvent. The preferred antisolvents are substantially miscible with the solvent and have a critical temperature of less than 160 DEG C. The desired particles are retained by the filter while the solvent and most of the antisolvent pass through the filter, resulting in separation of the particles from the solvent.
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2.发明公开IMPROVED SOLID ACID SUPERCRITICAL ALKYLATION REACTIONS USING CARBON DIOXIDE AND/OR OTHER CO-SOLVENTS 失效固体酸超临界烷基化反应使用二氧化碳和/或救济资金解决方案
公开(公告)号：EP0994832A1
公开(公告)日：2000-04-26
申请号：EP98926289.4
申请日：1998-06-04
CPC分类号： C07C2/58 , B01J3/008 , C07C2521/06 , C07C2529/06 , Y02P20/544
摘要： Improved isoparaffin-olefin alkylation solid catalyst processes are provided which are characterized by low coke laydown and catalyst deactivation rates and production of valuable branched chain, high octane number alkylates. The processes of the invention involve providing a starting reactant mixture comprising an isoparaffin, an olefin and a co-solvent or diluent (carbon dioxide in molar excess, methane, hydrogen or mixtures thereof), and contacting the reactant mixture with an alkylation catalyst at near-critical or preferably supercritical conditions for the reaction mixture. The carbon dioxide serves as a co-solvent and reduces the critical temperature (Tc) of the reaction mixture, thereby allowing lower reaction temperatures. The isoparaffin and olefin reactants are preferably pretreated to minimize moisture, peroxide and oxygenate impurities therein.
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公开(公告)号：EP1943237B1
公开(公告)日：2015-06-17
申请号：EP06826630.3
申请日：2006-10-25
申请人： University Of Kansas
IPC分类号： C07D301/12
CPC分类号： C07D301/12 , Y02P20/582
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4.发明授权CATALYTIC OXIDATION OF ORGANIC SUBSTRATES BY TRANSITION METAL COMPLEXES IN ORGANIC SOLVENT MEDIA EXPANDED BY SUPERCRITICAL OR SUBCRITICAL CARBON DIOXIDE 有权有机底使用有机溶剂，用超或亚临界二氧化碳的过渡金属络合物催化氧化正在扩大
公开(公告)号：EP1268383B1
公开(公告)日：2009-07-29
申请号：EP01928364.7
申请日：2001-04-03
IPC分类号： C07C45/00 , C07C49/105 , C07C41/00 , C07C37/00 , C07C27/00 , C07C29/03 , C07C67/00 , C07B41/04 , C07B41/02 , C08F2/46
CPC分类号： C07D303/04 , C07B41/00 , C07C27/12 , C07C29/50 , C07C45/34 , C07C46/08 , C07C2601/14 , C07C2601/16 , C07D301/06 , Y02P20/544 , C07C49/713 , C07C49/603 , C07C35/14 , C07C35/18
摘要： Improved oxidation methods are provided wherein a reaction mixture comprising a substrate to be oxidized (e.g., phenols, alkenes) and an oxidation catalyst (typically dispersed in an organic solvent system) is supplemented with a compressed gas which expands the reaction mixture, thus accelerating the oxidation reaction. In preferred practice pressurized subcritical or supercritical carbon dioxide is used as the expanding gas, which is introduced into the reaction mixture together with an oxidizing agent. The inventive methods improve the substrate conversion and product selectivity by increasing the solubility of the oxidizing agent in the reaction mixture.
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公开(公告)号：EP2411357B1
公开(公告)日：2018-04-25
申请号：EP10756727.3
申请日：2010-03-23
申请人： University of Kansas
IPC分类号： C07C51/255 , C07C51/265 , C07C63/00 , B01J19/26 , B01J8/00 , B01J10/00 , B01J4/00
CPC分类号： C07C51/255 , B01J4/002 , B01J10/007 , B01J2219/00006 , B01J2219/00063 , B01J2219/00065 , B01J2219/00162 , C07C51/265 , C07C63/00
摘要： Oxidation process can include: introducing small droplets of liquid reaction mixture having oxidizable reactant, catalyst, and solvent into a reaction zone containing oxygen and diluent gas; and oxidizing the reactant with the oxygen at a suitable reaction temperature and a suitable reaction pressure to produce an oxidized product. The liquid reaction mixture can have an aromatic feedstock having an oxidizable substituent as the oxidizable reactant. The oxidized product can include an aromatic compound having at least one carboxylic acid. For example, the aromatic feedstock can include a benzene ring having at least one oxidizable alkyl substituent, furan hetero-ring having at least one oxidizable alkyl substituent, a naphthalene poly-ring having at least one oxidizable alkyl substituent, derivatives thereof, and mixtures thereof.
