摘要:
The invention is directed to an SVO electrochemical cell having high rate capability. The cathode is produced by coating a mixture of an active material, conductive additives, a mixed binder, and an aluminum foil current collector. The mixed binder consists of a mixture of heat treated polyamic acid with PVDF. The use of heat treated polyamic acid maintains adhesion to the conductive current collector while the PVDF portion of the binder gives flexibility. A particularly preferred couple is of a lithium/silver vanadium oxide (Li/SVO) chemistry and the binder mixture enables an active slurry of SVO to be coated onto a current collector without delamination.
摘要:
A mixture of polymeric binders that is insoluble in nonaqueous organic electrolytes activating alkali metal or alkali metal ion electrochemical cells, is described. The mixed binder formulation provides electrodes that are flexible and non-brittle, and cells incorporating the electrodes are dischargeable at elevated temperatures. The binder formulation is a mixture of halogenated polymeric material, preferably PVDF, and a polyimide which is a product of the conversion of polyamic acid.
摘要:
The invention is directed to an SVO electrochemical cell having high rate capability. The cathode is produced by coating a mixture of an active material, conductive additives, a mixed binder, and an aluminum foil current collector. The mixed binder consists of a mixture of heat treated polyamic acid with PVDF. The use of heat treated polyamic acid maintains adhesion to the conductive current collector while the PVDF portion of the binder gives flexibility. A particularly preferred couple is of a lithium/silver vanadium oxide (Li/SVO) chemistry and the binder mixture enables an active slurry of SVO to be coated onto a current collector without delamination.
摘要:
The current invention relates to the preparation of an improved cathode active material for non-aqueous lithium electrochemical cell. In particular, the cathode active material comprises ε-phase silver vanadium oxide prepared by using a γ-phase silver vanadium oxide starting material. The reaction of γ-phase SVO with a silver salt produces the novel ε-phase SVO possessing a lower surface area than ε-phase SVO produced from vanadium oxide (V 2 O 5 ) and a similar silver salt as starting materials. Consequently, the low surface area ε-phase SVO material provides an advantage in greater long term stability in pulse dischargeable cells.
摘要:
The present invention relates to an improved method of synthesizing unsymmetric linear organic carbonates of the formula R 1 OCOOR 2 comprising the reaction of two symmetric dialkyl carbonates, R 1 OCOOR 1 and R 2 OCOOR 2 , in the presence of a nucleophilic reagent or an election donating reductant as a catalyst, wherein R 1 and R 2 can be either saturated or unsaturated alkyl or aryl groups, is described. The presence invention further provides a preparation method for a nonaqueous organic electrolyte having an unsymmetric linear organic carbonate as a co-solvent.
摘要:
A mixture of polymeric binders that is insoluble in nonaqueous organic electrolytes activating alkali metal or alkali metal ion electrochemical cells, is described. The mixed binder formulation provides electrodes that are flexible and non-brittle, and cells incorporating the electrodes are dischargeable at elevated temperatures. The binder formulation is a mixture of halogenated polymeric material, preferably PVDF, and a polyimide which is a product of the conversion of polyamic acid.
摘要:
The current invention relates to the preparation of an improved cathode active material for non-aqueous lithium electrochemical cell. In particular, the cathode active material comprises ε-phase silver vanadium oxide prepared by using a γ-phase silver vanadium oxide starting material. The reaction of γ-phase SVO with a silver salt produces the novel ε-phase SVO possessing a lower surface area than ε-phase SVO produced from vanadium oxide (V 2 O 5 ) and a similar silver salt as starting materials. Consequently, the low surface area ε-phase SVO material provides an advantage in greater long term stability in pulse dischargeable cells.