VERFAHREN ZUR HERSTELLUNG VON POLYESTERN

    公开(公告)号:EP1799746A1

    公开(公告)日:2007-06-27

    申请号:EP05756506.1

    申请日:2005-06-18

    IPC分类号: C08G63/81 C08G63/181

    CPC分类号: C08G63/81 C08G63/181

    摘要: The invention relates to a method for producing polyesters of aromatic dicarboxylic acids with aliphatic and/or cycloaliphatic diols, during which an aromatic dicarboxylic acid present in a saturated solution is, in the presence of a monocarboxylic acid or of a mixture of a monocarboxylic acid with water or in another suitable solvent, reacted with an aliphatic or cycloaliphatic diol to form a dicarboxylic acid alkane diolester carboxylate and/or oligomers thereof, which can be polycondensed in additional method steps to form polyester.

    摘要翻译: 本发明涉及一种用脂族和/或脂环族二醇生产芳族二羧酸聚酯的方法,在该方法中,在一元羧酸或一元羧酸与 水或在另一合适的溶剂中,与脂族或脂环族二醇反应以形成二羧酸烷二酯羧酸酯和/或其低聚物,其可在另外的方法步骤中缩聚以形成聚酯。

    VERFAHREN UND VORRICHTUNG ZUR HERSTELLUNG VON POLYESTERN UND COPOLYESTERN
    6.
    发明公开
    VERFAHREN UND VORRICHTUNG ZUR HERSTELLUNG VON POLYESTERN UND COPOLYESTERN 审中-公开
    方法和设备用于生产聚酯和共聚酯

    公开(公告)号:EP1720928A1

    公开(公告)日:2006-11-15

    申请号:EP04803840.0

    申请日:2004-12-14

    IPC分类号: C08G63/78 B01D5/00

    摘要: Disclosed is a method for producing polyesters by means of esterification or re-esterification, precondensation of the esterified/re-esterified product, and polycondensation of the precondensed product at a pressure of 0.2 to 500 mbar and a temperature of 230 to 330 °C. According to said method, the vapors formed during precondensation and polycondensation are condensed and the obtained cooled diol is redirected into the condensation stage. In order to improve the degree of separation, the vapors are directed into a bottomless direct contact condenser, the base of which is immersed into the top funnel-shaped section of a barometrically dipped downpipe so as to form an annular space, cooled diol is sprayed into the vapors in the top section of the direct contact condenser, the remaining vapors are recovered via the annular space, and the formed polymer aggregates are removed.