VERFAHREN ZUM NACHWEIS VON STRAHLUNG
    1.
    发明公开
    VERFAHREN ZUM NACHWEIS VON STRAHLUNG 审中-公开
    法辐射检测

    公开(公告)号:EP3011364A1

    公开(公告)日:2016-04-27

    申请号:EP14731267.2

    申请日:2014-06-18

    摘要: The invention relates to a method for optical detection of radiation, comprising the provision of a first component for converting radiation having an energy in the range greater than 10
    3 eV into radiation having an energy in the range from 0.5 eV to 20 eV, and a second component for absorbing radiation having an energy in the range from 0.5 eV to 20 eV, wherein the second component emits detectable light due to the absorption. Thus it is firstly possible to detect radioactive radiation in a spatially resolved manner, and secondly, depending on the corresponding measuring structure, to obtain information on the type of radiation by means of a statistical evaluation or by layer thicknesses or different layer arrangements.

    ZWEIKERNIGE METALL(I)-KOMPLEXE MIT TETRADENTATEN LIGANDEN FÜR OPTOELEKTRONISCHE ANWENDUNGEN
    10.
    发明公开
    ZWEIKERNIGE METALL(I)-KOMPLEXE MIT TETRADENTATEN LIGANDEN FÜR OPTOELEKTRONISCHE ANWENDUNGEN 审中-公开
    ZWEIKERNIGE METALL(I)-KOMPLEXE MIT TETRADENTATEN LIGANDENFÜROPTOELEKTRONISCHE ANWENDUNGEN

    公开(公告)号:EP3160974A1

    公开(公告)日:2017-05-03

    申请号:EP15732632.3

    申请日:2015-06-25

    申请人: cynora GmbH

    摘要: The invention relates to metal(I) complexes of the formula A and to the use thereof in optoelectronic components, especially in OLEDs, with M = independently selected from the group consisting of Cu and Ag; X = independently selected from the group consisting of Cl, Br, I, CN, OCN, SCN, alkynyl, thiolate and N
    3 ; L = a tetradentate ligand composed of two identical or different subunits EHD joined via a spacer unit S'' and optionally S', with E = RE* (when E*= N, P, As, Sb) or E* (when E* = C*, O, S) with E* independently selected from the group consisting of N, where N is not an imine nitrogen atom or part of an N-heteroaromatic ring, P, C*, O, S, As and Sb with C*= a divalent carbene carbon atom and R = independently selected from the group consisting of hydrogen, halogen and substituents bonded directly or via oxygen atoms (-OR), nitrogen atoms (-NR
    2 ), silicon atoms (-SiR
    3 ) or sulfur atoms (-SR), and alkyl, heteroalkyl, aryl, heteroaryl, alkenyl and alkynyl groups or substituted alkyl, heteroalkyl, aryl, heteroaryl and alkenyl groups (with substituents such as halogens or deuterium, alkyl groups, heteroalkyl groups, aryl groups, heteroaryl groups); D = RD* (when D* = N, P, As, Sb) or D* (when D* = C*, O, S) with D* independently selected from the group consisting of N, where N is not an imine nitrogen atom or part of an N-heteroaromatic ring, P, C*, O, S, As and Sb with C*= a divalent carbene carbon atom and R = independently selected from the group consisting of hydrogen, halogen and substituents bonded directly or via oxygen atoms (-OR), nitrogen atoms (-NR
    2 ), silicon atoms (-SiR
    3 ) or sulfur atoms (-SR), and alkyl, heteroalkyl, aryl, heteroaryl, alkenyl and alkynyl groups or substituted alkyl, heteroalkyl, aryl, heteroaryl and alkenyl groups; where D and E are different from one another.

    摘要翻译: 本发明涉及式A的金属(I)络合物及其在光电子器件中,特别是在OLED中的用途,其中M =独立地选自Cu和Ag; X =独立地选自Cl,Br,I,CN,OCN,SCN,炔基,硫醇盐和N 3; L =通过间隔单元S“和任选的S'与E = RE *(当E * = N,P,As,Sb时)或E *(当E *,其中E *独立地选自N,其中N不是亚胺氮原子或部分N-杂芳环,P,C *,O,S,As和Sb 其中C * =二价卡宾碳原子且R =独立地选自氢,卤素和直接或经由氧原子(-OR),氮原子(-NR 2),硅原子(-SiR 3)或硫原子键合的取代基 (-SR)和烷基,杂烷基,芳基,杂芳基,烯基和炔基或取代的烷基,杂烷基,芳基,杂芳基和烯基(具有取代基如卤素或氘,烷基,杂烷基,芳基, 基团); 当D *独立地选自N,其中N不是亚胺时,D = RD *(当D * = N,P,As,Sb时)或D *(当D * = C *,O,S时) 氮原子或N-杂芳环的一部分,P,C *,O,S,As和Sb,其中C * =二价卡宾碳原子且R =独立地选自氢,卤素和直接键合的取代基或 (-OR),氮原子(-NR 2),硅原子(-SiR 3)或硫原子(-SR)以及烷基,杂烷基,芳基,杂芳基,烯基和炔基或取代的烷基,杂烷基,芳基, 杂芳基和烯基; D和E彼此不同。