公开(公告)号：EP1355853A4

公开(公告)日：2005-06-08

申请号：EP01983334

申请日：2001-11-21

申请人： VERY SMALL PARTICLE COMPANY PT

发明人： TALBOT PETER CADE ,  ALARCO JOSE ANTONIO ,  EDWARDS GEOFFREY ALAN

IPC分类号： B82B3/00 ,  B01J19/00 ,  C01B13/14 ,  C01B13/18 ,  C01B13/32 ,  C01F1/00 ,  C01F17/00 ,  C01G1/02 ,  C01G3/00 ,  C01G25/00 ,  C01G45/00 ,  C01G45/02 ,  C01G51/00 ,  C01G53/00 ,  C01G53/02 ,  C01B13/36 ,  C01G3/02 ,  C01G25/02 ,  C01G51/04 ,  C01G53/04

CPC分类号： C01G3/006 ,  B82Y30/00 ,  C01B13/18 ,  C01B13/185 ,  C01F17/0043 ,  C01G1/02 ,  C01G25/006 ,  C01G25/02 ,  C01G45/02 ,  C01G45/1242 ,  C01G45/1264 ,  C01G51/02 ,  C01G51/42 ,  C01G53/02 ,  C01G53/56 ,  C01G53/68 ,  C01P2002/01 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2004/04 ,  C01P2004/50 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/17

摘要： A method of producing particles having nano-sized grains, the method comprising the steps of: (a) preparing a solution containing one or more metal cations; (b) mixing the solution from step (a) with one or more surfactants to form a surfactant/liquid mixture and (c) heating the mixture from step (b) above to form the particles.

公开(公告)号：EP3235915A1

公开(公告)日：2017-10-25

申请号：EP15845394.4

申请日：2015-09-22

申请人： Acondicionamiento Tarrasense (Centro Tecnológico LEITAT) ,  Consejo Superior De Investigaciones Científicas

发明人： MARTÍNEZ CRESPIERA, Sandra ,  AMANTIA, David ,  PELEGRÍN RELLÁN, César ,  MARTÍN GONZÁLEZ, María Soledad ,  RULL BRAVO, Marta ,  ABAD MAYOR, Begoña ,  FERNÁNDEZ LOZANO, José Francisco ,  GUTIÉRREZ TAUSTE, David ,  DELLA PIRRIERA, Monica ,  FACCINI, Mirko ,  AUBOUY, Laurent

IPC分类号： C22C1/00 ,  H01L35/00 ,  C01G51/02 ,  C01G30/00 ,  B82Y30/00

CPC分类号： B82Y30/00 ,  C01G30/00 ,  C01G51/02 ,  C22C1/00 ,  H01L35/00

摘要： The invention relates to a method for the production of nanostructured skutterudites of the CoSb 3 type from a solution of the corresponding precursor acetate salts and a polymer. The method includes a step of atomisation or electrospinning in order to eliminate the solvent from said solution and to nanostructure the precursor that is subsequently heat-treated under an inert atmosphere.

摘要翻译： 本发明涉及由相应的前体乙酸盐和聚合物的溶液生产CoSb 3型纳米结构化方钴矿的方法。 该方法包括雾化或静电纺丝的步骤，以便从所述溶液中除去溶剂并使在惰性气氛下随后热处理的前体纳米结构化。

公开(公告)号：EP2218787A1

公开(公告)日：2010-08-18

申请号：EP09166859.0

申请日：2009-07-30

申请人： Korea Institute of Science and Technology

发明人： Kim, Dong-Wan ,  Shim, HyunWoo ,  Ko, Young Dae ,  Choi, Kyoung Jin ,  Park, Jae-Gwan

IPC分类号： C12P3/00 ,  B01J35/00 ,  B01J35/02 ,  C01G1/02 ,  C01G49/08 ,  C07C15/52 ,  C07C69/618

CPC分类号： C12P3/00 ,  C01G49/08 ,  C01G51/02 ,  C01P2002/72 ,  C01P2002/85 ,  C01P2002/88 ,  C01P2004/03 ,  C01P2006/40 ,  H01M4/485 ,  H01M4/621 ,  H01M10/0525 ,  Y10T428/13

摘要： The present invention relates to an organic-inorganic composite comprising bacteria and transition metal oxides and a method of manufacturing the same. More specifically, the present invention relates to an organic-inorganic composite comprising bacteria and transition metal oxides manufactured by attaching cationic transition metal precursor to bacterial surface, wherein the bacteria with high negative charge on its surface is used as a template, refluxing the bacteria and transition metal ions at room temperature in the presence of sodium borohydride (NaBH 4 ), and inducing reduction/spontaneous oxidation, thereby having an excellent high capacity electrochemical properties, and a method of manufacturing the same.
Therefore, the method of manufacturing the organic-inorganic composite according to the present invention has advantages that it enables to reduce manufacturing cost and the time required therein, mass production, low temperature synthesis, synthesis of uniform nano-structures, control of one dimensional type, be applied to other metal oxides, thus being expected to be used as parts in other electrochemical fields including lithium secondary batteries, super capacitor, nanoelectro-optical system, catalyst and the like.