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公开(公告)号：EP2681180B1
公开(公告)日：2017-08-23
申请号：EP12755652.0
申请日：2012-02-14
CPC分类号： C07C45/505 , B01J19/24 , B01J31/1683 , B01J31/2404 , B01J31/4046 , B01J31/4053 , B01J31/4061 , B01J2231/321 , B01J2531/822 , C07C45/50 , C07C47/02 , Y02P20/584 , C07C47/19
摘要： Allyl alcohol, particularly from biobased sources such as glycerol, is hydroformylated to products including 4-hydroxybutyraldehyde and 4-hydroxy-2-methylpropionaldehyde by forming a homogeneous reaction mixture including allyl alcohol, a rhodium-based hydroformylation catalyst and a near critical liquefiable petroleum gas or mixture of such gases, reacting the near critical liquefiable petroleum gas (or gas mixture)-expanded allyl alcohol substrate with carbon monoxide and with hydrogen in the presence of the catalyst, and recovering substantially all of the petroleum gas or gases overhead by reducing the pressure and degassing the product mixture. Dense propane is especially useful as a single inert solvent/diluent, and substantially no other solvent/diluent is needed.
摘要翻译： 通过形成包括烯丙醇，铑基加氢甲酰化催化剂和近临界可液化石油气的均相反应混合物，将烯丙醇，特别是来自生物基源如甘油的烯丙醇加氢甲酰化成包括4-羟基丁醛和4-羟基-2-甲基丙醛的产物 或这些气体的混合物，在催化剂存在下使近临界可液化石油气（或气体混合物）膨胀的烯丙醇基质与一氧化碳和氢反应，并通过还原基本上回收所有石油气或多种气体 压力和产物混合物脱气。 致密丙烷作为单一的惰性溶剂/稀释剂特别有用，并且基本不需要其他溶剂/稀释剂。
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7.发明公开SINGLE SOLVENT GAS EXPANDED HYDROFORMYLATION PROCESS 有权EIN-LÖSUNGSMITTELGASEXPANSIONS-HYDROFORMYLIERUNGSVERFAHREN
公开(公告)号：EP2681180A2
公开(公告)日：2014-01-08
申请号：EP12755652.0
申请日：2012-02-14
CPC分类号： C07C45/505 , B01J19/24 , B01J31/1683 , B01J31/2404 , B01J31/4046 , B01J31/4053 , B01J31/4061 , B01J2231/321 , B01J2531/822 , C07C45/50 , C07C47/02 , Y02P20/584 , C07C47/19
摘要： Allyl alcohol, particularly from biobased sources such as glycerol, is hydroformylated to products including 4-hydroxybutyraldehyde and 4-hydroxy-2-methylpropionaldehyde by forming a homogeneous reaction mixture including allyl alcohol, a rhodium-based hydroformylation catalyst and a near critical liquefiable petroleum gas or mixture of such gases, reacting the near critical liquefiable petroleum gas (or gas mixture)-expanded allyl alcohol substrate with carbon monoxide and with hydrogen in the presence of the catalyst, and recovering substantially all of the petroleum gas or gases overhead by reducing the pressure and degassing the product mixture. Dense propane is especially useful as a single inert solvent/diluent, and substantially no other solvent/diluent is needed.
