摘要:
The invention relates to a method for optical detection of radiation, comprising the provision of a first component for converting radiation having an energy in the range greater than 10 3 eV into radiation having an energy in the range from 0.5 eV to 20 eV, and a second component for absorbing radiation having an energy in the range from 0.5 eV to 20 eV, wherein the second component emits detectable light due to the absorption. Thus it is firstly possible to detect radioactive radiation in a spatially resolved manner, and secondly, depending on the corresponding measuring structure, to obtain information on the type of radiation by means of a statistical evaluation or by layer thicknesses or different layer arrangements.
摘要:
The invention relates to a process for producing a cross-linked organic transition metal complex in a multi-dimensional network, comprising the step of carrying out a first reaction, which involves a first reactant in the form of an organic metal complex and a second reactant in order to form a multi-dimensional network, the metal complex being cross-linked during the reaction in the forming multi-dimensional network.
摘要:
The invention relates to metal(I) complexes of the formula A and to the use thereof in optoelectronic components, especially in OLEDs, with M = independently selected from the group consisting of Cu and Ag; X = independently selected from the group consisting of Cl, Br, I, CN, OCN, SCN, alkynyl, thiolate and N 3 ; L = a tetradentate ligand composed of two identical or different subunits EHD joined via a spacer unit S'' and optionally S', with E = RE* (when E*= N, P, As, Sb) or E* (when E* = C*, O, S) with E* independently selected from the group consisting of N, where N is not an imine nitrogen atom or part of an N-heteroaromatic ring, P, C*, O, S, As and Sb with C*= a divalent carbene carbon atom and R = independently selected from the group consisting of hydrogen, halogen and substituents bonded directly or via oxygen atoms (-OR), nitrogen atoms (-NR 2 ), silicon atoms (-SiR 3 ) or sulfur atoms (-SR), and alkyl, heteroalkyl, aryl, heteroaryl, alkenyl and alkynyl groups or substituted alkyl, heteroalkyl, aryl, heteroaryl and alkenyl groups (with substituents such as halogens or deuterium, alkyl groups, heteroalkyl groups, aryl groups, heteroaryl groups); D = RD* (when D* = N, P, As, Sb) or D* (when D* = C*, O, S) with D* independently selected from the group consisting of N, where N is not an imine nitrogen atom or part of an N-heteroaromatic ring, P, C*, O, S, As and Sb with C*= a divalent carbene carbon atom and R = independently selected from the group consisting of hydrogen, halogen and substituents bonded directly or via oxygen atoms (-OR), nitrogen atoms (-NR 2 ), silicon atoms (-SiR 3 ) or sulfur atoms (-SR), and alkyl, heteroalkyl, aryl, heteroaryl, alkenyl and alkynyl groups or substituted alkyl, heteroalkyl, aryl, heteroaryl and alkenyl groups; where D and E are different from one another.