摘要翻译： 本发明涉及包含细菌和过渡金属氧化物的有机 - 无机复合物及其制造方法。 更具体地说，本发明涉及通过将阳离子过渡金属前体附着到细菌表面而制造的细菌和过渡金属氧化物的有机 - 无机复合物，其中表面上具有高负电荷的细菌用作模板，回流细菌和 过渡金属离子在室温下在硼氢化钠（NaBH 4）存在下，诱导还原/自发氧化，从而具有优异的高容量电化学性能及其制造方法。 因此，本发明的有机 - 无机复合体的制造方法具有能够降低制造成本和所需时间，批量生产，低温合成，均匀纳米结构的合成，一维型的控制的优点 应用于其他金属氧化物，因此预计可用作其它电化学领域的部件，包括锂二次电池，超级电容器，纳米电光学系统，催化剂等。

公开(公告)号：EP2134880A1

公开(公告)日：2009-12-23

申请号：EP08718314.1

申请日：2008-03-28

申请人： ExxonMobil Chemical Patents Inc.

发明人： VAN DRIESSCHE, Eddy ,  VAN VLIET, Arie ,  CAERS, Raphael, Frans ,  BECKERS, Hubertus ,  GARTON, Ronald ,  DA CRUZ, Bertrand ,  LEPAGNOL, Michel ,  KOOKE, Edwin

IPC分类号： C22B23/00 ,  C01G51/02 ,  C07C45/50

CPC分类号： C22B23/026 ,  C01G51/02 ,  C07C45/50 ,  C22B23/065 ,  Y02P10/224 ,  C07C47/02

摘要： In a hydroformylation reaction, the circulation and recovery of cobalt carbonyl in a cobalt catalyst cycle using carbonylate as an intermediate and acidification thereof, is improved by supplying an aqueous sulfuric acid solution containing less than 16 %wt of sulfuric acid to the carbonylate to control sulfuric acid concentration in the carbonylate/acid mixture, before accounting for any acid consuming reaction, to a value of from 2% to 10% by weight. Single step and multistage liquid/liquid extraction techniques as well as vapour/liquid extraction techniques followed by the absorption of cobalt from the vapour in an organic liquid both benefit from this improvement.

公开(公告)号：EP1355853B1

公开(公告)日：2009-04-08

申请号：EP01983334.2

申请日：2001-11-21

申请人： Very Small Particle Company Limited

发明人： TALBOT, Peter, Cade ,  ALARCO, Jose, Antonio ,  EDWARDS, Geoffrey, Alan

IPC分类号： C01B13/36 ,  C01F1/00 ,  C01F17/00 ,  C01G1/02 ,  C01G3/02 ,  C01G25/02 ,  C01G45/02 ,  C01G51/04 ,  C01G53/04

CPC分类号： C01G3/006 ,  B82Y30/00 ,  C01B13/18 ,  C01B13/185 ,  C01F17/0043 ,  C01G1/02 ,  C01G25/006 ,  C01G25/02 ,  C01G45/02 ,  C01G45/1242 ,  C01G45/1264 ,  C01G51/02 ,  C01G51/42 ,  C01G53/02 ,  C01G53/56 ,  C01G53/68 ,  C01P2002/01 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2004/04 ,  C01P2004/50 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/17

摘要： A method of producing particles having nano-sized grains, the method comprising the steps of: (a) preparing a solution containing one or more metal cations; (b) mixing the solution from step (a) with one or more surfactants to form a surfactant/liquid mixture and (c) heating the mixture from step (b) above to form the particles.

