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公开(公告)号：EP2482978B1
公开(公告)日：2018-05-09
申请号：EP10818213.0
申请日：2010-09-28
IPC分类号： B01J31/12 , C07B53/00 , C07D307/28 , C07F9/572
CPC分类号： C07F15/008 , B01J31/1658 , B01J31/1666 , B01J31/2409 , B01J2231/324 , B01J2531/0216 , B01J2531/0266 , B01J2531/822 , C07B53/00 , C07D307/28 , C07D403/10 , C07F9/5728
摘要： Novel polymeric rhodium catalysts having repeating subunits of Formula (I), wherein R1-R8, X, A, m, n and p are as defined in the application, are described along with methods of using these catalysts, as well as precursors therefor, in the chemical synthesis transformations.
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公开(公告)号：EP1313559A2
公开(公告)日：2003-05-28
申请号：EP01963854.3
申请日：2001-08-09
发明人： HOVEYDA, Amir, H. , KINGSBURY, Jason , GARBER, Steven , GRAY, Brian, Lawrence , FOURKAS, John, T.
CPC分类号： C07F15/0046 , B01J23/462 , B01J31/1625 , B01J31/1641 , B01J31/1666 , B01J31/1683 , B01J31/1805 , B01J31/2208 , B01J31/2273 , B01J31/2404 , B01J31/28 , B01J31/4038 , B01J2231/482 , B01J2231/543 , B01J2531/821 , C07B2200/11 , C07C6/02 , C07C29/00 , C07C67/293 , C07C2531/22 , C07C2601/08 , C07C2601/16 , C07D233/56 , C08F290/00 , C08G83/003 , C08L51/04 , C08L51/08 , Y02P20/584 , Y02P20/588 , C07C35/18 , C07C35/06 , C07C35/21 , C07C69/013 , C07C69/145
摘要： Hyghly active, recoverable and recyclable transition metal-based metathesis catalysts and their organometallic complexes including dendrimeric complexes are disclosed, including a Ru complex bearing a 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene and styrenyl ether ligand. The heterocyclic ligand significantly enhances the catalytic activity, and the styrenyl ether allows for the easy recovery of the Ru complex. Derivatized catalysts capable of being immobilized on substrate surfaces are also disclosed. The present catalysts can be used to catalyze ring-closing metathesis (RCM), ring-opening (ROM) and cross metatheses (CM) reactions, and promote the efficient formation of various trisubstituted olefins at ambient temperature in high yield.
摘要翻译： 公开了高活性，可回收和可回收的过渡金属基复分解催化剂及其有机金属络合物，包括树枝状复合物，包括带有1,3-二甲基-4,5-二氢咪唑-2-亚基和苯乙烯基醚配体的Ru络合物。 杂环配体显着增强了催化活性，苯乙烯醚容易回收Ru络合物。 还公开了能够固定在基材表面上的衍生化催化剂。 本催化剂可用于催化闭环复分解（RCM），开环（ROM）和交叉反应（CM）反应，促进各种三取代烯烃在环境温度下的高效率形成。
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公开(公告)号：EP2482978A4
公开(公告)日：2014-09-17
申请号：EP10818213
申请日：2010-09-28
申请人： UNIV ALBERTA
IPC分类号： B01J31/12 , C07B53/00 , C07D307/28 , C07F9/572
CPC分类号： C07F15/008 , B01J31/1658 , B01J31/1666 , B01J31/2409 , B01J2231/324 , B01J2531/0216 , B01J2531/0266 , B01J2531/822 , C07B53/00 , C07D307/28 , C07D403/10 , C07F9/5728
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4.发明公开RUTHENIUM COMPLEX LIGAND, RUTHENIUM COMPLEX, CARRIED RUTHENIUM COMPLEX CATALYST AND THE PREPARING METHODS AND THE USE THEREOF 有权钌络合物配体，钌络合物，携带的钌络合物催化剂及其制备方法及其用途
公开(公告)号：EP1905777A1
公开(公告)日：2008-04-02
申请号：EP06761350.5
申请日：2006-07-03
申请人： Zhan, Zheng-Yun
发明人： Zhan, Zheng-Yun
CPC分类号： B01J31/2265 , B01J31/068 , B01J31/1666 , B01J31/1683 , B01J31/2208 , B01J31/2273 , B01J31/2278 , B01J31/2404 , B01J31/403 , B01J2231/54 , B01J2531/821 , B01J2540/34 , B01J2540/40 , B01J2540/62 , C07C315/04 , C07C2601/10 , C07F15/0046 , Y02P20/584 , C07C317/14
