摘要:
The present invention is directed to provide an efficient production method which is capable of not only obtaining a cyclic sulfonic acid ester (sultone) at low cost and in high yield, but also the sulfonic acid ester (sultone) stably even in a commercial scale. The present invention relates to a method for producing hydroxysultone comprising a first step where a diol having a specified structure and a thionyl halide are reacted to obtain a cyclic sulfite having a specified structure, and a second step where the cyclic sulfite is reacted with water or/and alcohol; a method for producing an unsaturated sultone having a specified structure comprising a third step where a hydroxylsultone having a specified structure is reacted with an acid halide or an acid anhydride to obtain an intermediate, subsequently the intermediate is treated with a base; as well as a cyclic sulfite having a specified structure.
摘要:
Object To provide a method for producing a bis-quaternary ammonium salt efficiently and a novel synthetic intermediate thereof. Solution The present invention relates to a method for producing a bis-quaternary ammonium salt represented by a general formula [3] which comprises reacting a disulfonic acid ester represented by a general formula [1] (in the formula, definitions of two R 1 's and T are as described in Claim 1) with a tertiary amine represented by a general formula [2] (in the formula, definitions of R 3 to R 5 are as described in Claim 1), and a novel disulfonic acid ester represented by a general formula [1'] (in the formula, two R 16 's represent independently a halogen atom or a C1-C3 fluoroalkyl group, and two m's represent independently an integer of 1 to 5) as an additive for an electrolyte for a lithium secondary battery.
摘要翻译:目的是提供一种高效地制造以季铵盐提供一种方法和它们的新的合成中间体。 方案本发明涉及一种制造方法,以季铵盐由通式[3]该方法包括使由通式[1](式中,两个R的定义1'代表一个二磺酸酯 s和t与由通式表示的叔胺,如权利要求1中所述)[2](式中,以R 5 R 3的定义如权利要求1中所述),和一种新型的二磺酸酯由代表 通式[1'](式中,两个R 16的独立地表示卤素原子或C1-C3氟烷基,和两个M的独立地表示从1到5的整数),作为对在电解液添加剂用于为 锂二次电池。
摘要:
A triphenyl sulfonium salt compound shown by the general formula [1] or [3]. (wherein R 1 and R 2 are each independently a hydrogen atom or a lower alkyl group, provided that at least one of R 1 and R 2 are a lower alkyl group, R 3 s are each independently an alkyl group, n is an integer of 0 to 3, i is an integer of 1 to 3, j is an integer of 0 to 2, provided that i+j=3, Y - is an anion derived from a sulfonic acid shown by the general formula [2]
R 4 ―SO 3 H [2]
[wherein R 4 is an alkyl group or an aryl group which may have as a substituent an alkyl group]). (wherein X is a phenyl group which has a substituent at an ortho- and/or a meta-position, m is an integer of 1 to 3, q is an integer of 0 to 2, provided that m+q=3, p is 1 or 2 and Z p- is an anion derived from a carboxylic acid).
摘要:
A resist composition comprising an alkalisoluble polymer, a special cross-linking agent containing one or more oxirane rings and at least one of -0-, -CO-, -COO- and -OCO- groups in the molecule, a photoacid generator, and a solvent can form a film having high transmittance for deep UV light such as ArF excimer laser beams and high etching resistance as well as high resolution, and thus suitable for forming a negative working pattern.
摘要:
Object To provide a method for producing a bis-quaternary ammonium salt efficiently and a novel synthetic intermediate thereof. Solution The present invention relates to a method for producing a bis-quaternary ammonium salt represented by a general formula [3] which comprises reacting a disulfonic acid ester represented by a general formula [1] (in the formula, definitions of two R 1 's and T are as described in Claim 1) with a tertiary amine represented by a general formula [2] (in the formula, definitions of R 3 to R 5 are as described in Claim 1), and a novel disulfonic acid ester represented by a general formula [1'] (in the formula, two R 16 's represent independently a halogen atom or a C1-C3 fluoroalkyl group, and two m's represent independently an integer of 1 to 5) as an additive for an electrolyte for a lithium secondary battery.
摘要翻译:目的是提供一种高效地制造以季铵盐提供一种方法和它们的新的合成中间体。 方案本发明涉及一种制造方法,以季铵盐由通式[3]该方法包括使由通式[1](式中,两个R的定义1'代表一个二磺酸酯 s和t与由通式表示的叔胺,如权利要求1中所述)[2](式中,以R 5 R 3的定义如权利要求1中所述),和二磺酸酯由A代表 通式[1'](式中,两个R 16的独立地表示卤素原子或C1-C3氟烷基,m的表示两个独立地在1整数〜5)。
摘要:
A compound shown by the general formula [3] (wherein X is a phenyl group which has a substituent at an ortho- and/or a meta-position, m is an integer of 1 to 3, q is an integer of 0 to 2, provided that m+q=3, p is 1 or 2 and Z p- is an anion derived from a carboxylic acid).
摘要:
To provide a polymer comprising as a structural unit a monomer unit containing a hydroxy group or other hydrophilic radical and other functional group in the molecule which is useful in medical, cosmetic and electric industries. A polymer comprising as a structural unit a monomer unit shown by the general formfula [1] (wherein R 1 and R 2 are, independently, a hydrogen atom or a halogen atom, R 3 is a hydrophilic radical and R 4 is a cyano group or a carboxyl group which may be esterified).
摘要翻译:提供一种包含作为结构单元的聚合物,其在分子中含有羟基或其它亲水基团和其它官能团的单体单元,其可用于医疗,化妆品和电力工业。 包含作为结构单元的聚合物是由通式(1)表示的单体单元(其中R 1和R 2独立地是氢原子或卤素原子,R 3是亲水基团 R 4为可被酯化的氰基或羧基)。
摘要:
A compound shown by the general formula [3] (wherein X is a phenyl group which has a substituent at an ortho- and/or a meta-position, m is an integer of 1 to 3, q is an integer of 0 to 2, provided that m+q=3, p is 1 or 2 and Z p- is an anion derived from a carboxylic acid).