公开(公告)号：EP1661649A1

公开(公告)日：2006-05-31

申请号：EP05025795.5

申请日：2005-11-25

申请人： Seoul National University Industry Foundation

发明人： Hyeon, Taeg-Hwan ,  Park, Jong-Nam

IPC分类号： B22F9/30 ,  B22F9/24 ,  C01G49/02 ,  C01G49/00 ,  C01G51/04 ,  C01G9/02 ,  C01F17/00

CPC分类号： G11B5/706 ,  B22F9/30 ,  B82Y10/00 ,  B82Y25/00 ,  B82Y30/00 ,  C01B13/32 ,  C01F17/0043 ,  C01G1/02 ,  C01G3/02 ,  C01G9/02 ,  C01G23/053 ,  C01G25/02 ,  C01G45/02 ,  C01G49/0072 ,  C01G49/02 ,  C01G49/06 ,  C01G49/08 ,  C01G51/00 ,  C01G51/02 ,  C01G51/04 ,  C01G53/04 ,  C01G55/00 ,  C01P2002/72 ,  C01P2002/82 ,  C01P2004/04 ,  C01P2004/32 ,  C01P2004/52 ,  C01P2004/64 ,  C01P2006/42 ,  H01F1/0054 ,  Y10T428/12014

摘要： The present invention is directed to a process for making nanoparticles of metals, metal alloys, metal oxides and multi-metallic oxides, which comprises the steps of reacting a metal salt dissolved in water with an alkali metal salt of C 4-25 carboxylic acid dissolved in a first solvent selected from the group consisting of C 5-10 aliphatic hydrocarbon and C 6-10 aromatic hydrocarbon to form a metal carboxylate complex; and heating the metal carboxylate complex dissolved in a second solvent selected from the group consisting of C 6-25 aromatic, C 6-25 ether, C 6-25 aliphatic hydrocarbon and C 6-25 amine to produce the nanoparticles.

摘要翻译： 本发明涉及一种制备金属，金属合金，金属氧化物和多金属氧化物纳米颗粒的方法，其包括以下步骤：使溶解在水中的金属盐与C 4-25羧酸的碱金属盐溶解 在选自C 5-10脂族烃和C 6-10芳族烃的第一溶剂中，形成金属羧酸盐络合物; 并加热溶解在选自C 6-25芳族，C 6-25醚，C 6-25脂族烃和C 6-25胺的第二溶剂中的金属羧酸盐络合物，以制备纳米颗粒。

公开(公告)号：EP0108698A1

公开(公告)日：1984-05-16

申请号：EP83420169.1

申请日：1983-10-28

申请人： RHONE-POULENC CHIMIE

发明人： Gauthier-Lafaye, Jean ,  Perron, Robert

IPC分类号： C01G51/00 ,  C07C51/10

CPC分类号： C01G51/006 ,  C01G51/02 ,  C01P2006/82

摘要： 57 Procédé de préparation des cobalttétracarbonylates alcalins ou alcalino-terreux par réaction d'un dérivé du cobalt ( + 2) avec l'oxyde de carbone caractérisé en ce que l'on opère en présence d'une base minérale prise dans le groupe formé par les hydroxydes alcalins ou alcalino-terreux et les bicarbonates alcalins ou alcalino-terreux et d'au moins un dérivé du soufre qui comporte au moins un atome de soufre dont le degré d'oxydation est inférieur ou égal à + 3 en milieu aqueux, alcoolique ou hydroalcoolique.
Ces composés peuvent être utilisés comme catalyseur dans lés réactions de carbonylation des dérivés organiques à groupes halométhyle.

公开(公告)号：EP2786820A1

公开(公告)日：2014-10-08

申请号：EP14166331.0

申请日：2005-11-25

申请人： Seoul National University Industry Foundation

发明人： Hyeon, Taeg-Hwan ,  Park, Jong-Nam

IPC分类号： B22F9/30 ,  B22F9/24 ,  C01G49/02 ,  C01G49/00 ,  C01G51/04 ,  C01G9/02 ,  C01F17/00

CPC分类号： G11B5/706 ,  B22F9/30 ,  B82Y10/00 ,  B82Y25/00 ,  B82Y30/00 ,  C01B13/32 ,  C01F17/0043 ,  C01G1/02 ,  C01G3/02 ,  C01G9/02 ,  C01G23/053 ,  C01G25/02 ,  C01G45/02 ,  C01G49/0072 ,  C01G49/02 ,  C01G49/06 ,  C01G49/08 ,  C01G51/00 ,  C01G51/02 ,  C01G51/04 ,  C01G53/04 ,  C01G55/00 ,  C01P2002/72 ,  C01P2002/82 ,  C01P2004/04 ,  C01P2004/32 ,  C01P2004/52 ,  C01P2004/64 ,  C01P2006/42 ,  H01F1/0054 ,  Y10T428/12014

摘要： The present invention is directed to a process for making nanoparticles of metals, metal alloys, metal oxides and multi-metallic oxides, which comprises the steps of reacting a metal salt dissolved in water with an alkali metal salt of C 4-25 carboxylic acid dissolved in a first solvent selected from the group consisting of C 5-10 aliphatic hydrocarbon and C 6-10 aromatic hydrocarbon to form a metal carboxylate complex; and heating the metal carboxylate complex dissolved in a second solvent selected from the group consisting of C 6-25 aromatic, C 6-25 ether, C 6-25 aliphatic hydrocarbon and C 6-25 amine to produce the nanoparticles.

