摘要:
Disclosed herein are energetic compositions and methods of making thereof. A composition includes hydrazinium nitroformate (HNF) particles dispersed in a polymeric binder and a bonding agent bonded to a surface of at least a portion the HNF particles. The bonding agent disclosed is a Lewis acid.
摘要:
The invention is directed to a method for preparing a pyrotechnic composition, to the use of a water-soluble cellulose ether binder, to a pyrotechnic composition, to a method for preparing a pyrotechnic charge, and to a pyrotechnic charge. The method of the invention comprises mixing the fibrous nitrocellulose in wet form with the one or more water-soluble cellulose ether binders and optionally one or more solvents, wherein the amount of organic solvent in the mixture is 10 wt. % or less based on total weight of the mixture.
摘要:
Disclosed herein are energetic compositions and methods of making thereof. A composition includes perchlorate or nitrate containing oxidizer particles, a polymeric binder, and a borylated ferrocene derivative bonding agent bonded to a surface of at least a portion the perchlorate or nitrate containing oxidizer particles to form a Lewis complex.
摘要:
The invention relates to a cast explosive composition, particularly to a pre-cure castable explosive composition comprising an explosive material, a polymerisable binder, a microencapsulated cross linking reagent, said microencapsulated cross linking reagent, comprising a cross linking agent encapsulated in a microcapsule.
摘要:
A method of forming composite materials includes mixing a first metal precursor with a chelating agent to form a first metal-chelate complex. The first metal-chelate complex is added to a polymer binder having terminating hydroxyl groups to form a polymer binder-first metal-chelate. The polymer binder first metal-chelate complex is mixed with an aluminum precursor. The aluminum precursor decomposes forming aluminum nanoparticles dispersed in a continuous phase material having metallic aluminum cores. At least one of the first metal-chelate complex and the first metal is dissolved in the continuous phase. The aluminum nanoparticles can have a passivating coating layer thereon provided by the polymer binder, or can have a passivating coating layer formed by including an epoxide, alcohol, carboxylic acid, or amine in the adding that forms passivating compound(s) which add further protection that can provide complete protection from oxidation of the metallic aluminum cores by air.
摘要:
The invention relates to Insensitive Munition (IM) energetic materials particularly IM propellant compositions, and yet further to nitrocellulose-free IM propellants. An energetic composition suitable for use as a propellant comprises the following components in the following relative proportions: component A; from 5% to 25% by weight of an IM energetic filler; component B: from 50% to 80% by weight of a highly energetic filler comprising at least one nitramine compound; component C of from 5% to 20% by weight of a binder; and component D of from 3% to 15% by weight of a plasticiser; the percentages by weight of components A, B, C and D together with minor additives, if any, adding to 100%.
摘要:
The present invention mainly relates to a method for producing a solid composite propellant (with a polyurethane binder filled with ammonium perchlorate and aluminum). Typically, the ammonium perchlorate charge of the propellant is obtained from at least two charges each having a specific single mode particle size distribution. It is thus possible to reduce the thrust oscillations and the alumina deposits at the rear bottom of the engine. The invention also relates to a solid composite propellant, to solid propellant charges, and to related rocket engines.
摘要:
L'invention se situe dans le domaine militaire des munitions explosives. Elle a pour objet un procédé semi-continu d'obtention d'un chargement explosif composite à matrice solide polyuréthanne chargée dont la charge est pulvérulente et comprend au moins un explosif nitré organique, par introduction dans un moule d'une composition explosive pâteuse puis réticulation thermique de cette composition. La composition est obtenue par mélange de constituants comprenant essentiellement un prépolymère polyol, un plastifiant, un monomère polyisocyanate et une charge solide pulvérulente comprenant au moins un explosif nitré organique. Plus précisément, on réalise tout d'abord, à partir de l'ensemble des constituants, 2 composants : . un composant A pâteux comprenant la totalité du prépolymère polyol et la totalité de la charge solide pulvérulente, . un composant B liquide comprenant la totalité du monomère polyisocyanate, le plastifiant étant indifféremment réparti entre les 2 composants A et B. On mélange ensuite, de façon continue, le composant A et le composant B de telle sorte que le rapport massique composant A / composant B soit constant et compris entre 95/5 et 99,5/0,5. Ce procédé simple et économique permet de s'affranchir, sans inconvénient, du compromis vie de pot / durée de cuisson de la composition.