摘要： The present invention disclosed a kind of ruthenium complex ligands, ruthenium complexes and immobilized ruthenium complex catalysts. The invention also relates to preparation and use of new ruthenium complex ligands, ruthenium complexes and immobilized ruthenium complex catalysts. The ruthenium complex ligand I and ruthenium complex II in the present invention have the following structures:
The immobilized ruthenium complex catalysts in the present invention have the structure of IV :
In the present invention, the ruthenium complexes and immobilized ruthenium complex catalysts have several significant advantages, e.g., high catalytic activity, high stability, easy recovery and reusability.摘要翻译： 本发明公开了一种钌配合物配体，钌配合物和固定化钌配合物催化剂。 本发明还涉及新型钌配合物配体，钌配合物和固定化钌配合物催化剂的制备和应用。 本发明中的钌配合物配体I和钌配合物II具有以下结构：本发明中的固定化钌配合物催化剂具有Ⅳ的结构：在本发明中，钌配合物和固定化的钌配合物催化剂具有几个显着的优点 如高催化活性，高稳定性，易回收性和可重复使用性。
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5.发明公开METHODS AND REAGENTS MAKING MULTIVALENT ARRAYS AND COMBINATORIAL LIBRARIES OF MULTIVALENT ARRAYS 有权生产多价结构的方法和试剂的多价结构的组合库
公开(公告)号：EP1200484A1
公开(公告)日：2002-05-02
申请号：EP00954149.1
申请日：2000-06-19
IPC分类号： C08F4/80
CPC分类号： B01J31/2265 , B01J19/0046 , B01J31/1666 , B01J2219/00497 , B01J2219/005 , B01J2219/00585 , B01J2219/00596 , B01J2219/00603 , B01J2219/00605 , B01J2219/0061 , B01J2219/00626 , B01J2219/00722 , B01J2219/00738 , B01J2231/14 , B01J2531/821 , B01J2531/825 , C07B2200/11 , C07F15/002 , C07F15/0046 , C08F10/00 , C40B40/14 , C08F2/38 , C08F4/80
摘要： Methods of preparing libraries of multivalent arrays and libraries made by the methods. Component multivalent arrays of a library have defined length, defined terminal functionality and defined pendant functional groups. Methods include the preparation of a multivalent array having the steps of polymerizing at least one monomer comprising at least one polymerizable group and at least one latent reactive group in the presence of a metal carbene catalyst to form a polymer template comprising at least one latent reactive group; and combining the polymer template with at least one functionalizing reagent comprising at least one reactive group under conditions effective to react the latent reactive group of the polymer template with the reactive group of the functionalizing reagent to form a multivalent array. Methods further include preparation of a telechelic polymer (mono- or bi-telechelic) that use a ruthenium or osmium carbene catalyst and a capping agent, at least one of which is functionalized.
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公开(公告)号：EP1905777B2
公开(公告)日：2018-06-27
申请号：EP06761350.5
申请日：2006-07-03
发明人： ZHAN, Zheng-Yun
CPC分类号： B01J31/2265 , B01J31/068 , B01J31/1666 , B01J31/1683 , B01J31/2208 , B01J31/2273 , B01J31/2278 , B01J31/2404 , B01J31/403 , B01J2231/54 , B01J2531/821 , B01J2540/34 , B01J2540/40 , B01J2540/62 , C07C315/04 , C07C2601/10 , C07F15/0046 , Y02P20/584 , C07C317/14
摘要： The present invention disclosed a kind of ruthenium complex ligands, ruthenium complexes and immobilized ruthenium complex catalysts. The invention also relates to preparation and use of new ruthenium complex ligands, ruthenium complexes and immobilized ruthenium complex catalysts. The ruthenium complex ligand I and ruthenium complex II in the present invention have the following structures: The immobilized ruthenium complex catalysts in the present invention have the structure of IV : In the present invention, the ruthenium complexes and immobilized ruthenium complex catalysts have several significant advantages, e.g., high catalytic activity, high stability, easy recovery and reusability.