摘要翻译： 本发明涉及一种制备金属，金属合金，金属氧化物和多金属氧化物纳米颗粒的方法，其包括以下步骤：使溶解在水中的金属盐与C 4-25羧酸的碱金属盐溶解 在选自C 5-10脂族烃和C 6-10芳族烃的第一溶剂中，形成金属羧酸盐络合物; 并加热溶解在选自C 6-25芳族，C 6-25醚，C 6-25脂族烃和C 6-25胺的第二溶剂中的金属羧酸盐络合物，以制备纳米颗粒。

公开(公告)号：EP2218787B1

公开(公告)日：2012-09-12

申请号：EP09166859.0

申请日：2009-07-30

申请人： Korea Institute of Science and Technology

发明人： Kim, Dong-Wan ,  Shim, HyunWoo ,  Ko, Young Dae ,  Choi, Kyoung Jin ,  Park, Jae-Gwan

IPC分类号： C12P3/00 ,  B01J35/00 ,  B01J35/02 ,  C01G1/02 ,  C01G49/08 ,  C07C15/52 ,  C07C69/618 ,  C01G51/02 ,  H01M4/62 ,  B01J37/36 ,  H01M4/02 ,  H01M4/485

CPC分类号： C12P3/00 ,  C01G49/08 ,  C01G51/02 ,  C01P2002/72 ,  C01P2002/85 ,  C01P2002/88 ,  C01P2004/03 ,  C01P2006/40 ,  H01M4/485 ,  H01M4/621 ,  H01M10/0525 ,  Y10T428/13

摘要： The present invention relates to an organic-inorganic composite comprising bacteria and transition metal oxides and a method of manufacturing the same. More specifically, the present invention relates to an organic-inorganic composite comprising bacteria and transition metal oxides manufactured by attaching cationic transition metal precursor to bacterial surface, wherein the bacteria with high negative charge on its surface is used as a template, refluxing the bacteria and transition metal ions at room temperature in the presence of sodium borohydride (NaBH 4 ), and inducing reduction/spontaneous oxidation, thereby having an excellent high capacity electrochemical properties, and a method of manufacturing the same. Therefore, the method of manufacturing the organic-inorganic composite according to the present invention has advantages that it enables to reduce manufacturing cost and the time required therein, mass production, low temperature synthesis, synthesis of uniform nano-structures, control of one dimensional type, be applied to other metal oxides, thus being expected to be used as parts in other electrochemical fields including lithium secondary batteries, super capacitor, nanoelectro-optical system, catalyst and the like.

公开(公告)号：EP2134880B1

公开(公告)日：2010-11-03

申请号：EP08718314.1

申请日：2008-03-28

申请人： ExxonMobil Chemical Patents Inc.

发明人： VAN DRIESSCHE, Eddy ,  VAN VLIET, Arie ,  CAERS, Raphael, Frans ,  BECKERS, Hubertus ,  GARTON, Ronald ,  DA CRUZ, Bertrand ,  LEPAGNOL, Michel ,  KOOKE, Edwin

IPC分类号： C22B23/00 ,  C01G51/02 ,  C07C45/50

CPC分类号： C22B23/026 ,  C01G51/02 ,  C07C45/50 ,  C22B23/065 ,  Y02P10/224 ,  C07C47/02

摘要： In a hydroformylation reaction, the circulation and recovery of cobalt carbonyl in a cobalt catalyst cycle using carbonylate as an intermediate and acidification thereof, is improved by supplying an aqueous sulfuric acid solution containing less than 16 %wt of sulfuric acid to the carbonylate to control sulfuric acid concentration in the carbonylate/acid mixture, before accounting for any acid consuming reaction, to a value of from 2% to 10% by weight. Single step and multistage liquid/liquid extraction techniques as well as vapour/liquid extraction techniques followed by the absorption of cobalt from the vapour in an organic liquid both benefit from this improvement.