摘要翻译： 烯丙醇，特别是生物碱源如甘油，通过形成包括烯丙醇，基于铑的加氢甲酰化催化剂和近临界液化石油气的均匀反应混合物，加氢甲酰化成包括4-羟基丁醛和4-羟基-2-甲基丙醛的产物 或这种气体的混合物，在催化剂存在下使近临界液化石油气（或气体混合物） - 膨胀的烯丙醇底物与一氧化碳和氢气反应，并通过减少基本上所有的石油气或天然气来回收 压力和脱气产物混合物。 浓缩丙烷作为单一惰性溶剂/稀释剂是特别有用的，并且基本上不需要其它溶剂/稀释剂。
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8.发明授权METHODS AND APPARATUS FOR PARTICLE PRECIPITATION AND COATING USING NEAR-CRITICAL AND SUPERCRITICAL ANTISOLVENTS 失效FOR TEILCHENAUSFALLUNG方法和装置和使关键或有关主要ANTI-SOLUTION基金涂料快速
公开(公告)号：EP0885038B1
公开(公告)日：2011-06-15
申请号：EP97914827.7
申请日：1997-02-28
CPC分类号： B05D1/025 , A61K9/1676 , A61K9/1688 , A61K9/1694 , A61K9/5089 , B01J2/04 , B05D2401/90
摘要： Improved method and apparatus (110) for particle precipitation and coating using near- or supercritical fluid conditions. A fluid dispersion (128) having a continuous phase dispersant and at least one precipitable substance therein is contacted with a supercritical fluid (SCF) antisolvent (126) so as to generate focused high frequency antisolvent sonic waves, breaking up the dispersion into extremely small droplets. The enhanced mass transfer rates between the droplets and the antisolvent causes precipitation of very small particles on the order of 0.1-10 microns. In coating processes, a turbulent fluidized flow of core particles is created using SCF antisolvent in an enclosed zone. The core particles are contacted therein at or near supercritical conditions by fluid dispersion containing a dispersant and together with a precipitable substance. The antisolvent depletes the dispersant and the substance is precipitated onto fluidized particles.
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9.发明公开TUNING PRODUCT SELECTIVITY IN CATALYTIC HYROFORMYLATION REACTIONS WITH CARBON DIOXIDE EXPANDED LIQUIDS 审中-公开调谐元件对特殊反应的催化HYDRO配方与扩展液态二氧化碳
公开(公告)号：EP2001829A2
公开(公告)日：2008-12-17
申请号：EP07758707.9
申请日：2007-03-16
申请人： UNIVERSITY OF KANSAS
发明人： SUBRAMANIAM, Bala , TUNGE, Jon, A. , JIN, Hong , GHOSH, Anindya
IPC分类号： C07C47/00
CPC分类号： C07C45/50 , Y02P20/544 , C07C47/02
摘要： An improved hydroformylation process is provided, which comprises reacting an olefin with CO and H2 in the presence of a hydroformylation catalyst in a liquid that has been volumetrically expanded with a compressed gas, such as supercritical carbon dioxide.
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10.发明公开PROCESS AND APPARATUS FOR SIZE SELECTIVE SEPARATION OF MICRO- AND NANO-PARTICLES 有权方法和设备的微型和纳米粒子的GRÖSSSENABHÄNGIGEN分离
公开(公告)号：EP1133345A1
公开(公告)日：2001-09-19
申请号：EP99945612.2
申请日：1999-09-09
IPC分类号： B01D61/00
CPC分类号： B01D11/0407 , B01D11/0403 , B01D11/0415 , B01D61/14 , C30B7/00 , C30B29/605
摘要： Processes and apparatuses are provided for continuously harvesting particles from organic solution-laden near-critical and supercritical fluids. Broadly, the processes and apparatuses utilize a filter or separator comprising a thin membrane supported on a sintered stainless steel tube. A feed stream comprising the desired particles, a supercritical antisolvent for the particles (preferably CO2), and a solvent for the particles, is contacted with the membrane layer of the filter under supercritical conditions for the mixture of antisolvent and solvent. The preferred antisolvents are substantially miscible with the solvent and have a critical temperature of less than 160 DEG C. The desired particles are retained by the filter while the solvent and most of the antisolvent pass through the filter, resulting in separation of the particles from the solvent.
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