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7.发明公开Ruthenium complex ligand, ruthenium complex and the use of the complex as a catalyst in olefin metathesis reactions 审中-公开RENHENIUMKOMPLEXLIGAND，RUTHENIUMKOMPLEX UND VERWENDUNG DES KOMPLEXES ALS KATALYSATOR IN OLEFINMETATHESEREAKINGEN
公开(公告)号：EP2886549A1
公开(公告)日：2015-06-24
申请号：EP14196282.9
申请日：2006-07-03
发明人： Zhan, Zheng-Yun
CPC分类号： B01J31/2265 , B01J31/068 , B01J31/1666 , B01J31/1683 , B01J31/2208 , B01J31/2273 , B01J31/2278 , B01J31/2404 , B01J31/403 , B01J2231/54 , B01J2531/821 , B01J2540/34 , B01J2540/40 , B01J2540/62 , C07C315/04 , C07C2601/10 , C07F15/0046 , Y02P20/584 , C07C317/14
摘要： The present invention disclosed a kind of ruthenium complex ligands, ruthenium complexes and immobilized ruthenium complex catalysts. The invention also relates to preparation and use of new ruthenium complex ligands and ruthenium complexes in metathesis reactions as catalysts have several significant advantages, e.g., high catalytic activity, high stability, easy recovery and reusability. The ruthenium complex ligand I and ruthenium complex II in the present invention have the following structures:
摘要翻译： 本发明公开了一种钌络合物配位体，钌络合物和固定化的钌络合物催化剂。 本发明还涉及新的钌络合物配位体和钌络合物在复分解反应中的制备和用途，因为催化剂具有几个显着的优点，例如高催化活性，高稳定性，容易的回收和再利用性。 本发明中的钌络合配体I和钌络合物II具有以下结构：
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8.发明授权RUTHENIUM COMPLEX LIGAND, RUTHENIUM COMPLEX, CARRIED RUTHENIUM COMPLEX CATALYST AND THE PREPARING METHODS AND THE USE THEREOF 有权钌络合物配体，钌络合物，携带的钌络合物催化剂及其制备方法及其用途
公开(公告)号：EP1905777B1
公开(公告)日：2015-05-06
申请号：EP06761350.5
申请日：2006-07-03
发明人： ZHAN, Zheng-Yun
CPC分类号： B01J31/2265 , B01J31/068 , B01J31/1666 , B01J31/1683 , B01J31/2208 , B01J31/2273 , B01J31/2278 , B01J31/2404 , B01J31/403 , B01J2231/54 , B01J2531/821 , B01J2540/34 , B01J2540/40 , B01J2540/62 , C07C315/04 , C07C2601/10 , C07F15/0046 , Y02P20/584 , C07C317/14
摘要： The present invention disclosed a kind of ruthenium complex ligands, ruthenium complexes and immobilized ruthenium complex catalysts. The invention also relates to preparation and use of new ruthenium complex ligands, ruthenium complexes and immobilized ruthenium complex catalysts. The ruthenium complex ligand I and ruthenium complex II in the present invention have the following structures: The immobilized ruthenium complex catalysts in the present invention have the structure of IV : In the present invention, the ruthenium complexes and immobilized ruthenium complex catalysts have several significant advantages, e.g., high catalytic activity, high stability, easy recovery and reusability.
摘要翻译： 本发明公开了一种钌络合物配位体，钌络合物和固定化的钌络合物催化剂。 本发明还涉及新的钌络合物配体，钌络合物和固定的钌络合物催化剂的制备和应用。 本发明中的钌配合物I和钌络合物II具有以下结构：本发明的固定化钌配合物催化剂具有IV的结构：本发明中，钌络合物和固定化的钌络合物催化剂具有几个显着的优点 例如催化活性高，稳定性好，易于回收和再利用。
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9.发明公开RUTHENIUM COMPLEX LIGAND, RUTHENIUM COMPLEX, CARRIED RUTHENIUM COMPLEX CATALYST AND THE PREPARING METHODS AND THE USE THEREOF 有权RUTHENIUMKOMPLEXLIGAND，钌，支持RUTHENIUMKOMPLEXKATALYSATOR和方法及用途
公开(公告)号：EP1905777A4
公开(公告)日：2011-03-23
申请号：EP06761350
申请日：2006-07-03
CPC分类号： B01J31/2265 , B01J31/068 , B01J31/1666 , B01J31/1683 , B01J31/2208 , B01J31/2273 , B01J31/2278 , B01J31/2404 , B01J31/403 , B01J2231/54 , B01J2531/821 , B01J2540/34 , B01J2540/40 , B01J2540/62 , C07C315/04 , C07C2601/10 , C07F15/0046 , Y02P20/584 , C07C317/14
摘要： The present invention disclosed a kind of ruthenium complex ligands, ruthenium complexes and immobilized ruthenium complex catalysts. The invention also relates to preparation and use of new ruthenium complex ligands, ruthenium complexes and immobilized ruthenium complex catalysts. The ruthenium complex ligand I and ruthenium complex II in the present invention have the following structures: The immobilized ruthenium complex catalysts in the present invention have the structure of IV : In the present invention, the ruthenium complexes and immobilized ruthenium complex catalysts have several significant advantages, e.g., high catalytic activity, high stability, easy recovery and reusability.
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公开(公告)号：EP1313559B2
公开(公告)日：2012-10-24
申请号：EP01963854.3
申请日：2001-08-09
发明人： HOVEYDA, Amir, H. , KINGSBURY, Jason , GARBER, Steven , GRAY, Brian, Lawrence , FOURKAS, John, T.
CPC分类号： C07F15/0046 , B01J23/462 , B01J31/1625 , B01J31/1641 , B01J31/1666 , B01J31/1683 , B01J31/1805 , B01J31/2208 , B01J31/2273 , B01J31/2404 , B01J31/28 , B01J31/4038 , B01J2231/482 , B01J2231/543 , B01J2531/821 , C07B2200/11 , C07C6/02 , C07C29/00 , C07C67/293 , C07C2531/22 , C07C2601/08 , C07C2601/16 , C07D233/56 , C08F290/00 , C08G83/003 , C08L51/04 , C08L51/08 , Y02P20/584 , Y02P20/588 , C07C35/18 , C07C35/06 , C07C35/21 , C07C69/013 , C07C69/145
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